Oxide melt solution calorimetry of Fe2+-bearing oxides and application to the magnetite-maghemite (Fe3O4-Fe 8/3O4) system

American Mineralogist

Volumn 97, Issue 1, 2012, Pages 164-175

  Lilova, Kristina I ^a   Xu, Fen ^a   Rosso, Kevin M ^b   Pearce, Carolyn I ^b   Kamali, Saeed ^a   Navrotsky, Alexandra ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

Author keywords

Enthalpies of mixing; High temperature oxide melt solution calorimetry; Iron bearing oxides; Magnetite maghemite spinel solid solution; Vacancy distribution

Indexed keywords

CALORIMETERS; CALORIMETRY; DROPS; ENTHALPY; ENTROPY; HEMATITE; LEAD COMPOUNDS; MAGNETITE; MIXING; SODIUM;

DISTRIBUTION OF CATIONS; ENTHALPIES OF FORMATION; HIGH TEMPERATURE OXIDE MELT SOLUTION CALORIMETRY; MAGHEMITES; MULTI-COMPONENT OXIDES; OXIDATIVE DISSOLUTION; SPINEL SOLID SOLUTIONS; VACANCY DISTRIBUTION;

SOLID SOLUTIONS;

CALORIMETRY; DISSOLUTION; ENTHALPY; HIGH TEMPERATURE; IRON; MAGHEMITE; MAGNETITE; MIXING; OXIDE; SOLID SOLUTION; SOLVENT;

EID: 84856350845     PISSN: 0003004X     EISSN: 19453027     Source Type: Journal    
DOI: 10.2138/am.2012.3883     Document Type: Article

References (124)

1. 4: Calorimetric measurements, thermochemical calculations, and geophysical application. Journal of Geophysical Research, 94, 15671-15685.
2. 3. Zeitschrift für Kristallographie, Kristallgeometrie, Kristallphysik, Kristallchemie, 137, 321-340.
3. Arenholz, E. and Prestemon, S. O. (2005) Design and performance of an eight-pole resistive magnet for soft X-ray magnetic dichroism measurements. Review of Scientific Instruments, 76, 083908.
4. Armstrong, R. J., Morrish, A. H., and Sawatzky, G. A. (1966) Mössbauer study of ferric ions in the tetrahedral and octahedral sites of a spinel. Physics Letters, 23, 414-416.
5. 1+y). Memoirs of the Faculty of Engineering, Kyoto University, 32, 66-77.
6. Bauminger, R., Cohen, S. G., Marinov, A., Ofer, S., and Segal, E. (1961) Study of the low temperature transition in magnetite and the internal fields acting on iron nuclei in some spinel ferrites, using Mössbauer absorption. Physical Review, 122, 1447-1450.
7. 3 vacancies ordering and lattice parameters. Journal of Solid State Chemistry, 163, 459-465.
8. 2. Journal of Petrology, 29, 445-522.
9. 6 octahedral chains. Journal of Solid State Chemistry, 67, 85-90. (Pubitemid 17553135)
10. Bichowsky, F. and Rossini, D., Eds. (1936) The Thermochemistry of Chemical Substances, 460 p. Reinold, New York.
11. Bomati-Miguel, O., Mazeina, L., and Navrotsky, A. (2008) Calorimetric study of maghemite nanoparticles synthesized by laser-induced pyrolysis. Chemistry of Materials, 20, 591-598. (Pubitemid 351212252)
12. Boudeulle, M., Batis-Landoulsi, H., Leclercq, C., and Vergnon, P. (1983) Structure of γ-ferric oxide microcrystals: vacancy distribution and superstructure. Journal of Solid State Chemistry, 48, 21-32. (Pubitemid 13561107)
13. Braun, P. B. (1952) Superstructure in spinels. Nature, 170, 1123.
14. 3) solid solutions: The effects of cation ordering on the thermodynamics of mixing. American Mineralogist, 79, 485-496.
15. Carel, C. and Vallet, P. (1981) First-order transition of magnetite at 1160 °C. Bulletin de la Societe Scientifique de Bretagne, 52, 55-59.
16. Chai, L. and Navrotsky, A. (1994) Enthalpy of formation of siderite and its application in phase equilibrium calculation. American Mineralogist, 79, 921-929.
17. 2. American Mineralogist, 81, 1141-1147.
18. 3 solid solution. Geochimica et Cosmochimica Acta, 60, 4377-4383.
19. Chase, M. W. Jr., Davies, C. A., Downey, J. R. Jr., Frurip, D. J., McDonald, R. A., and Syverud, A. N. (1985) JANAF Thermochemical Tables. Third edition. Part II. Cr-Zr. Journal of Physical and Chemical Reference Data 14 (Suppl. 1).
20. 12 (almandine) by high temperature alkali borate solution calorimetry. Geochimica et Cosmochimica Acta, 47, 1597-1603.
21. Chen, C. T., Idzerda, Y. U., Lin, H. J., Smith, N. V., Meigs, G., Chaban, E., Ho, G. H., Pellegrin, E., and Sette, F. (1995) Experimental confirmation of the X-ray magnetic circular dichroism. Sum rules for iron and cobalt. Physical Review Letters, 75, 152-155.
22. [6, 4]Al in phlogopite: Hightemperature solution calorimetry, heat capacities and thermodynamic properties of the phlogopite-eastonite join. American Mineralogist, 77, 1191-1205. (Pubitemid 23387984)
23. Coey, J. M. D. and Morrish, A. H. (1971) Mössbauer study of conduction in magnetite. Journal de Physique, Colloque 1, Cl-271-Cl-273.
24. Cook, D. C., Oh, S. J., Balasubramanian, R., and Yamashita, M. (1999) The role of goethite in the formation of the protective corrosion layer on steels. Hyperfine Interactions, 122, 59-70.
25. Cormack, A. N. (1983) A perfect lattice approach to non-stoichiometry. Solid State Ionics, 8, 187-192.
26. Cornell, R. M. and Schwertmann, U., Eds. (2003) The Iron Oxides: Structure, properties, reactions, occurrences and uses, 664 p. Wiley-VCH, Darmstadt.
27. Da Costa, G. M., De Grave, E., Bryan, A. M., and Bowen, L. H. (1994) Mössbauer studies of nano-sized aluminum-substituted maghemites. Hyperfine Interactions, 94, 1983-1987.
28. Da Costa, G. M., De Grave, E., and Vandenberghe, R. E. (1998) Mössbauer studies of magnetite and Al-substituted maghemites. Hyperfine Interactions, 117, 207-243. (Pubitemid 128692779)
29. Darken, L. S. and Gurry, R. W. (1945) The system iron-oxygen. I. The wüstite field and related equilibria. Journal of the American Chemical Society, 67, 1398-1412.
30. - (1946) The system iron-oxygen. II. Equilibrium and thermodynamics of liquid oxide and other phases. Journal of the American Chemical Society, 68, 798-819.
31. 3O jarosites. Geochimica et Cosmochimica Acta, 67, 2063-2076. (Pubitemid 36755126)
32. Dunn, D. S., Bogart, M. B., Brossia, C. S., and Cragnolino, G. A. (2000) Corrosion of iron under alternating wet and dry conditions. Corrosion, 56, 470-480.
33. Esdaile, J. D. (1983) The correlation of the thermodynamic properties of wüstite by a Gaussian based formalism. Metallurgical Transactions A: Physical Metallurgy and Materials Science, 14, 771-775. (Pubitemid 13570334)
34. Fabrichnaya, O. B. and Sundman, B. (1997) The assessment of thermodynamic parameters in the Fe-O and Fe-Si-O systems. Geochimica et Cosmochimica Acta, 61, 4539-4555.
35. 3 by neutron diffraction. Physical Review, 112, 1130-1131.
36. Fukasawa, T., Iwatsuki, M., and Furukawa, M. (1993) State analysis and relationship between lattice constants and compositions including minor elements of synthetic magnetite and maghemite. Analytica Chimica Acta, 281, 413-419. (Pubitemid 23303469)
37. 3. Nature, 217, 1118-1121.
38. 4. Nature, 228, 548-549.
39. Gillot, B., Rousset, A., and Dupre, G. (1978) Influence of crystallite size on the oxidation kinetics of magnetite. Journal of Solid State Chemistry, 25, 263-271. (Pubitemid 8632890)
40. Glushko, V. P., Medvedev, V. A., Bergman, G. A., Vasilev, B. P., Gurvich, L. V., Alekseev, V. I., Kolesov, V. P., Yungman, V. S., Ioffe, N. T., Vorabev, A. F., and others. (1972) Thermicheskie konstanty veshchestv. Academy of Science, Russia.
41. Goursat, A. G. and Smeltzer, W. W. (1973) Oxidation of iron. Reviews on High-Temperature Materials, 1, 351-396.
42. 3, and their relationship to structure. Physics and Chemistry of Minerals, 16, 164-171.
43. Gota, S., Gautier-Soyer, M., and Sacchi, M. (2000) Fe 2p absorption in magnetic oxides: Quantifying angular-dependent saturation effects. Physical Review B, 62, 4187-4190.
44. Greaves, C. (1983) A powder neutron diffraction investigation of vacancy ordering and covalence in γ-ferric oxide. Journal of Solid State Chemistry, 49, 325-333. (Pubitemid 14471672)
45. 4) from 300 to 1050 K. Ferrimagnetic transition and zero point entropy. Journal of Chemical Thermodynamics, 6, 859-872.
46. Guillemet-Fritsch, S., Navrotsky, A., Tailhades, P., Coradin, H., and Wang, M. (2005) Thermochemistry of iron manganese oxide spinels. Journal of Solid State Chemistry, 178, 106-113. (Pubitemid 40214912)
47. Haavik, C., Stølen, S., Fjellvåg, H., Hanfland, M., and Häusermann, D. (2000) Equation of state of magnetite and its high-pressure modification: thermodynamics of the Fe-O system at high pressure. American Mineralogist, 85, 514-523. (Pubitemid 30236915)
48. 3. Zeitschrift fur Physikalische Chemie, Abteilung B: Chemie der Elementarprozesse, Aufbau der Materie, 29, 95-103.
49. 3 small particles. Solid State Communication, 22, 779-782. (Pubitemid 8559124)
50. 3. Zeitschrift fur Physikalische Chemie, 844, 216-226.
51. 3, with comments on selected oxygen buffer reactions. American Mineralogist, 75, 781-790.
52. Holland, T. J. B. and Powell, R. (1998) An internally consistent thermodynamic data set for phases of petrological interest. Journal of Metamorphic Geology, 16, 309-343. (Pubitemid 28388692)
53. 4 and phase equilibria in the system Pb-Pt-O. Journal of Alloys and Compounds, 481, 228-232.
54. Janowski, J., Benesch, R., Jaworski, M., and Miklasinski, A. (1970a) Thermodynamic properties of wüstite obtained by oxidizing pure iron. Metalurgia i Odlewnictwo, 37, 11-28.
55. Janowski, J., Benesch, R., Bialek, H., Dargel, L., Jaworski, M., Kolodziejczyk, A., Miklasinski, A., and Obuszko, Z. (1970b) Determination of thermodynamic properties and structure of wüstite by measuring some physical quantities. Metalurgia i Odlewnictwo, 38, 7-32.
56. Knacke, O., Kubaschewski, O., and Hesselmann, K., Eds. (1991) Thermochemical Properties of Inorganic Substances. second edition, 688 p. Springer-Verlag, Berlin.
57. 4. Physics and Chemistry of Minerals, 20, 536-540.
58. Komarov, V. F., Oleinikov, N. N., and Tretyakov, Yu. D. (1967) Thermodynamic properties of solid solutions based on hematite in an iron-oxygen system. Izvestiya Akademii Nauk SSSR, Neorganicheskie Materialy, 3, 1064-1072.
59. Kryukova, G. N., Chuvilin, A. L., and Sadykov, V. A. (1990) On the γ-ferric oxide superstructure observation by high resolution electron microscopy. Journal of Solid State Chemistry, 89, 208-211.
60. Kullerud, G., Donnay, G., and Donnay, J. D. H. (1969) Omission solid solution in magnetite: kenotetrahedral magnetite. Zeitschrift für Kristallographie, Kristallgeometrie, Kristallphysik, Kristallchemie, 128, 1-17.
61. Kündig, W. and Hargrove, R. S. (1969) Electron hopping in magnetite. Solid State Communications, 7, 223-227.
62. Kurepin, V. A (1975) Activity of components, thermodynamical characteristics of reactions, and phase equilibriums in the iron-oxygen system at high temperatures and pressures. Geokhimiya, 10, 1475-1483 (in Russian).
63. Laberty, C. and Navrotsky, A. (1998) Energetics of stable and metastable lowtemperature iron oxides and oxyhydroxides. Geochimica et Cosmochimica Acta, 62, 2905-2913. (Pubitemid 29198814)
64. Leonovich, B. I., Lykasov, A. A., and Platonova, O. V. (2001) Thermodynamic analysis of iron-oxygen system. Izvestiya Vysshikh Uchebnykh Zavedenii, Chernaya Metallurgiya, 6, 3-7.
65. Lindsley, D. H. (1976) The crystal chemistry and structure of oxide minerals as exemplified by the Fe-Ti oxides. In D. Rumble, Ed., Oxide Minerals, 3, p. L-1-L-60. Reviews in Mineralogy, Mineralogical Society of America, Chantilly, Virginia.
66. Lindsley, D. H., Ed. (1991) Oxide Minerals: Petrologic and Magnetic Significance, vol. 25, 509 p. Reviews in Mineralogy, Mineralogical Society of America, Chantilly, Virginia.
67. 3 join. Physics and Chemistry of Minerals, 25, 591-596. (Pubitemid 29109832)
68. Majzlan, J., Navrotsky, A., and Neil, J. M. (2002) Energetics of anhydrite, barite, celestine, and anglesite: A high-temperature and differential scanning calorimetry study. Geochimica et Cosmochimica Acta, 66, 1839-1850. (Pubitemid 34557557)
69. 3). American Mineralogist, 88, 855-859. (Pubitemid 36770566)
70. Marucco, J. F., Gerdanian, P., and Dodé, M. (1970) Determination of partial molar values of an oxygen mixture in ferrous oxide at 1075 °C. I. Direct measurements of partial molar enthalpies of an oxygen mixture using a Tian-Calvettype high-temperature microcalorimeter. Journal de Chimie Physique et de Physico-Chimie Biologique, 67, 906-912.
71. 3: Stability of the perovskite phase. Physics and Chemistry of Minerals, 21, 207-212.
72. 3 particles with different axial (length/width) ratios. Journal of Solid State Chemistry, 108, 158-163.
73. Morris, R. V., Golden, D. C., Bell, J. F. III, Shelfer, T. D., Scheinost, A. C., Hinman, N. W., Furniss, G., Mertzman, S. A., Bishop, J. L., Ming, D. W., Allen, C. C., and Britt, D. T. (2000) Mineralogy, composition, and alteration of Mars Pathfinder rocks and soils: Evidence from multispectral, elemental, and magnetic data on terrestrial analogue, SNC meteorite, and Pathfinder samples. Journal of Geophysical Research [Planets], 105 (E1), 1757-1817.
74. Navrotsky, A. (1977) Progress and new directions in high temperature calorimetry. Physics and Chemistry of Minerals, 2, 89-104.
75. - (1997) Progress and new directions in high-temperature calorimetry revisited. Physics and Chemistry of Minerals, 24, 222-241.
76. 2 systems. Physics of the Earth and Planetary Interiors, 19, 275-292.
77. 2 in high-temperature lead borate solution calorimetry of volatile-bearing phases. American Mineralogist, 79, 1099-1109.
78. 2. American Mineralogist, 84, 1622-1626. (Pubitemid 30052330)
79. Néel, L. (1948) Propriétés magnétiques des ferrites. Ferrimagnétisme et antiferromagnétisme. Annales de Physique, 3, 137-198.
80. Neff, D., Dillmann, P., Bellot-Gurlet, L., and Beranger, G. (2004) Corrosion of iron archaeological artefacts in soil: characterisation of the corrosion system. Corrosion Science, 47, 515-535.
81. Noguchi, T. and Nakamura, T. (2000) Mineralogy of antarctic micrometeorite recovered from the Dome Fuji Station. Antarctic Meteorite Research, 13, 285-301.
82. 2O-CuO from emf measurements. American Mineralogist, 73, 470-486.
83. Pattrick, R. A. D., van der Laan, G., Henderson, C. M. B., Kuiper, P., Dudzik, E., and Vaughan, D. J. (2002) Cation site occupancy in spinel ferrites studied by X-ray magnetic circular dichroism: developing a method for mineralogists. European Journal of Mineralogy, 14, 1095-1102. (Pubitemid 35391626)
84. Pearce, C. I., Henderson, C. M. B., Telling, N. D., Pattrick, R. A. D., Charnock, J. M., Coker, V. S., Arenholz, E., Tuna, F., and van der Laan, G. (2010) Fe site occupancy in magnetite-ulvospinel solid solutions: A new approach using X-ray magnetic circular dichroism. American Mineralogist, 95, 425-439.
85. Peterson, M. L., White, A. F., Brown, G. E. Jr., and Parks, G. A. (1997) Surface passivation of magnetite by reaction with aqueous Cr (IV): XAFS and TEM results. Environmental Science and Technology, 31, 1573-1576. (Pubitemid 27194534)
86. Raccah, P. and Vallet, P. (1962) Thermodynamic properties of wüstite, a solid solution of iron and oxygen. Comptes Rendus de l'Académie des Sciences, 254, 1038-1040.
87. Ringwood, A. E. (1977) Composition of he core and implications for origin of the earth. Geochemistry Journal, 11, 111-135.
88. Rizzo, H. F., Gordon, R. S., and Cutler, I. B. (1968) Determination of thermodynamic properties in single-phase wüstite by coulometric titration in a high-temperature galvanic cell. National Bureau of Standards, 296, 129-142.
89. - (1969) Determination of phase boundaries and thermodynamic functions in the iron-oxygen system by E. M. F. measurements. Journal of the Electrochemical Society, 116, 266-274.
90. Robie, R. A. and Hemingway, B. S. (1995) Thermodynamic properties of minerals and related substances at 298.15 K and 1 bar (105 Pascals) pressure and at higher temperatures, 461 p. U. S. Geological Survey Bulletin, no. 2131.
91. 3. Journal of Magnetism and Magnetic Materials, 297, 107-117. (Pubitemid 41563275)
92. Scott, T. B., Allen, G. C., Heard, P. J., and Randell, M. G. (2005) Reduction of U (VI) to U (IV) on the surface of magnetite. Geochimica et Cosmochimica Acta, 69, 5639-5646.
93. 4): laserinduced thermal effects and oxidation. Journal of Raman Spectroscopy, 34 845-852.
94. 3: Synchrotron X-ray powder diffraction and high-resolution electron microscopy studies. Journal of Applied Crystollography, 28, 141-145.
95. 3. Zeitschrift für Anorganische und Allgemeine Chemie, 293, 228-232.
96. Smelik, E., Jenkins, DM., and Navrotsky, A. (1994) A calorimetric study of synthetic amphiboles along the tremolite-tschermakite join and the heats of formation of magnesiohornblende and tschermakite. American Mineralogist 79, 1110-1122.
97. 3). Journal of Chemical Thermodynamics, 42, 1142-1151.
98. Spencer, P. J. and Kubaschewski, O. (1978) A thermodynamic assessment of the iron-oxygen system. CALPHAD: Computer Coupling of Phase Diagrams and Thermochemistry, 2, 147-167.
99. Stohr, J. (1995) X-ray magnetic circular dichroism spectroscopy of transition metal thin films. Journal of Electron Spectroscopy and Related Phenomena, 75, 253-272.
100. Stølen, S., Glöckner, R., Grønvold, F, Atake, T, and Izumisawa, S. (1996) Heat capacity and thermodynamic properties of nearly stoichiometric wüstite from 13 to 450 K. American Mineralogist, 81, 973-981.
101. Sundman, B. (1991) An assessment of the iron-oxygen system. Journal of Phase Equilibria, 12, 127-140.
102. Takai, S., Akishige, Y, Kawaji, H., Atake, T, and Sawaguchi, E. (1994) Lowtemperature heat capacities and Verwey transition of magnetite. Journal of Chemical Thermodynamics, 26, 1259-1266.
103. 3. Journal of the Physical Society of Japan, 21, 1256-1263.
104. Tessier F, Navrotsky, A., Niewa, R., Leineweber, A., Jacobs, H., Kikkawa, S., Takahashi, M., Kanamaru, F, Di Salvo, F. J. (2000) Energetics of binary iron nitrides. Solid State Sciences, 2, 457-462.
105. 4) solid solution. Determination of heat of formation. Physics and Chemistry of Minerals, 7, 43-46.
106. 3. Journal of the Physical Society of Japan, 17, Suppl. BII, 391-394.
107. Vallet, P. (1975a) Thermodynamic properties of solid wüstite below 911 °C. Comptes Rendus des seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 280, 239-241.
108. - (1975b) Thermodynamic properties of solid wüstite at temperatures over 911 °C. Comptes Rendus des seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 281, 291-294.
109. II. Revue de Chimie Minerale, 23, 362-377.
110. Vallet, P., Kleman, M., and Raccah, P. (1963) New thermodynamic properties and a new diagram for solid wüstite. Comptes rendus hebdomadaires des séances de l'Académie des Sciences, 256, 136-138.
111. Vandenberghe, R. E. and De Grave, E. (1989) Mössbauer studies of oxidic spinels. Mössbauer Spectroscopy Applied to Inorganic Chemistry, 3, 159-182.
112. Van der Laan, G. and Kirkman, I. W. (1992) The 2p absorption-spectra of 3d transition-metal compounds in tetrahedral and octahedral symmetry. Journal of Physics-Condensed Matter, 4, 4189-4204.
113. Van der Laan, G. and Thole, B. T. (1991) Strong magnetic-X-ray dichroism in 2p absorption-spectra of 3d transition-metal ions. Physical Revew B, 43, 13401-13411.
114. Van der Laan, G., Zaanen, J., Sawatzky, G. A., Karnatak, R. C., and Esteva, J. M. (1986) Comparison of X-ray absorption with X-ray photoemission of nickel dihalides and NiO. Physical Revew B, 33, 4253-4263.
115. van Oorschot, I. H. M. and Dekkers, M. J. (1999) Dissolution behaviour of finegrained magnetite and maghemite in the citrate-bicarbonate-dithionite extraction method. Earth and Planetary Science Letters, 167, 283-295. (Pubitemid 29301002)
116. Van Oosterhout, G. W. and Rooijmans, C. J. M. (1958) A new superstructure in γ-ferric oxide. Nature, 181, 44-45.
117. 4) and its transition point at low temperatures. Nature, 144, 327-328.
118. Verwey, E. J. W. and de Boer, J. H. (1936) Cation arrangement in a few oxides with crystal structures of the spinel type. Recueil des Travaux Chimiques des Pays-Bas et de la Belgique, 55, 531-540.
119. Weber, H. P. and Hafner, S. S. (1971) Vacancy distribution in nonstoichiometric magnetites. Zeitschrift für Kristallographie, 133, 327-340.
120. 4 heat capacity and thermodynamic properties from 5 to 350 K, low-temperature transition. Journal of Chemical Thermodynamics, 1, 543-557.
121. White, A. F. and Peterson, M. L. (1996) Reduction of aqueous transition metal species on the surfaces of Fe (II)-containing oxides. Geochimimica et Cosmochimica Acta, 60, 3799-3814.
122. Wood, B. J. and Kleppa, O. J. (1981) Thermochemistry of forsterite-fayalite olivine solutions. Geochimica et Cosmochimica Acta, 45, 529-534.
123. 1-0.125xS (0 ≤ x ≤ 1) solid solutions. American Mineralogist, 95, 717-723.
124. Xu, H., Zhang Y., and Navrotsky, A. (2001) Enthalpies of formation of microporous titanosilicates ETS-4 and ETS-10. Microporous and Mesoporous Materials, 47, 285-291. (Pubitemid 32965263)