Sequential N-O and N-N bond cleavage of N-heterocyclic carbene-activated nitrous oxide with a vanadium complex

Journal of the American Chemical Society

Volumn 134, Issue 3, 2012, Pages 1471-1473

  Tskhovrebov, Alexander G ^a   Solari, Euro ^a   Wodrich, Matthew D ^a   Scopelliti, Rosario ^a   Severin, Kay ^a  

^a EPFL   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

BOND CLEAVAGES; BOND SCISSIONS; DINITROGEN; N-HETEROCYCLIC; N-HETEROCYCLIC CARBENES; NITROUS OXIDE; REACTION SEQUENCES; VANADIUM COMPLEXES;

ANESTHETICS; CARBON INORGANIC COMPOUNDS; NITROGEN OXIDES; ORGANIC COMPOUNDS;

VANADIUM COMPOUNDS;

CARBENE; NITROUS OXIDE; VANADIUM;

ARTICLE; ATOM; CHEMICAL BOND; CHEMICAL REACTION;

EID: 84856262926     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja210976a     Document Type: Article

References (45)

1. Dameris, M. Angew. Chem., Int. Ed. 2010, 49, 489-491
2. Wuebbels, D. J. Science 2009, 326, 56-57
3. Ravishankara, A. R.; Daniel, J. S.; Portmann, R. W. Science 2009, 326, 123-125
4. Leont'ev, A. V.; Fomicheva, O. A.; Proskurnina, M. V.; Zefirov, N. S. Russ. Chem. Rev. 2001, 70, 91-104
5. Panov, G. I.; Dubkov, K. A.; Kharitonov, A. S. In Modern Heterogeneous Oxidation Catalysis; Noritaka, M., Ed.; Wiley-VCH: Weinheim, Germany, 2009; pp 217-252.
6. Parmon, V. N.; Panov, G. I.; Noskov, A. S. Catal. Today 2005, 100, 115-131
7. Tolman, W. B. Angew. Chem., Int. Ed. 2010, 49, 1018-1024
8. Lee, D.-H.; Mondal, B.; Karlin, K. D. In Activation of Small Molecules; Tolman, W. B., Ed.; Wiley-VCH, Weinheim, Germany, 2006; pp 43-79.
9. Pomowski, A.; Zumft, W. G.; Kroneck, P. M. H.; Einsle, O. Nature 2011, 477, 234-237
10. Piro, N. A.; Lichterman, M. F.; Harman, W. H.; Chang, C. J. J. Am. Chem. Soc. 2011, 133, 2108-2111
11. Demir, S.; Montalvo, E.; Ziller, J. W.; Meyer, G.; Evans, W. J. Organometallics 2010, 29, 6608-6611
12. Laban, T.; Mandel, A.; Magull, J. Z. Anorg. Allg. Chem. 1999, 625, 1273-1277
13. Vaughan, G. A.; Sofield, C. D.; Hillhouse, G. L. J. Am. Chem. Soc. 1989, 111, 5491-5493
14. Reeds, J. O.; Yonke, B. L.; Zavalij, P. Y.; Sita, L. R. J. Am. Chem. Soc. 2011, 133, 18602-18605
15. Cherry, J.-P. F.; Johnson, A. R.; Baraldo, L. M.; Tsai, Y.-C.; Cummins, C. C.; Kryatov, S. V.; Rybak-Akimova, E. V.; Capps, K. B.; Hoff, C. D.; Haar, C. M.; Nolan, S. P. J. Am. Chem. Soc. 2001, 123, 7271-7286
16. Johnson, A. R.; Davis, W. M.; Cummins, C. C.; Serron, S.; Nolan, S. P.; Musaev, D. G.; Morokuma, K. J. Am. Chem. Soc. 1998, 120, 2071-2085
17. Laplaza, C. E.; Odom, A. L.; Davis, W. M.; Cummins, C. C. J. Am. Chem. Soc. 1995, 117, 4999-5000
18. Tskhovrebov, A. G.; Solari, E.; Wodrich, M. D.; Scopelliti, R.; Severin, K. Angew. Chem., Int. Ed. 2012, 51, 232-234
19. Bartsch, R. A.; Chae, Y. M.; Ham, S.; Birney, D. M. J. Am. Chem. Soc. 2001, 123, 7479-7486
20. Rehse, K.; Brümmer, U.; Unsöld, E. Pharmazie 1998, 53, 820-824
21. Akiba, K.-y.; Matsunami, S.; Eguchi, C.; Inamato, N. Bull. Chem. Soc. Jpn. 1994, 47, 935-937
22. Thoman, C. J.; Hunsberger, I. M. J. Org. Chem. 1968, 33, 2852-2857
23. Neu, R. C.; Otten, E.; Lough, A.; Stephan, D. W. Chem. Sci 2011, 2, 170-176
24. Neu, R. C.; Otten, E.; Stephan, D. W. Angew. Chem., Int. Ed. 2009, 48, 9709-9712
25. Otten, E.; Neu, R. C.; Stephan, D. W. J. Am. Chem. Soc. 2009, 131, 9918-9919
26. Vivanco, M.; Ruiz, J.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Organometallics 1993, 12, 1794-1801
27. Seidel, W.; Kreisel, G. Z. Anorg. Allg. Chem. 1977, 435, 146-152
28. Seidel, W.; Kreisel, G. Z. Chem. 1974, 14, 25
29. Vivanco, M.; Ruiz, J.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Organometallics 1993, 12, 1802-1810
30. Ruiz, J.; Vivanco, M.; Floriani, C.; Chiesi-Villa, A.; Guastini, C. Chem. Commun. 1991, 762-764
31. Odom, A. L.; Cummins, C. C. J. Am. Chem. Soc. 1995, 117, 6613-6614
32. Tsai, Y.-C.; Wang, P.-Y.; Lin, K.-M.; Chen, S.-A.; Chen, J.-M. Chem. Commun. 2008, 205-207
33. Cummins, C. C.; Schrock, R. R.; Davis, W. M. Inorg. Chem. 1994, 33, 1448-1457
34. Bottomley, F.; Darkwa, J. J. Chem. Soc., Dalton Trans. 1988, 2505-2506
35. Bottomley, F.; Darkwa, J. J. Chem. Soc., Dalton Trans. 1983, 399-400
36. Bottomley, F.; White, P. S. J. Chem. Soc., Chem. Commun. 1981, 28-29
37. Bultitude, J.; Larkworthy, L. F.; Povey, D. C.; Smith, G. W.; Dilworth, J. R.; Leigh, G. J. J. Chem. Soc., Chem. Commun. 1986, 1748-1750
38. Kopka, K.; Mattes, R. Z. Naturforsch. 1996, 51b, 1675-1678
39. Woitha, C.; Behrens, U.; Vergopoulos, V.; Rehder, D. J. Organomet. Chem. 1990, 393, 97-109
40. Hammerl, A.; Klapötke, T. M.; Nöth, H.; Marchhold, M.; Holl, G.; Kaiser, M.; Ticmanis, U. Inorg. Chem. 2001, 40, 3570-3585
41. Batsanov, A. S.; Goeta, A. E.; Howard, J. A. K.; Hughes, A. K.; Malget, J. M. J. Chem. Soc., Dalton Trans. 2001, 1820-1826
42. Toda, F.; Hyoda, S.; Okada, K.; Hirotsu, K. J. Chem. Soc., Chem. Commun. 1995, 1531-1532
43. Zhang, S.; Tamm, M.; Nomura, K. Organometallics 2011, 30, 2712-2720
44. Zhang, S.; Nomura, K. J. Am. Chem. Soc. 2010, 132, 4960-4965
45. Chang, K.-C.; Lu, C.-F.; Wang, P.-Y.; Lu, D.-Y.; Chen, H.-Z.; Kuo, T.-S.; Tsai, Y.-C. Dalton Trans. 2011, 40, 2324-2331