Synthesis and characterization of superfine pure tetragonal nanocrystalline sulfated zirconia powder by a non-alkoxide sol-gel route

Advanced Powder Technology

Volumn 23, Issue 1, 2012, Pages 80-87

  Heshmatpour, Felora ^a   Aghakhanpour, Reza Babadi ^a  

^a K N TOOSI UNIVERSITY OF TECHNOLOGY   (Iran)

Author keywords

Nanocrystalline; Non alkoxide sol gel; Pure tetragonal; Sulfated zirconia

Indexed keywords

ACIDIC CONDITIONS; CRYSTAL PHASE; FIELD EMISSION SCANNING ELECTRON MICROSCOPES; FOURIER TRANSFORM INFRARED; NANOCRYSTALLINES; PURE TETRAGONAL; SMALL SIZE; SOL-GEL ROUTES; SULFATE SPECIES; SULFATED ZIRCONIA; SULFATING AGENTS; TETRAGONAL PHASE; TRANSMISSION ELECTRON MICROSCOPE;

CALCINATION; CRYSTALLITE SIZE; GELS; NANOCRYSTALLINE POWDERS; OPTICAL PROPERTIES; PHOTOLUMINESCENCE SPECTROSCOPY; SCANNING ELECTRON MICROSCOPY; SOL-GEL PROCESS; SOL-GELS; SOLS; TRANSMISSION ELECTRON MICROSCOPY; X RAY DIFFRACTION; X RAY DIFFRACTION ANALYSIS; ZIRCONIUM;

ZIRCONIA;

EID: 84856098376     PISSN: 09218831     EISSN: 15685527     Source Type: Journal    
DOI: 10.1016/j.apt.2010.12.012     Document Type: Article

References (53)

1. M.B. Reddy, and K.P. Meghshyam Organic syntheses and transformations catalyzed by sulfated zirconia Chem. Rev. 109 6 2009 2185 2208
2. S. Tominaka, N. Akiyama, F. Croce, T. Momma, B. Scrosati, and T. Osaka Sulfated zirconia nanoparticles as a proton conductor for fuel cell electrodes J. Power Sources 185 2008 656 663
3. F. Schmidt New catalyst preparation technologies observed from an industrial viewpoint Appl. Catal. A: Gen. 221 2001 15 21 (Pubitemid 34524098)
4. D.A. Ward, and E.I. Ko One step synthesis and characterization of zirconia -sulfate aerogels as solid super acids J. Catal. 150 1994 18 33
5. D.A. Ward, and E.I. Ko Sol-gel synthesis of zirconia supports - important properties for generating N-butane isomerization activity upon sulfate promotion J. Catal. 157 1995 321 333
6. H. Armendariz, B. Coq, D. Tichit, R. Dutartre, and F. Figueras Influences of some synthesis parameters and activation procedures on the one-step sol-gel synthesis of sulfated-zirconia catalysts, followed by TG-DSC and mass spectrometry J. Catal. 173 1998 345 354
7. C.L. Bianchi, S. Ardizzone, and G. Cappelletti The role of the sol-gel parameters Surf. Interface Anal. 36 2004 745 748
8. 2 catalysts for n-butane isomerization Appl. Catal. A: Gen. 230 2002 137 151 (Pubitemid 34284591)
9. E.E. Platero, M.P. Mentruit, C.O. Arean, and A. Zecchina 'FTIR studies on the acidity of sulfated zirconia prepared by thermolysis of zirconium sulfate J. Catal. 162 1996 268 276
10. R. Barthos, F. Lonyi, J. Engelhardt, and J. Valyon A study of the acidic and catalytic properties of pure and sulfated zirconia-titania and zirconia-silica mixed oxides Top. Catal. 10 2000 79 87
11. G. Resofski, M. Muhler, S. Sprenger, U. Wild, and Z. Paal Electron spectroscopy of sulfated zirconia, Its activity in n-hexane conversion and possible reasons of its deactivation Appl. Catal. A: Gen. 240 2003 71 81
12. 2 obtained by sol-gel process Stud. Surf. Sci. Catal. 143 2002 1045 1052
13. A. Zarubica, and P. Putanov Content of sulfates and their stability-key factors determining the catalytic activity of sulfated zirconia catalysts J. Chem. Serb. Soc. 72 7 2007 679 686
14. V.C.F. Holm, G. C. Bailey, US Pat., 3 032 599, 1962.
15. M. Hino, S. Kobayashi, and K. Arata Reactions of butane and isobutane catalyzed by zirconium oxide treated with sulfate ion. Solid superacid catalyst J. Am. Chem. Soc. 101 1979 6439 6441
16. M. Hino, and K. Arata Synthesis of solid acid catalysts with acid strength of H0>-16.04J Chem. Soc. Chem. Commun. 18 1980 851 852
17. 2 modified with sulfur compounds J. Mol. Catal. 52 1989 361 368
18. A. Minesso, F. Genna, T. Finotto, A. Baldan, and A. Benedetti Synthesis and characterisation of sulfated zirconia sol-gel systems J. Sol-Gel Sci. Technol. 24 2002 197 206 (Pubitemid 34630639)
19. 3 J. Catal. 238 2006 39 45 (Pubitemid 43112440)
20. 2 for n-butane isomerization Top. Catal. 6 1998 101 106
21. 3-promoted sulfated zirconia systems: morphological, structural and redox properties Microporous Mesoporous Mater. 81 2005 19 29
22. 2- J. Catal. 131 1991 199 203
23. C.Y. Hsu, C.R. Heimbuch, C.T. Armes, and B.C. Gates A highly active solid superacid catalyst for n-butane isomerization: a sulfated oxide containing iron, manganese and zirconium J. Chem. Soc. Chem. Comm. 22 1992 1645 1646
24. T. Jin, T. Yamaguchi, and K. Tanabe Mechanism of acidity generation on sulfur-promoted metal oxides J. Phys. Chem. 90 1986 4794 4796
25. T. Yamaguchi, T. Jin, and K. Tanabe Structure of acid sites on sulfur-promoted iron oxide J. Phys. Chem. 90 1986 3148 3152
26. F.R. Chen, G. Coudurier, J.F. Joly, and J.C. Vedrine Superacid and catalytic properties of sulfated zirconia J. Catal. 143 1993 616 626
27. M.A. Ecormier, K. Wilson, and A.F. Lee Structure-reactivity correlations in sulphated zirconia catalysts for the isomerization of a-pinene J. Catal. 215 2003 57 65
28. R.C. Garvie, and M.F. Goss Intrinsic size dependence of the phase transformation temperature on zirconia microcrystals J. Mater. Sci. 21 1986 1253 1257 (Pubitemid 16520300)
29. R.C. Garvie The occurrence of metastable tetragonal zirconia as a crystallite size effect J. Phys. Chem. 69 1965 1238 1243
30. C. Morterra, G. Poncelet, F. Pinna, and M. Signoretto Crystal phase, spectral features, and catalytic activity of sulfated-doped zirconia systems J. Catal. 157 1995 109 123
31. J.A. Moreno, and G. Poncelet Isomerization of n-butane over sulfated Al- and Ga-promoted zirconium oxide catalysts J. Catal. 203 2001 453 465
32. R. Srinivasan, T.R. Watkins, C.R. Hubbard, and B.H. Davis Sulfated zirconia catalysts: the crystal phases and their transformations Chem. Mater. 7 1995 725 730
33. L. Ben hamouda, and A. Ghorbel Sol-gel preparation of highly active sulfated zirconia supported by alumina catalysts J. Sol-Gel Sci. Technol. 26 2003 831 836
34. M.G. Cutrufello, U. Diebold, and R.D. Gonzalez Optimization of synthesis variables in the preparation of active sulfated zirconica catalysts Catal. Lett. 101 2005 5 13
35. 1H-MAS-NMR J. Chem. Soc. Chem. Commun. 10 1994 1181 1182
36. M.K. Mishra, B. Tyagi, and R.V. Jasra Synthesis and characterization of nano-crystalline sulfated zirconia by sol-gel method J. Mol. Catal. A: Chem. 223 2004 61 65
37. M.K. Mishra, B. Tyagi, and R.V. Jasra Effect of synthetic parameters on structural, textural, and catalytic properties of nanocrystalline sulfated zirconia prepared by sol-gel technique Ind. Eng. Chem. Res. 42 23 2003 5727 5736 (Pubitemid 37363097)
38. B.D. Cullity, S.R. Stock, Elements of X-ray diffraction, Prentice Hal1, Englewood Cliffs, 2001.
39. Tetragonal JCPDS No. 70-1769.
40. B. Tyagi, K. Sidhpuria, B. Shaik, and R.V. Jasra Synthesis of nanocrystalline zirconia using sol-gel and precipitation techniques Ind. Eng. Chem. Res. 45 2006 8643 8650 (Pubitemid 46057415)
41. J.A. Wang, M.A. Valenzyela, J. Salmons, A. Vazquez, A. Garcia-Ruiz, and X. Bokhimi Comparative study of nanocrystalline zirconia prepared by precipitation and sol-gel methods Catal. Today 68 2001 21 30 (Pubitemid 32746127)
42. F. Namavar, G. Wang, C.L. Cheung, R.F. Sabirianov, X.C. Zeng, W.N. Mei, J. Bai, J.R. Brewer, H. Haider1, and K.L. Garvin Thermal stability of nanostructurally stabilized zirconium oxide Nanotechnology 18 2007 415702 415707
43. J. Livage, M. Henry, and C. Sanchez Sol-gel chemistry of transition metal oxides Progr. Solid State Chem. 18 1988 259 341
44. B. Himmel, T. Gerber, and H. Burger X-ray diffraction investigations of silica gel structures J. Non-Cryst. Solids 91 1987 122 136 (Pubitemid 17568868)
45. G.Y. Guo, Yu-Li Chen, and W.J. Ying Thermal, spectroscopic and X-ray diffractional analyses of zirconium hydroxides precipitated at low pH values Mater. Chem. Phys. 84 2004 308 314
46. S. Chen, Y. Yin, D. Wang, Y. Liu, and X. Wang Structures, growth modes and spectroscopic properties of small zirconia clusters J. Cryst. Growth 282 2005 498 505 (Pubitemid 41085147)
47. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, fourth ed., John Wiley, New York, 1986, Chapter 2.
48. M. Salavati-Niasari, M. Dadkhah, and F. Davar Synthesis and characterization of pure cubic zirconium oxide nanocrystals by decomposition of bis-aqua, tris-acetylacetonato zirconium(IV) nitrate as new precursor complex Inorg. Chim. Acta 362 2009 3969 3974
49. 2 nanoparticles by thermolysis of a new precursor Polyhedron 28 2009 3005 3009
50. 3+ microspheres: solvothermal synthesis and luminescence properties Cryst. Growth Des. 7 2007 730 735
51. J. Petry, W. Vandervorst, and T. Conard The band structure of ALCVD AlZr- and AlHf-oxides as measured by XPS Mater. Sci. Eng. B 109 2004 56 59
52. 2 nanoparticles Solid State Sci. 9 2007 1105 1109 (Pubitemid 350198961)
53. J. Joo, T. Yu, Y.W. Kim, H.M. Park, F. Wu, J.Z. Zhang, and T. Hyeon Multigram scale synthesis and characterization of monodisperse tetragonal zirconia nanocrystal J. Am. Chem. Soc. 125 2003 6553 6557 (Pubitemid 36605422)