Mechanism and regioselectivity of the electrochemical reduction in polychlorobiphenyls (PCBs): Kinetic analysis for the successive reduction of chlorines from dichlorobiphenyls

Journal of Physical Chemistry C

Volumn 116, Issue 1, 2012, Pages 655-664

  Muthukrishnan, A ^a,c   Boyarskiy, Vadim ^b   Sangaranarayanan, M V ^a   Boyarskaya, Irina ^b  

^a INDIAN INSTITUTE OF TECHNOLOGY MADRAS   (India)

^b ST PETERSBURG STATE UNIVERSITY   (Russian Federation)

^c NATIONAL TAIWAN UNIVERSITY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

ANALYSIS OF THE PRODUCT; BOND REDUCTIONS; BOND-BREAKING; BULK ELECTROLYSIS; BUTLER-VOLMER KINETICS; DICHLOROBIPHENYLS; DRIVING FORCES; ELECTROCHEMICAL REDUCTIONS; ELECTRON-TRANSFER STEP; EXPERIMENTAL DATA; HETEROGENEOUS RATE CONSTANT; INTRINSIC BARRIERS; KINETIC ANALYSIS; MARCUS-HUSH; POLYCHLOROBIPHENYLS; POTENTIAL SWEEP VOLTAMMETRY; QUANTUM CHEMICAL CALCULATIONS; REGIO-SELECTIVE; THEORETICAL CALCULATIONS; TRANSFER COEFFICIENT;

BOND LENGTH; CHEMICAL ANALYSIS; ELECTROLYTIC REDUCTION; POLYCHLORINATED BIPHENYLS; QUANTUM CHEMISTRY; RATE CONSTANTS; REGIOSELECTIVITY;

CHLORINE;

EID: 84855885864     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp2066474     Document Type: Article

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