Syntheses, structures and magnetic properties of two 2D lanthanide-copper complexes with an unprecedented μ7-EDTA coordination mode

Inorganic Chemistry Communications

Volumn 16, Issue , 2012, Pages 28-32

  Hu, Shengmin ^a   Sheng, Tianlu ^a   Wen, Yuehong ^a   Fu, Ruibiao ^a   Wu, Xintao ^a  

^a FUJIAN INSTITUTE OF RESEARCH ON THE STRUCTURE OF MATTER   (China)

Author keywords

Copper; Crystal structure; EDTA; Lanthanide; Magnetic properties

Indexed keywords

EID: 84855656591     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2011.11.022     Document Type: Article

References (47)

1. A. Bencini, C. Benelli, A. Caneschi, R.L. Carlin, A. Dei, and D. Gatteschi Crystal and molecular structure of and magnetic coupling in two complexes containing gadolinium(III) and copper(II) ions J. Am. Chem. Soc. 107 1985 8128 8136
2. R.E.P. Winpenny The structures and magnetic properties of complexes containing 3d- and 4f-metals Chem. Soc. Rev. 27 1998 447 452
3. Y. Liang, R. Cao, W. Su, M. Hong, and W. Zhang Syntheses, structures, and magnetic properties of two gadolinium(III)-copper(II) coordination polymers by a hydrothermal reaction Angew. Chem. Int. Ed. 39 2000 3304 3307
4. A.J. Blake, R.O. Gould, C.M. Grant, P.E.Y. Milne, S. Parsons, and R.E.P. Winpenny Heterometallic complexes containing d- and f-block elements: synthesis and structural characterisation of novel Ni-Er and Co-Dy compounds J. Chem. Soc. Dalton Trans. 1997 1665 1666
5. 3Gd complexes Chem. Eur. J. 1 1995 614 618
6. 3COO) Inorg. Chem. 39 2000 165 168
7. III couple? 2. Structures and magnetic properties of novel trinuclear complexes with μ-phenolato-μ- oximato (Cu-Ln-Cu) cores (Ln = La, Ce, Gd) Inorg. Chem. 39 2000 5994 6000 (Pubitemid 32061739)
8. Q.-Y. Chen, Q.-H. Luo, Z.-L. Wang, and J.-T. Chen Synthesis and crystal structure of the first d-f heterodinuclear Dy(III)-Cu(II) cryptate Chem. Commun. 2000 1033 1034 (Pubitemid 30415139)
9. N. Sakagami, and K. Okamoto Novel discrete structure of oxalate-bridged heteronuclear Cr(III)-Nd(III) complex Chem. Lett. 27 1998 201 202
10. S. Decurtins, M. Gross, H.W. Schmalle, and S. Ferlay Molecular chromium(III)-lanthanide(III) compounds (Ln = La, Ce, Pr, Nd) with a polymeric, ladder-type architecture: a structural and magnetic study Inorg. Chem. 37 1998 2443 2449 (Pubitemid 128487895)
11. A.D. Cutland, R.G. Malkani, J.W. Kampf, and V.L. Pecoraro Lanthanide [15]metallacrown-5 complexes form nitrate-selective chiral cavities Angew. Chem. Int. Ed Engl. 39 2000 2689 2692 (Pubitemid 30629187)
12. 3}•S (Ln = Lanthanide element; opba = ortho-phenylenebis(oxamato), S = solvent molecules) Inorg. Chem. 38 1999 3692 3697
13. T. Sanada, T. Suzuki, and S. Kaizaki Heterotrinuclear complexes containing d- and f-block elements: synthesis and structural characterisation of novel lanthanide(III)-nickel(II)-lanthanide(III) compounds bridged by oxamidate J. Chem. Soc. Dalton Trans. 1998 959 966
14. B.-Q. Ma, S. Gao, G. Su, and G.-X. Xu Cyano-bridged 4f-3d coordination polymers with a unique two-dimensional topological architecture and unusual magnetic behavior Angew. Chem. Int. Ed Engl. 40 2001 434 437 (Pubitemid 32114896)
15. 3 Chem. Lett. 24 1995 887 888 (Pubitemid 126009123)
16. 8 Inorg. Chem. 37 1998 6186 6191 (Pubitemid 128489905)
17. 2O J. Chem. Soc. Dalton Trans. 1999 2005 2008
18. Y. Cui, G. Cheng, J. Ren, Y.-T. Qian, and J.-S. Huang Syntheses, structures and magnetic behaviors of Di- and trinuclear pivalate complexes containing both cobalt(II) and lanthanide(III) ions Inorg. Chem. 39 2000 4165 4168
19. 4Tb clusters J. Am. Chem. Soc. 120 1998 209 210 (Pubitemid 28046449)
20. J.-J. Zhang, S.-M. Hu, L.-M. Zheng, X.-T. Wu, Z.-Y. Fu, J.-C. Dai, W.-X. Du, H.-H. Zhang, and R.-Q. Sun Synthesis and characterization of a series of novel heptanuclear trigonal-prismatic polyhedra with different edge-ligands Chem. Eur. J. 8 2002 5742 5749
21. 2 bridge Chem. Commun. 2004 1186 1187 (Pubitemid 38801466)
22. 24 cluster node Chem. Eur. J. 10 2004 3963 3969
23. 2] glycinato blade fragments J. Am. Chem. Soc. 129 2007 15144 15146 (Pubitemid 350247797)
24. X.-J. Kong, Y.-P. Ren, W.-X. Chen, L.-S. Long, Z.-P. Zheng, R.-B. Huang, and L.-S. Zheng A four-shell, nesting doll-like 3d-4f cluster containing 108 metal ions Angew. Chem. Int. Ed. 47 2008 2398 2401
25. H.-B. Cui, B. Zhou, L.-S. Long, Y. Okano, H. Kobayashi, and A. Kobayashi A porous coordination-polymer crystal containing one-dimensional, water chains exhibits guest-induced lattice distortion and a dielectric anomaly Angew. Chem. Int. Ed. 47 2008 3376 3380
26. X.-J. Kong, Y.-P. Ren, L.-S. Long, Z.-P. Zheng, R.-B. Huang, and L.-S. Zheng A. Keplerate, Magnetic cluster featuring an icosidodecahedron of Ni(II) ions, encapsulating a dodecahedron of La(III) ions J. Am. Chen. Soc. 129 2007 7016 7017 (Pubitemid 46903265)
27. 3NTA = nitrilotriacetic acid) coordination polymers: crystal structure and magnetic properties Polyhedron 21 2002 1097 1103
28. Y. Yamada, M. Tanabe, Y. Miyashita, and K. Okamoto Oxalato-bridged di- and trinuclear Co(III)-Dy(III) complexes derived from mononuclear Co(III) complex with nitrilotriacetate Polyhedron 22 2003 1455 1459
29. H.-Z. Kou, Y.-B. Jiang, and A.-L. Cui Two-dimensional coordination polymers exhibiting antiferromagnetic Gd(III)-Cu(II) coupling Cryst. Growth Des. 5 2005 77 79 (Pubitemid 40169722)
30. n Inorg. Chem. 48 2009 6326 6328
31. 2O (Ln = Nd, Gd; M = Mn, Co) Polyhedron 17 1998 2243 2248 (Pubitemid 128350995)
32. 2O J. Chem. Cryst. 30 2000 163 166 (Pubitemid 33216889)
33. 4CDTA = trans-1,2-cyclohexanedinitrilotetraacetic acid) J. Chem. Soc. Dalton Trans. 2000 1003 1004
34. X.-J. Kong, H. Zhang, H.-X. Zhao, Y.-P. Ren, L.-S. Long, Z.-P. Zheng, G.S. Nichol, R.-B. Huang, and L.-S. Zheng Framework solids possessing both hydrophobic and hydrophilic pores constructed by face-sharing Keplerate-Type heterometal-organic polyhedra Chem. Eur. J. 16 2010 5292 5296
35. n Acta Chim. Sin. 54 1996 795 801
36. 2O}n complexes Acta Chim. Sin. 49 1991 569 575
37. 2O (M,M′ = Zn, Zn; Zn-Co; Co, Co; or Mn, Co) complexes J. Chem. Soc. Dalton Trans. 1989 863 871
38. R.-Y. Wang, T.-Z. Jin, and Z.-P. Zheng A new paradigmatic lanthanide coordination chemistry: assembling lanthanide-hydroxo clusters under physiological or higher-pH conditions Acta Chim. Sin. 58 2000 1481 1492
39. n Inorg. Chim. Acta 360 2007 1616 1620
40. G.S. Smith, and J.L. Hoard The structure of dihydrogen ethylenediaminetetraacetatoaquonickel(II) J. Am. Chem. Soc. 81 1959 556 561
41. F.S. Stephens Crystal and molecular structure of aquo(dihydrogen ethylenediaminetetra-acetato)copper(II) J. Chem. Soc. A 1969 1723 1734
42. 2 - ligand Inorg. Chem. 41 2002 429 432
43. Y.-Y. Wang, Q. Shi, Q.-Z. Shi, Y.-C. Gao, and X. Hou Molecular structure, characterization and magnetic properties of novel mixed-valence copper(I, II) α, β-unsaturated carboxylate complexes with triphenylphosphine and methanol ligands Polyhedron 19 2000 891 898
44. - anion Acta Cryst. C40 1984 635 638
45. 2 - Inorg. Chem. 45 2006 11030 11034
46. S.-M. Hu, S.-C. Xiang, J.-J. Zhang, T.-L. Sheng, R.-B. Fu, and X.-T. Wu (*) Synthesis, structure, and magnetic properties of three chiral sodium-centered polynuclear copper(II) clusters with L-alanine Eur. J. Inorg. Chem. 2008 1141 1146
47. V.H. Crawford, H.W. Richardson, J.R. Wasson, D.J. Hodgson, and W.E. Hatfield Relationship between the singlet-triplet splitting and the CuOCu bridge angle in hydroxo-bridged copper dimers Inorg. Chem. 15 1976 2107 2110