The assessment of thermodynamic parameters in the Fe-O and Fe-Si-O systems

Geochimica et Cosmochimica Acta

Volumn 61, Issue 21, 1997, Pages 4539-4555

  Fabrichnaya, O B ^a   Sundman, B ^b  

^a UPPSALA UNIVERSITY   (Sweden)

^b ROYAL INSTITUTE OF TECHNOLOGY   (Sweden)

Author keywords

[No Author keywords available]

Indexed keywords

IRON-SILICON-OXYGEN SYSTEM; MAGNETITE; PHASE EQUILIBRIUM; THERMODYNAMICS; WUSTITE;

EID: 0031426646     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0016-7037(97)00256-1     Document Type: Article

References (104)

1. 2. J. Amer. Ceramic Soc. 38, 264-280.
2. Akaogi M., Ito E., and Navrotsky A. (1989) Olivine-modified spinel-spinel transitions in the system: Calorimetric measurements, thermochemical calculation and geophysical application. J. Geophys. Res. 94, 15671-15685.
3. Akaogi M., Yusa H., Shiraishi K., and Suzuki T. (1995) Thermodynamic properties of α-quartz, coesite and stishovite and equilibrium phase relations at high pressures and high temperatures. J. Geophys. Res. 100, 22337-22347.
4. 3. Phys. Earth Planet Inter. 3, 186-188.
5. 4. J. Geophys. Res. 70, 1969-1977.
6. 4. J. Geophys. Res. 68, 679-686.
7. Akimoto S., Yagi T., and Inoue K. (1977) High-pressure phase boundaries in silicate systems using X-ray diffraction. In High-pressure Research: Application in Geophysics (ed. M. H. Manghnani and S. Akimoto), pp. 585-602. Academic Press.
8. 2 at pressures up to 250 kbar and temperatures up to 3000° C. Phys. Earth Planet. Inter. 6, 154-160.
9. 2 using a structure based model for the liquid silicate. Calphad 9, 271-282.
10. Bodsworth C. (1959) The activity of ferrous oxide in silicate melts. J. Iron Steel Inst. 193, 13-24.
11. Boehler R. (1992) Melting of the Fe-FeO and the Fe-FeS systems at high pressure: Constraints on core temperature. Earth Planet. Sci. Lett. 111, 217-227.
12. Bohlen S. R., Essene E. J., and Boettcher A. L. (1980) Reinvestigation and application of olivine-quartz-orthopyroxene barometry. Earth Planet. Sci. Lett. 47, 1-10.
13. 2. Amer. J. Sci. 24, 177-213.
14. Bryant P. E. and Smeltzer W. W. (1969) The dissociation pressure of hematite. J. Electrochem. Soc. 116, 1409-1410.
15. Carel C. (1967) Recherches experimentales et theoriques sur le diagramme d'etat de la wustite solide au-dessus de 910° C. Mem. Sci. Rev. Met. 64, 821-836.
16. Cirilli V. (1946) Studio dell'equilibrio di riduzione con ossido di carbonio, delgi ossidi di ferro in presenza di silice. Gazz. Chim. Italian 76, 331-338.
17. Coughlin J. P., King E. G., and Bonnickson K. P. (1951) High-temperature heat contents of ferrous oxide, magnetite and ferric oxide. J. Amer. Chem. Soc. 73, 3891-3893.
18. Darken L. S. (1948) Melting points of iron oxides on silica; phase equilibria in the system Fe-Si-O as function of gas composition and temperature. J. Amer. Chem. Soc. 70, 2046-2053.
19. Darken L. S. and Gurry R. W. (1945) The system iron-oxygen. 1. The wustite field and related equilibria. J. Amer. Chem. Soc. 67, 1398-1412
20. Darken L. S. and Gurry R. W. (1946) The system iron-oxygen. 2. Equilibrium and thermodynamics of liquid oxide and other phases. J. Amer. Chem. Soc. 68, 798-816.
21. Datsur M. N. and Chipman J. (1949) Equilibrium in the reaction of hydrogen with oxygen in liquid iron. Metals. Trans. 185, 441-445.
22. 4). Ber. Bunsenges Phys. Chem. 86, 112-118.
23. Distin P. A., Whiteway S. G., and Masson C. R. (1971) Solubility of oxygen in liquid iron from 1785° C to 1960° C. A new technique for the study of slag-metal equilibria. Canadian Met. Quaterly 10, 73-78.
24. Fei Y. (1995) Thermal expansion. In Mineral Physics & Crystallography. A Handbook of Physical Constants (ed. T. J. Ahrens), pp. 29-44, AGU.
25. Fei Y. (1996) Crystal chemistry of FeO at high pressure and temperature. In Mineral spectroscopy: A Tribute to Roger G. Burns (ed. M. D. Dyar et al.), pp. 243-254. The Geochemical Soc. Special. Publ. N5.
26. Fei Y. and Mao H. (1994) In situ determination of the NiAs phase of FeO at high pressure and temperature. Science 226, 1678-1680.
27. Fei Y. and Saxena S. (1986) Thermochemical data for phase equilibria in the system Fe-Mg-Si-O at high pressure and temperature. Phys. Chem. Minerals 13, 311-324.
28. Giddings R. A. and Gordon R. S. (1973) Review of oxygen activities and phase boundaries in wustite as determined by electromotive-force and gravimetric methods. J. Amer. Ceramic Soc. 56, 111-116.
29. 2. Metall. Trans. B 11, 107-117.
30. 3 due to the pressure effect on the crystal field. In High-pressure Research in Geophysics (ed. S. Akimoto and M. H. Manghnani), pp. 595-609. Center for Acad Publ.
31. Greig J.W. (1927a) Immiscibility in silicate melts. Amer. J. Sci. 13, 133-154.
32. 2. Amer. J. Sci. 14, 473-484.
33. 4) from 300 to 1050 K. Ferrimagnetic transition and zero-point entropy. J. Chem. Thermodynamics 6, 859-872.
34. Hallstedt B. (1992) Thermodynamics and reactions in Al-Ca-Mg-Si alloy-oxide composites. Ph.D. thesis, Royal Inst. of Technology.
35. 1-xO): A review of its defect structure and physical properties. Rev. Geophys. Space Phys. 22, 37-46.
36. Hewitt D. A. (1978) A redetermination of the fayalite-magnetite-quartz equilibrium between 650 and 850E C. Amer. J. Sci. 278, 715-724.
37. Hillert M., Jansson B., Sundman B., and Ågren J. (1985) A two-sublattice model for molten solutions with different tendency for ionization. Metal. Tran. A 16, 261-266.
38. Hsu L. C. (1967) Melting of fayalite up to 40 kilobars. J. Geophys. Res. 72, 4235-4244.
39. 4 phase diagram by synchrotron radiation. J. Geophys. Res. 91, 4697-4703.
40. 2 at elevated pressures. Phys. Earth Planet. Inter. 13, 213-218.
41. Jacob K. T., Kale G. M., and Iyengar G. N. K. (1989) Chemical potentials of oxygen for fayalite-quartz-iron and fayalite-quartz-magnetite equilibria. Metall. Trans. B 20, 679-685.
42. 3 in the temperature range 1000-1600 K. Scandanavian J. Metall. 14, 252-256.
43. Jacobsson E. and Rosen E. (1981) Thermodynamic studies of high temperature equilibria 25. Solid state emf studies of the systems Fe-FeO, Ni-NiO and Co-CoO in the temperature range 1000-1600 K. Scandanavian. J. Metall. 10, 39-43.
44. Jansson B. (1984) Evaluation of parameters in thermochemical models using different types of experimental data simultaneously. TRITA-MAC 234, Royal Inst. of Technology, Stockholm.
45. Jeanloz R. and Ahrens T. (1980) Equations of state of CaO and FeO. Geophys. J. Royal Astron. Soc. 62, 505-528.
46. Kanzaki M. (1990) Melting of silica up to 7 GPa. J. Amer. Ceramic Soc. 73, 3706-3707.
47. Katsura T., Iwasaki B., Kimura S., and Akimoto S. (1967) High-pressure synthesis of the stoichiometric compound FeO. J. Chem. Phys. 47, 4559-4560.
48. Kieffer S. W. (1979) Thermodynamics and lattice vibrations of minerals 1. Mineral heat capacities and their relationships to simple lattice vibrations of minerals. Rev. Geophys. Space Phys. 17, 1-19.
49. Knittle E. (1995) Static compression measurements of equations of state. In Mineral Physics and Crystallography. A Handbook of Physical Constants (ed T. J. Ahrens), pp. 98-142. AGU.
50. Kubaschewski O. (1982) Iron-binary Phase Diagrams p. 185. Springer.
51. 2. Carnegie Inst. Washington Yearbook 65, 226-230.
52. 4 and FeO. Earth Planet. Sci. Lett. 33, 101-106.
53. Liu L., Shen P., and Bassett W. A. (1982) High-pressure polymorphism of FeO? An alternative interpretation and its implications for the Earth's core. Geophys. J. Royal Astron. Soc. 70, 57-66.
54. Liu J., Topor L., Zhang J., and Navrotsky A. (1996) Calorimetric study of coesite-stishovite transformation and calculation of the phase boundary. Phys. Chem. Minerals 23, 11-16.
55. 4) Carnegie Inst. Washington Yearbook 70, 176-177.
56. Mao H. K., Takahashi T., Bassett W. A., Kinsland G. L., and Merrill L. (1974) Isothermal compression of magnetite to 320 kbar and pressure-induced phase transformation. J. Geophys. Res. 79, 1165-1170.
57. McCammon C. A. (1993) Effect of pressure on the composition of the lower mantle end member FexO. Science 259, 66-68.
58. xO: The iron-rich phase boundary. Phys. Chem. Minerals 10, 106-113.
59. Michal E. J. and Schuhmann R., Jr. (1952) Thermodynamics of iron-silicate slags: Slags saturated with solid silica. Trans. AIME 194, 723-728.
60. 2. Trans. AIME 203, 965-976.
61. 2 system. Phys. Earth Planet. Inter. 19, 275-292.
62. 4 up to about 200 kbar. J. Phys. Earth 27, 189-208.
63. 2 melts by EMF method using zirconia solid electrolyte. Metall. Trans. B 13, 423-427.
64. 3 in the pressure range up to 65 GPa using synchrotron radiation. Phys. Scripta 43, 327-330.
65. 4). Amer. Mineral. 72, 67-75.
66. 2O-CuO from emf measurements. Amer. Mineral. 73, 470-486.
67. Pelton A.D. (1994) Thermodynamically optimized phase diagrams of oxide systems. Phase diagrams for ceramists. v. 7
68. 2 in air. J. Amer. Ceramic Soc. 42, 413-423.
69. 4 liquid. Geophys. Res. Lett. 17, 2093-2096.
70. 2: drop calorimetry measurements between 1000 and 1800 K and review from O to 2000 K. Geochim. Cosmochim. Acta 46, 2639-2658.
71. Richet P., Mao H., and Bell P.M. (1989) Bulk moduli of magnesiowustite from static compression measurement. J. Geophys. Res. 94, 3037-3045.
72. Ringwood A. E. and Hibberson W. (1990) The system Fe-FeO revisited. Phys. Chem. Minerals 17, 313-319.
73. Robie R.A. and Hemingway B.S. (1995) Thermodynamic properties of minerals and related substances at 298.15 K and 1 bar (105 Pascal) pressure and higher temperatures. USGS Bull. 2131.
74. 4) between 5.1 and 383 K: Comparison of calorimetric and equilibrium values for QFM buffer reaction. Amer. Mineral. 67, 463-469.
75. 2. Geochim. Cosmochim. Acta 60, 2379-2395.
76. Saxena S. K. and Shen G. (1992) Assessed data on heat capacity, thermal expansion and compressibility for some oxides and silicates. J. Geophys. Res. 97, 19813-19826.
77. Saxena S. K., Chatterjee N., Fei Y., and Shen G. (1993) Thermodynamic Data on Oxides and Silicates. Springer Verlag.
78. Schenck R., Franz H., and Laymann A. (1932) Gleichgewichtsuntersuchungen uber die Rediktions-, Oxydations- und Kohlungsvorgänge beim Eisen XI. Z. Anorg. u Allg. Chem. 206, 129-151.
79. Schuhmann R., Jr. and Ensio P. J. (1951) Thermodynamics of iron-silicate slags: Slags saturated with gamma iron. Trans. AIME 194, 723-728.
80. 2 system at slagmaking temperatures. Trans. AIME 197, 1097-1104.
81. Schwab R. G. and Kustner D. (1981) Die Gleichgewichtsfugazitäten technologisch und petrologisch wichtiger sauerstoffpuffer. Neues Jb. Mineral. Abhandlungen 140, 111-141.
82. Schwerdtfeger K. and Muan A. (1966) Activities in olivine and pyroxene solid solutions of the system Fe-Mn-Si-O at 1150EC. Trans. AIME 236, 201-211.
83. Selleby M. (1993) An assessment of the Fe-O-Si system. Trita-Mac 509, Royal Inst. of Technology, Stockholm.
84. Shen G. and Lazor P. (1995) Measurement of melting temperatures of some minerals under lower mantle pressures. J. Geophys. Res. 100, 17699-17713.
85. Shen P., Bassett W. A., and Liu L. (1983) Experimental determination of effects of pressure and temperature on the stoichiometry and phase relations of wustite. Geochim. Cosmochim. Acta 47, 773-778.
86. Shen G., Lazor P., and Saxena S.K. (1993) Melting of wustite and iron up to pressures of 600 kbar. Phys. Chem. Minerals 20, 91-96.
87. Simons B. (1980) Composition-lattice parameter relationship of the magnesiowustite solid solution series. Carnegie Inst. Washington Yearbook 79, 376-380.
88. Simons B. and Seifert F. (1979) High-pressure wustite: cell parameters and Mossbauer spectra. Carnegie Inst. Washington Yearbook 78, 625-626.
89. Srecec I., Ender A., Woermann E., Gans W., Jacobsson E., Eriksson G., and Rosen E. (1987) Activity-composition relations of magnesiowustite solid solution series in equilibrium with metallic iron in the temperature range 1050-1400 K. Phys. Chem. Minerals 14, 492-498.
90. Stebbins J. F. and Carmichael I. S. E. (1984) The heat of fusion of fayalite. Amer. Mineral. 69, 292-297.
91. Stolen S., Glockner R., Gronvold F., Atake T., and Izumisawa S. (1996) Heat capacity and thermodynamic properties of nearly stoichiometric wustite from 13 to 450 K. Amer. Mineral. 81, 973-981.
92. Sundman B. (1991) An assessment of the Fe-O system. J. Phase Equilibria 12, 127-140.
93. Sundman B. and Ågren J. (1981) A regular solution model for phase with several components and sublattices, suitable for computer applications, J. Phys. Chem. Solids 42, 297-301.
94. Sundman B., Jansson B., and Andersson J. -O. (1985) The Termo-Calc databank system. Calphad 9, 153-190.
95. Swamy V., Saxena S. K., Sundman B., and Zhang J. (1994) A thermodynamic assessment of silica phase diagram. J. Geophys. Res. 99, 11787-11794.
96. x) near the p to n transition. Trans. AIME 239, 1215-1218.
97. 4 and GaAs determined from shock-composition experiments. In High-pressure Research: Applications in Geophysics (ed M. H. Manghnani and S. Akimoto), pp. 463-476. Academic Press.
98. Tankins E. S., Gokcen N. A., and Belton G. R. (1964) The activity and solubility of oxygen in liquid iron, nickel and cobalt. Trans. AIME 230, 820-827.
99. Vallet P. and Raccah P. (1965) Thermodynamic properties of solid iron (II) oxide. Mem. Sci. Rev. Met. 62, 1-29.
100. 4) heat capacity and thermodynamic properties from 5 to 350 K, low-temperature transition. J. Chem. Thermodynamics 1, 543-557.
101. 3. In High-pressure Research in Geophysics (ed. S. Akimoto and M. H. Manghnani), pp. 81-90. Center for Academic Publ.
102. 4 using sinchrotron radiation. J. Geophys. Res. 92, 6207-6213.
103. 2 at 9-14 GPa. J. Geophys. Res. 98, 19785-19793.
104. Zhang J., Liu B., Untsumi W., and Liebermann R. C. (1996) In situ X-ray observations of coesite-stishovite transition: Reversed phase boundary and kinetics. Phys. Chem. Mineral. 23, 1-10.