Synthesis, Structures, and Magnetic Properties of Carboxylate-Bridged Tetranuclear Copper(II)-Lanthanoid(HI) Complexes [Cu2Ln2 (betaine)10(H2O)8](ClO4) 10·2H2O and [Cu2Ln2(betaine) 12(ClO4)2](ClO4)8

Inorganic Chemistry

Volumn 37, Issue 24, 1998, Pages 6186-6191

  Chen, Xiao Ming ^a   Wu, Yu Luan ^a   Yang, Yang Yi ^a   Aubin, Sheila M J ^b   Hendrickson, David N ^b  

^a SUN YAT SEN UNIVERSITY   (China)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000284224     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic980525g     Document Type: Article

References (53)

1. Chen, X.-M.; Tong, Y.-X.; Xu, Z.-T.; Mak, T. C. W. J. Chem. Soc., Dalton Trans. 1995, 4001. Tong, Y.-X.; Chen, X.-M.; Ng, S. W. Polyhedron 1997, 16, 3363 and references therein.
2. Chen, X.-M.; Tong, Y.-X.; Xu, Z.-T.; Mak, T. C. W. J. Chem. Soc., Dalton Trans. 1995, 4001. Tong, Y.-X.; Chen, X.-M.; Ng, S. W. Polyhedron 1997, 16, 3363 and references therein.
3. (a) Chen, X.-M.; Mak, T. C. W. Polyhedron 1994, 13, 1087.
4. (b) Chen, X.-M.; Mak, T. C. W. Inorg. Chem. 1994, 33, 2444.
5. Chen, X.-M.; Mak, T. C. W. Polyhedron 1991, 10, 273.
6. For reviews, see: (a) Mehrotra, C.; Bohra, R. C. Metal Carboxylates; Academic Press: New York, 1983. (b) Oldham, C. In Comprehensive Coordination Chemistry, Wilkinson, G., Gillard, R., McCleverty, J. A., Eds.; Pergamon Press: Oxford, 1987; Vol. 2, Chapter 15, pp 435-460. (c) Ouchi, A.; Suzuki, Y.; Ohki, Y.; Koizumi, Y. Coord. Chem. Rev. 1988, 92, 29.
7. For reviews, see: (a) Mehrotra, C.; Bohra, R. C. Metal Carboxylates; Academic Press: New York, 1983. (b) Oldham, C. In Comprehensive Coordination Chemistry, Wilkinson, G., Gillard, R., McCleverty, J. A., Eds.; Pergamon Press: Oxford, 1987; Vol. 2, Chapter 15, pp 435-460. (c) Ouchi, A.; Suzuki, Y.; Ohki, Y.; Koizumi, Y. Coord. Chem. Rev. 1988, 92, 29.
8. For reviews, see: (a) Mehrotra, C.; Bohra, R. C. Metal Carboxylates; Academic Press: New York, 1983. (b) Oldham, C. In Comprehensive Coordination Chemistry, Wilkinson, G., Gillard, R., McCleverty, J. A., Eds.; Pergamon Press: Oxford, 1987; Vol. 2, Chapter 15, pp 435-460. (c) Ouchi, A.; Suzuki, Y.; Ohki, Y.; Koizumi, Y. Coord. Chem. Rev. 1988, 92, 29.
9. Chen, X.-M.; Tong, M.-L.; Wu, Y.-L.; Luo, Y.-J. J. Chem. Soc., Dalton Trans. 1996, 2181. Tong, M.-L.; Wu, Y.-L.; Chen, X.-M.; Sun, Z.; Hendrickson, D. N. Chem. Res. Chin. Univ. 1998, 14, 230.
10. Chen, X.-M.; Tong, M.-L.; Wu, Y.-L.; Luo, Y.-J. J. Chem. Soc., Dalton Trans. 1996, 2181. Tong, M.-L.; Wu, Y.-L.; Chen, X.-M.; Sun, Z.; Hendrickson, D. N. Chem. Res. Chin. Univ. 1998, 14, 230.
11. (a) Holtzelmann, R.; Wieghardt, K.; Ensling, J.; Romstedt, H.; Gütlich, P.; Bill, E.; Flörke, U.; Haupt, H.-J. J. Am. Chem. Soc. 1992, 114, 9470.
12. (b) Bovorik, A. S.; Hendrich, M. P.; Holman, T. R.; Munck, E.; Papaefthymiou, V.; Que, L., Jr. J. Am. Chem. Soc. 1990, 112, 6031
13. (c) Tanase, T.; Watton, S. P.; Lippard, S. J. J. Am. Chem. Soc. 1994, 116, 9401 and references therein.
14. (a) Clegg, W.; Little, I. R.; Straughan, B. P. J. Chem. Soc., Dalton Trans. 1988, 1916
15. (b.) Clegg, W.; Little, I. R.; Straughan, B. P. J. Chem. Soc., Dalton Trans. 1986, 1283
16. (c) Langs, D. A.; Hare, C. R. J. Chem. Soc. 1967, 890
17. (d) Klop, A. J.; Duisenberg, A. J. M.; Spek, A. L. Acta Crystallogr., Sect. C 1983, 39, 1342
18. (e) Cingi, M. B.; Landredi, A. M. M.; Tiripicchio, A.; Tiripicchio, M. Acta Crystallogr., Sect. B 1977, 33, 659
19. (f) Smith, G.; O'Reilly, E. J.; Kennard, C. H. L.; White, A. H. J. Chem. Soc., Dalton Trans. 1985, 243
20. (g) Sanchis, M. J.; Gomez-Romere, P.; Folgado, J.-V.; Sapiña, F.; Ibanez, R.; Beltrán, A.; Garcia. J.; Beltrán, D. Inorg. Chem. 1992, 31, 2915.
21. (a) Andruh, M.; Ramade, I.; Codjovi, E.; Guillou, O.; Kahn, O.; Trombe, J. C. J. Am. Chem. Soc. 1993, 115, 1822.
22. (b) Benelli, C.; Caneschi, A.; Gatteschi, D.; Guilou, O.; Pardi, L. Inorg. Chem. 1990, 29, 1750
23. (c) Andruh, M.; Kahn, O.; Sainto, J.; Dromzee, Y.; Jeannin, S. Inorg. Chem. 1993, 32, 1623
24. (d) Bencini, A.; Benelli, C.; Caneschi, A.; Dei, A.; Gatteschi, D. Inorg. Chem. 1986, 25, 572
25. (e) Bencini, A.; Benelli, C.; Caneschi, A.; Carlin, R. L.; Dei, A.; Gatteschi, D. J. Am. Chem. Soc. 1985, 107, 8128.
26. (a) Guillou, O.; Kahn, O.; Oushoorm, R.; Boubeker, K.; Batail, P. Inorg. Chim. Acta 1992, 189-200, 1190.
27. (b) Georges, R.; Kahn, O.; Guillou, O. Phys. Rev. B 1994, 49, 3235
28. (c) Li, Y.-T.; Jiang, Z.-H.; Ma, S.-L.; Li, X.-Y.; Liao, D.-Z.; Yan, S.-P.; Wang, G.-L. Transition Met. Chem (N.Y.) 1994, 14, 432
29. (d) Sanz, L. L.; Ruiz, R.; Lloret, F.; Faus, J.; Juvle, M.; Borrás-Almemar, J. J.; Journaux, Y. Inorg. Chem. 1996, 35, 7393.
30. (a) Wang, S.; Pang, Z.; Smith, D. L. Inorg. Chem. 1993, 32, 4992.
31. (b) Wang, S.; Pang, Z.; Wagner, M. J. Inorg. Chem. 1992, 31, 5381.
32. (c) Blake, A. J.; Cherepamov, V. A.; Dunlop, A. A.; Grant, C. M.; Milne, P. E. Y.; Rawson, J. M.; Winpenny, R. E. J. Chem. Soc., Dalton Trans. 1994, 2719
33. (d) Blake, A. J.; Gould, R. O.; Grant, C. M.; Milne, P. E. Y.; Winpenny, R. E. J. Chem. Soc., Chem. Commun. 1992, 522
34. (e) Brechin, E. K.; Harris, S. G.; Parson, S.; Winpenny, R. E. J. Chem. Soc., Dalton Trans. 1997, 1665 and references therein.
35. (a) Chen, X.-M.; Aubin, S. M. J.; Wu, Y.-L.; Yang, Y.-S.; Mak, T. C. W.; Hendrickson, D. N. J. Am. Chem. Soc. 1995, 117, 9600.
36. (b) Chen, X.-M.; Wu, Y.-L.; Tong, Y.-X.; Huang, X.-Y. J. Chem. Soc., Dalton Trans. 1996, 2443
37. (c) Chen, X.-M.; Wu, Y.-L.; Wang, R.-J. Sci. China, Ser. B 1996, 39, 536.
38. Wu, Y.-L.; Tong, Y.-X.; Yang, Y.-S.; Chen, X.-M. Acta Sci. Nat. Univ. Sunyatseni 1995, 34 (4), 36. Wu, Y.-L. Ph.D. Thesis, Zhongshan University, Guangzhou, China, 1995.
39. Wu, Y.-L.; Tong, Y.-X.; Yang, Y.-S.; Chen, X.-M. Acta Sci. Nat. Univ. Sunyatseni 1995, 34 (4), 36. Wu, Y.-L. Ph.D. Thesis, Zhongshan University, Guangzhou, China, 1995.
40. Boudreaux, E. A.; Mulay, L. N. Theory and Application of Molecular Paramagnetism; Wiley: New York, 1976.
41. North, A. C. T.; Phillips, D. C.; Mathews, F. S. Acta Crystallogr., Sect. A 1968, 24, 351.
42. Sheldrick, G. M. SHELXTL-Plus; Siemens Analytical X-ray Instruments Inc.: Madison, WI, 1990.
43. Sheldrick, G. M. SHELKL-97; Program for X-ray Crystal Structure Refinement; Göttingen University: Göttingen, Germany, 1997.
44. International Tables for X-ray Crystallography; Kluwer Academic Publisher: Dordrecht, Holland, 1992; Vol. C, Tables 4.2.6.8 and 6.1.1.4.
45. Chen, X.-M.; Mak, T. C. W. Struct. Chem. 1993, 4, 247, Chen, X. M.; Feng, X.-L.; Xu, Z.-T.; Zhang, X.-H.; Xue, F.; Mak, T. C. W. Polyhedron 1998, in press and references therein.
46. Chen, X.-M.; Mak, T. C. W. Struct. Chem. 1993, 4, 247, Chen, X. M.; Feng, X.-L.; Xu, Z.-T.; Zhang, X.-H.; Xue, F.; Mak, T. C. W. Polyhedron 1998, in press and references therein.
47. Chen, X.-M.; Wu, Y.-L.; Wang, R.-J.; Mak, T. C. W. Polyhedron 1996, 15, 739-744.
48. Shannon, R. D. Acta Crystallogr., Sect. A 1976, 32, 751.
49. Chen, X.-M.; Wu, Y.-L.; Yang, Y. S. Aust. J. Chem. 1995, 48, 1643.
50. Tong, M.-L.; Zhou, Z.-Y.; Wu, Y.-L.; Chen, X.-M. Malays. J. Sci. 1996, 17B, 87. Yu, X.-L.; Tong, M.-L.; Chen, X.-M. Acta Sci. Nat. Univ. Sunyatseni 1996, 35 (6), 133.
51. Tong, M.-L.; Zhou, Z.-Y.; Wu, Y.-L.; Chen, X.-M. Malays. J. Sci. 1996, 17B, 87. Yu, X.-L.; Tong, M.-L.; Chen, X.-M. Acta Sci. Nat. Univ. Sunyatseni 1996, 35 (6), 133.
52. Chen, X.-M.; Wu, Y.-L.; Tong, Y.-X.; Sun, Z.; Hendrickson, D. N. Polyhedron 1997, 16, 4265.
53. Panagiotopouls, A.; Zafiropoulos, T. F.; Perlpes, S. P.; Balkalbasis, E.; Masson-Ramada, I.; Kahn, O.; Terzis, A.; Raptopoulou, C. P. Inorg. Chem. 1995, 34, 4918.