Natural hydrous amorphous silica: Quantitation of network speciation and hydroxyl content by 29Si MAS NMR and vibrational spectroscopy

American Mineralogist

Volumn 97, Issue 1, 2012, Pages 203-211

  Chemtob, Steven M ^a   Rossman, George R ^a   Stebbins, Jonathan F ^b  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^b STANFORD UNIVERSITY   (United States)

Author keywords

Amorphous silica; IR spectroscopy; NMR spectroscopy; Raman spectroscopy

Indexed keywords

COATINGS; INFRARED SPECTROSCOPY; MAGIC ANGLE SPINNING; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; RAMAN SCATTERING; RAMAN SPECTROSCOPY; SILICA GEL; SILICATES; SILICON; SPECTROSCOPIC ANALYSIS; VIBRATIONAL SPECTROSCOPY;

AMORPHOUS SILICA; ATTENUATED TOTAL REFLECTANCE INFRARED; ELEVATED TEMPERATURE; MAGIC ANGLE SPINNING NMR; PARAMAGNETIC CENTERS; SPIN LATTICE RELAXATION RATES; STRETCHED EXPONENTIAL; VIBRATIONAL SPECTROSCOPIC METHODS;

SILICA;

AMORPHOUS MEDIUM; HYDROXYL RADICAL; INFRARED SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE; RAMAN SPECTROSCOPY; SILICA MINERAL; SPECIATION (CHEMISTRY);

HAWAII [(ISL) HAWAIIAN ISLANDS]; HAWAII [UNITED STATES]; HAWAIIAN ISLANDS; KILAUEA; UNITED STATES;

EID: 84856338342     PISSN: 0003004X     EISSN: 19453027     Source Type: Journal    
DOI: 10.2138/am.2012.3921     Document Type: Article

References (44)

1. 29Si high-resolution nuclear magnetic resonance. Journal of the American Ceramic Society, 88, 1514-1520. (Pubitemid 41557931)
2. Adams, S. J., Hawkes, G. E., and Curzon, E. H. (1991) A solid state 29Si nuclear magnetic resonance study of opal and other hydrous silicas. American Mineralogist, 76, 1863-1871.
3. Almeida, R. M. and Pantano, C. G. (1990) Structural investigation of silica gel films by infrared spectroscopy. Journal of Applied Physics, 68, 4225-4232.
4. Angeli, F., Gaillard, M., Jollivet, P., and Charpentier, T. (2006) Influence of glass composition and alteration solution on leached silicate glass structure: A solidstate NMR investigation. Geochimica et Cosmochimica Acta, 70, 2577-2590.
5. Bertoluzza, A., Fagnano, C., Morelli, M. A., Gottardi, V., and Guglielmi, M. (1982) Raman and infrared spectra on silica gel evolving toward glass. Journal of Non-Crystalline Solids, 48, 117-128.
6. Braunstein, D. and Lowe, D. R. (2001) Relationship between spring and geyser activity and the deposition and morphology of high temperature (>73 °C) siliceous sinter, Yellowstone National Park, Wyoming, U. S. A. Journal of Sedimentary Research, 71, 747-763.
7. 27Al NMR study of amorphous and paracrystalline opals from Australia. Journal of Non-Crystalline Solids, 332, 242-248.
8. Carroll, S. A., Maxwell, R. S., Bourcier, W., Martin, S., and Hulzey, S. (2002) Evaluation of silica-water surface chemistry using NMR spectroscopy. Geochimica et Cosmochimica Acta, 66, 913-926. (Pubitemid 38459275)
9. Champagnon, B., Panczer, G., and Chemarin, C. (1997) Differentiation of natural silica glasses using Raman microspectrometry. Chemie der Erde-Geochemistry, 57, 289-296. (Pubitemid 127616107)
10. Chemtob, S. M., Jolliff, B. L., Rossman, G. R., Eiler, J. M., and Arvidson, R. E. (2010) Silica coatings in the Ka'u Desert, Hawaii, a Mars analog terrain: A micromorphological, spectral, chemical and isotopic study. Journal of Geophysical Research, 115, E04001.
11. Davis, K. M. and Tomozawa, M. (1996) An infrared spectroscopic study of water-related species in silica glasses. Journal of Non-Crystalline Solids, 201, 177-198. (Pubitemid 126362879)
12. 29Si magic-angle-spinning NMR of opals: incoherent long-and short-range order in opal CT. American Mineralogist, 72, 1195-1203.
13. Devreux, F., Boilot, J. P., Chaput, F., and Sapoval, B. (1990) NMR determination of the fractal dimension in silica aerogels. Physical Review Letters, 65, 614-617.
14. Engelhardt, G. and Michel, D. (1987) High-Resolution Solid-State NMR of Silicates and Zeolites, 485 p. Wiley, New York.
15. Farr, T. G. and Adams, J. B. (1984) Rock coatings in Hawaii. GSA Bulletin, 95, 1077-1083.
16. Faye, G. H. and Miller, R. M. (1973) "Blue Dragon" basalt from Craters of the Moon National Monument, Idaho: origin of color. American Mineralogist, 58, 1048-1051.
17. Fulignati, P., Sbrana, A., Luperini, W., and Greco, V. (2002) Formation of rock coatings induced by the acid fumarole plume of the passively degassing volcano of La Fossa (Vulcano Island, Italy). Journal of Volcanology and Geothermal Research, 115, 397-410. (Pubitemid 34792321)
18. 29Si MAS NMR studies of the spin-lattice relaxation time and bond-angle distribution in vitreous silica. Philosophical Magazine, 53, L81-L87. (Pubitemid 16547124)
19. 29Si MAS-NMR study on some non-crystalline silica minerals. Journal of Non-Crystalline Solids, 119, 173-180. (Pubitemid 20698454)
20. Graetsch, H., Gies, H., and Topalovic, I. (1994) NMR, XRD and IR study on microcrystalline opals. Physics and Chemistry of Minerals, 21, 166-175.
21. 29Si NMR spin-lattice relaxation studies. Canadian Journal of Chemistry, 85, 56-65. (Pubitemid 46693205)
22. Ilieva, A., Mihailova, B., Tsintsov, Z., and Petrov, O. (2007) Structural state of microcrystalline opals: a Raman spectroscopic study. American Mineralogist, 92, 1325-1333.
23. Kamitsos, E. I., Patsis, A. P., and Kordas, G. (1993) Infrared-reflectance spectra of heat-treated, sol-gel-derived silica. Physical Review B, 48, 12499-12505.
24. 2O minerals. Fortschritte der Mineralogie, 52, 17-51.
25. Maciel, G. E. and Sindorf, D. W. (1980) Silicon-29 nuclear magnetic resonance study of the surface of silica gel by cross polarization and magic-angle spinning. Journal of the American Chemical Society, 102, 7606-7607.
26. MacKenzie, K. J. D. and Smith, M. E. (2002) Multinuclear Solid-State NMR of Inorganic Materials, 727 p. Pergamon, New York.
27. 29Si MAS-NMR. Journal of Non-Crystalline Solids, 127, 53-64.
28. Malfait, W. J. and Halter, W. E. (2008) Structural relaxation in silicate glasses and melts: High-temperature Raman spectroscopy. Physical Review B, 77, 014201.
29. Matos, M. C., Ilharco, L. M., and Almeida, R. M. (1992) The evolution of TEOS to silica gel and glass by vibrational spectroscopy. Journal of Non-Crystalline Solids, 147-148, 232-237. (Pubitemid 23589320)
30. McMillan, P. (1984) Structural studies of silicate glasses and melts-applications and limitations of Raman spectroscopy. American Mineralogist, 69, 622-644. (Pubitemid 15473400)
31. Minitti, M. E., Weitz, C. M., Lane, M. D., and Bishop, J. L. (2007) Morphology, chemistry, and spectral properties of Hawaiian rock coatings and implications for Mars. Journal of Geophysical Research, 112, E05015.
32. Monsivais-Gámez, E., Ruiz, F., and Martínez, J. R. (2007) Four-membered rings family in the Si-O extended rocking IR band from quantum chemistry calculations. Journal of Sol-Gel Science and Technology, 43, 65-72. (Pubitemid 46897457)
33. Morel, F. M. M. and Hering, J. G. (1993) Principles and Applications of Aquatic Chemistry, 588 p. Wiley, New York.
34. Mulder, C. A. M. and Damen, A. A. J. M. (1987) The origin of the "defect" 490 cm-1 Raman peak in silica gel. Journal of Non-Crystalline Solids, 93, 387-394.
35. Mysen, B. O. and Richet, P. (2005) Silicate Glasses and Melts, Properties and Structure, 544 p. Elsevier, Amsterdam.
36. 27Al NMR study of the destabilization process of a paracrystalline opal from Mexico. Journal of Non-Crystalline Solids, 353, 1650-1656. (Pubitemid 46601473)
37. 2 lifetime. Geophysical Research Letters, 29, 1783.
38. Rodgers, K. A., Cook, K. L., Browne, P. R. L., and Campbell, K. A. (2002) The mineralogy, texture and significance of silica derived from alteration by steam condensate in three New Zealand geothermal fields. Clay Minerals, 27, 299-322. (Pubitemid 34805822)
39. Rodgers, K. A. and Hampton, W. A. (2003) Laser Raman identification of silica phases comprising microtextural components of sinters. Mineralogical Magazine, 67, 1-13. (Pubitemid 36294805)
40. Schmidt, M., Botz, R., Rickert, D., Bohrmann, G., Hall, S. R., and Mann, S. (2001) Oxygen isotopes of marine diatoms and relations to opal-A maturation. Geochimica et Cosmochimica Acta, 65, 201-211. (Pubitemid 32223120)
41. Sindorf, D. W. and Maciel, G. E. (1982) Cross-polarization/magic-angle- spinning silicon-29 nuclear magnetic resonance study of silica gel using trimethylsilane bonding as a probe of surface geometry and reactivity. Journal of Physical Chemistry, 86, 5208-5219.
42. Stebbins, J. F. and McMillan, P. (1993) Compositional and temperature effects on five coordinated silicon in ambient pressure silicate glasses. Journal of Non-Crystalline Solids, 160, 116-125. (Pubitemid 23699805)
43. 29Si NMR results for chemical shift anisotropy, spin-lattice relaxation, and mechanism of hydration. American Mineralogist, 94, 905-915.
44. 2 deposited by remote plasmaenhanced chemical vapor deposition and incorporated by postdeposition exposure to water vapor. Journal of Vacuum Science and Technology A, 8, 1374-1381.