Molar mass characterization of cellulose acetates over a wide range of high DS by size exclusion chromatography with multi-angle laser light scattering detection

Carbohydrate Polymers

Volumn 88, Issue 1, 2012, Pages 96-102

  Ghareeb, Hewa Othman ^a   Malz, Frank ^a   Kilz, Peter ^b   Radke, Wolfgang ^a  

^a FRAUNHOFER INSTITUTE FOR STRUCTURAL DURABILITY AND SYSTEM RELIABILITY LBF   (Germany)

^b Polymer Standards Service GmbH   (Germany)

Author keywords

Cellulose acetate; Degree of substitution; Light scattering; Molar mass characterization; Size exclusion chromatography

Indexed keywords

AVERAGE DEGREE; AVERAGE MOLAR MASS; CALIBRATION CURVES; CELLULOSE ACETATES; CORRECTION FACTORS; DEACETYLATION; DEGREE OF SUBSTITUTION; ELUTION VOLUMES; LITHIUM CHLORIDE; MOLAR MASS DISTRIBUTION; MULTIANGLE LASER LIGHT SCATTERING; SIZE EXCLUSION; SODIUM HYDROXIDES;

ACETYLATION; CALIBRATION; CELLULOSE; CHLORINE COMPOUNDS; LIGHT SCATTERING; LITHIUM; MOLAR MASS; SCATTERING; SODIUM; VOLATILE FATTY ACIDS;

SIZE EXCLUSION CHROMATOGRAPHY;

EID: 84855983711     PISSN: 01448617     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.carbpol.2011.11.071     Document Type: Article

References (36)

1. W.J. Alexander, and T.E. Muller Evaluation of pulps, rayon fibers, and cellulose acetate by GPC and other fractionation methods Separation Science 6 1 1971 47 71
2. C. Aparecida da Silva, M. Maria Favaro, I.V. Pagotto Yoshida, and M. do Carmo Gonalves Nanocomposites derived from cellulose acetate and highly branched alkoxysilane Journal of Applied Polymer Science 121 5 2011 2559 2566
3. M.G.D. Baumann, and A.H. Conner Carbohydrate polymers as adhesives 2003 Marcel Dekker New York
4. H. Benoît, Z. Grubisic, P. Rempp, D. Decker, and J.G. Zilliox Liquid-phase chromatographic study of branched and linear polystyrenes of known structure Journal of Chemical Physics 63 11-12 1966 1507 1514
5. S.A. Berkowitz Specific refractive index increment measurements on macromolecules using a waters R401 differential refractometer Journal of Liquid Chromatography 6 8 1983 1359 1373
6. K.J. Edgar Cellulose esters in drug delivery Cellulose 14 1 2007 49 64 (Pubitemid 46486880)
7. K.J. Edgar, C.M. Buchanan, J.S. Debenham, P.A. Rundquist, B.D. Seiler, and M.C. Shelton Advances in cellulose ester performance and application Progress in Polymer Science 26 9 2001 1605 1688 (Pubitemid 33090644)
8. W.L. Elsdon, J.M. Goldwasser, and A. Rudin Concentration effects in the gel permeation chromatography of broad distribution polymers Journal of Polymer Science Polymer Letters Edition 19 10 1981 483 493
9. B. Fleury, J. Dubois, C. Léonard, J.P. Joseleau, and H. Chanzy Microgels and ionic associations in solutions of cellulose diacetate Cellulose 1 2 1994 131 144
10. Y. Funaki, K. Ueda, S. Saka, and S. Soejima Characterization of cellulose acetate in acetone solution. Studies on prehump II in GPC pattern Journal of Applied Polymer Science 48 3 1993 419 424 (Pubitemid 23622644)
11. V.W. Goodlett, J.T. Dougherty, and H.W. Patton Characterization of cellulose acetates by nuclear magnetic resonance Journal of Polymer Science Part A-1 9 1 1971 155 161
12. Z. Grubisic, P. Rempp, and H. Benoît A universal calibration for gel permeation chromatography Journal of Polymer Science Part B: Polymer Letters 5 9 1967 753 759
13. L.A. Hiller JR The reaction of cellulose acetate with acetic acid and water Journal of Polymer Science Part A-1 10 4 1953 385 423
14. F. Howlett, and E. Martin Study of the rate of saponification of cellulose acetates Journal of the Textile Institute Transactions 38 4 1947 T212 T225
15. K. Kamide, Y. Miyazaki, and T. Abe Dilute solution properties and unperturbed chain dimension of cellulose triacetate Polymer Journal 11 7 1979 523 538 (Pubitemid 10407319)
16. K. Kamide, K. Okajima, K. Kowsaka, and T. Matsui Solubility of cellulose acetate prepared by different methods and its correlationships with average group distribution on glucopyranose units Polymer Journal 19 12 1987 1405 1412 (Pubitemid 18562953)
17. K. Kamide, M. Saito, and T. Abe Dilute solution properties of water-soluble incompletely substituted cellulose acetate Polymer Journal 13 5 1981 421 431 (Pubitemid 12425684)
18. B. Kosan, S. Dorn, F. Meister, and T. Heinze Preparation and subsequent shaping of cellulose acetates using ionic liquids Macromolecular Materials and Engineering 295 7 2010 676 681
19. R.C. Law Cellulose acetate in textile application Macromolecular Symposia 208 1 2004 255 265
20. S.-J. Lee, C. Altaner, J. Puls, and B. Saake Determination of the substituent distribution along cellulose acetate chains as revealed by enzymatic and chemical methods Carbohydrate Polymers 54 3 2003 353 362
21. J. Li, L.-P. Zhang, F. Peng, J. Bain, T.-Q. Yuan, and F. Xu Microwave-assisted solvent-free acetylation of cellulose with acetic anhydride in the presence of iodine as a catalyst Molecules 14 9 2009 3551 3566
22. R. Mahendran, R. Malaisamy, and D. Mohan Cellulose acetate and epoxy resin blend ultrafiltration membranes: Preparation, characterization and application Journal of Macromolecular Science, Part A: Pure and Applied Chemistry 39 9 2002 1025 1035
23. F. Mahmud, and E. Catterall Fractionation and characterization of commercial cellulose triacetate by gel permeation chromatography ACS Symposium Series 245 1984 365 375 (Pubitemid 15535918)
24. C.J. Malm, R.E. Glegg, J.T. Salzer, D.F. Ingerick, and L.J. Tanghe Hydrolysis of cellulose esters Industrial & Engineering Chemistry Process Design and Development 5 1 1966 81 87
25. S. Mori Correction method for a concentration effect in the calculation of molecular weight averages from GPC chromatograms Journal of Applied Polymer Science 20 8 1976 2157 2164
26. S. Mori Calibration of size exclusion chromatography columns for determination of polymer molecular weight distribution Analytical Chemistry 53 12 1981 1813 1818 (Pubitemid 12438222)
27. M.C.V. Nagel, and T. Heinze Esterification of cellulose with acyl-1H-benzotriazole Polymer Bulletin 65 9 2010 873 881
28. N. Olaru, and L. Olaru Cellulose acetate deacetylation in benzene/acetic acid/water systems Journal of Applied Polymer Science 94 5 2004 1965 1968 (Pubitemid 39543360)
29. M. Peres de Paula, T.M. Lacerda, and E. Frollini Sisal cellulose acetates obtained from heterogeneous reactions Express Polymer Letters 2 6 2008 423 428
30. M. Saito Viscometric and light scattering study on dilute solution properties of cellulose acetate with a degree of substitution of 1.75 Polymer Journal 15 3 1983 249 253
31. E. Samios, R.K. Dart, and J.V. Dawkins Preparation, characterization and biodegradation studies on cellulose acetates with varying degrees of substitution Polymer 38 12 1997 3045 3054
32. J.E. Sealey, G. Samaranayake, J.G. Todd, and W.G. Glasser Novel cellulose derivatives. IV. Preparation and thermal analysis of waxy esters of cellulose Journal of Polymer Science Part B: Polymer Physics 34 9 1996 1613 1620 (Pubitemid 126599367)
33. M.S. Song, G.X. Hu, X.Y. Li, and B. Zhao Study on the concentration effects in size exclusion chromatography. VII. A quantitative verification for the model theory of concentration and molecular mass dependences of hydrodynamic volumes for polydisperse polymers Journal of Chromatography A 961 2 2002 155 170 (Pubitemid 34761915)
34. L.J. Tanghe, W.J. Rebel, and R.J. Brewer Prehump in the gel-permeation chromatography fractionation of pulp cellulose acetate Journal of Polymer Science Part A-1 8 10 1970 2935 2947
35. T.I. Usmanov, Y.T. Tashpulatov, F.T. Abdullaev, and A.Z. Sultanov Investigation by PMR spectroscopy of the reactivities of the acetate groups in the saponification of polysaccharide triacetates Chemistry of Natural Compounds 33 5 1997 530 533
36. J. Wu, J. Zhang, H. Zhang, J. He, Q. Ren, and M. Guo Homogeneous acetylation of cellulose in a new ionic liquid Biomacromolecules 5 2 2004 266 268 (Pubitemid 38404459)