Rapid crystallization of LiFePO 4 particles by facile emulsion-mediated solvothermal synthesis

Powder Technology

Volumn 219, Issue , 2012, Pages 128-134

  Jugovic D ^a   Mitric M ^b   Kuzmanovic M ^a   Cvjeticanin N ^c   Markovic S ^a   Skapin S ^d   Uskokovic D ^a  

^a INSTITUTE OF TECHNICAL SCIENCES   (Serbia)

^b UNIVERSITY OF BELGRADE   (Serbia)

^c UNIVERSITY OF BELGRADE   (Serbia)

^d JO EF STEFAN INSTITUTE   (Slovenia)

Author keywords

Electrode materials; Lithium iron phosphate (LiFePO 4); Scanning electron microscopy; X ray diffraction

Indexed keywords

CARBON COATING; DISCHARGE CAPACITIES; ELECTRODE MATERIAL; FIELD EMISSION SCANNING ELECTRON MICROSCOPY; LIFEPO; LITHIUM IRON PHOSPHATES; LOW TEMPERATURES; POST ANNEALING; RAPID CRYSTALLIZATION; SCANNING ELECTRONS; SOLVOTHERMAL SYNTHESIS; SOLVOTHERMAL TREATMENT; SYNTHESIS CONDITIONS; TRITON X-100; X-RAY POWDER;

CRYSTAL ORIENTATION; EMULSIFICATION; ENERGY DISPERSIVE SPECTROSCOPY; FIELD EMISSION MICROSCOPES; IRON COMPOUNDS; LITHIUM; MORPHOLOGY; OLIVINE; SCANNING ELECTRON MICROSCOPY; X RAY DIFFRACTION; X RAY POWDER DIFFRACTION;

LITHIUM ALLOYS;

CARBON; CYCLOHEXANE; HEXANOL; IRON; LITHIUM; LITHIUM IRON PHOSPHATE; PHOSPHATE; TRITON X 100; UNCLASSIFIED DRUG; WATER;

ARTICLE; CRYSTAL STRUCTURE; CRYSTALLIZATION; ELECTRIC POTENTIAL; ELECTROCHEMISTRY; EMULSION; ENERGY DISPERSIVE SPECTROSCOPY; FIELD EMISSION SCANNING ELECTRON MICROSCOPY; LOW TEMPERATURE; MORPHOLOGY; POWDER; PROCEDURES; SOLVOTHERMAL SYNTHESIS; SPECTROSCOPY; SYNTHESIS; X RAY DIFFRACTION;

EID: 84856431744     PISSN: 00325910     EISSN: 1873328X     Source Type: Journal    
DOI: 10.1016/j.powtec.2011.12.028     Document Type: Article

References (30)

1. 4. Nature Materials 2008, 7:741-747.
2. 4 cathodes. Electrochemistry Communications 2007, 9:2778-2783.
3. 4 nanoplates. Journal of Materials Chemistry 2009, 19:605-610.
4. 4 prepared by sol-gel method based on citric acid. Solid State Ionics 2005, 176:1801-1805.
5. 4. Journal of Power Sources 2006, 163:180-184.
6. 4. Journal of Power Sources 2007, 167:524-528.
7. Kim J.-K., Choi J.-W., Chauhan G.S., Ahn J.-H., Hwang G.-C., Choi J.-B., Ahn H.-J. Enhancement of electrochemical performance of lithium iron phosphate by controlled sol-gel synthesis. Electrochimica Acta 2008, 53:8258-8264.
8. 4 by a combination of spray pyrolysis with planetary ball-milling followed by heat treatment and their electrochemical properties. Powder Technology 2009, 191:111-116.
9. 4 at high rate performance. Journal of Alloys and Compounds 2011, 509:1279-1284.
10. Padhi K., Nanjundswamy K.S., Goodenough J.B. Phospho-olivines as positive-electrode materials for rechargeable lithium batteries. Journal of the Electrochemical Society 1997, 144:1188-1194.
11. 4: an X-ray diffraction and Mössbauer spectroscopy study. Solid State Ionics 2000, 130:41-52.
12. 4 (M=Mn, Fe, Co, Ni) olivine materials. Electrochemical and Solid-State Letters 2004, 7:A30-A32.
13. Jugovic D., Uskokovic D. A review of recent developments in the synthesis procedures of lithium iron phosphate powders. Journal of Power Sources 2009, 190:538-544.
14. 4 platelets as cathode material for lithium-ion batteries. Journal of Physical Chemistry C 2010, 114:16806-16812.
15. 4 synthesized by the hydrothermal method at 443 K. Journal of Materials Chemistry 2007, 17:4803-4810.
16. 4 powders for Li-ion battery applications. Chemistry of Materials 2009, 21:1096-1107.
17. Tarascon Jean-Marie, Recham N., Armand M., Chotard J.-N., Barpanda P., Walker W., Dupont L. Hunting for better Li-based electrode materials via low temperature inorganic synthesis. Chemistry of Materials 2010, 22:724-739.
18. 4 electrode by solvothermal synthesis and their cathode properties. Journal of Power Sources 2010, 195:6167-6171.
19. Nan C., Lu J., Chen C., Peng Q., Li Y. Solvothermal synthesis of lithium iron phosphate nanoplates. Journal of Materials Chemistry 2011, 21:9994-9996.
20. 4 nanodendrites in a novel system of ethylene glycol-water. Journal of Crystal Growth 2010, 312:3493-3502.
21. Yang Shiliu, Zhou Xufeng, Zhang Jiangang, Liu Zhaoping Morphology-controlled solvothermal synthesis of LiFePO4 as a cathode material for lithium-ion batteries. Journal of Materials Chemistry 2010, 20:8086-8091.
22. 4 hierarchically dumbell-like microstructures by nanoplate self-assembly and their application as a cathode material in lithium-ion batteries. Journal of Physical Chemistry C 2009, 113:3345-3351.
23. Xua Z., Xua L., Lai Q., Ji Xiaoyang Microemulsion synthesis of LiFePO4/C and its electrochemical properties as cathode materials for lithium-ion cells. Materials Chemistry and Physics 2007, 105:80-85.
24. 4 nanowires. Journal of Solid State Chemistry 2007, 180:284-290.
25. Penn R.L., Banfield F. Morphology development and crystal growth in nanocrystalline aggregates under hydrothermal conditions: insights from titania. Geochimica et Cosmochimica Acta 1999, 63:1549-1557.
26. Fisher C.A.J., Islam M.S. Surface structures and crystal morphologies of LiFePO4: relevance to electrochemical behaviour. Journal of Materials Chemistry 2008, 18:1209-1215.
27. Cheary R.W., Coelho A.A. A fundamental parameters approach of X-ray line-profile fitting. Journal of Applied Crystallography 1992, 25:109-121.
28. Zhu D.-M., Feng K.-I., Schelly Z.A. Reverse micelles of Triton X-100 in cyclohexane. Effects of temperature, water content, and salinity on the aggregation behavior. The Journal of Physical Chemistry 1992, 96:2382-2385.
29. Cölfen H., Mann S. Higher-order organization by mesoscale self-assembly and transformation of hybrid nanostructures. Angewandte Chemie International Edition 2003, 42:2350-2365.
30. 4. Journal of Power Sources 2005, 146:570-574.