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Volumn 50, Issue 19, 2011, Pages 11073-11086

Transesterification of dimethyl carbonate with ethanol to form ethyl methyl carbonate and diethyl carbonate: A comprehensive study on chemical equilibrium and reaction kinetics

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVITY-BASED; ARRHENIUS EQUATION; CHEMICAL EQUILIBRIUM CONSTANT; CHEMICAL EQUILIBRIUMS; COMPREHENSIVE STUDIES; DIETHYL CARBONATES; DIMETHYL CARBONATE; ETHYL METHYL CARBONATE; HOMOGENEOUS CATALYST; KINETIC MODELS; SODIUM ETHOXIDES; TEMPERATURE DEPENDENCE; VAN'T HOFF EQUATION;

EID: 84855614997     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie2014982     Document Type: Article
Times cited : (85)

References (50)
  • 1
    • 34547684656 scopus 로고    scopus 로고
    • Reactive distillation: The front-runner of industrial process intensification. A full review of commercial applications, research, scale-up, design and operation
    • Harmsen, G. J. Reactive Distillation: The Front-Runner of Industrial Process Intensification. A Full Review of Commercial Applications, Research, Scale-Up, Design and Operation. Chem. Eng. Process. 2007, 46, 774.
    • (2007) Chem. Eng. Process. , vol.46 , pp. 774
    • Harmsen, G.J.1
  • 2
    • 0037332333 scopus 로고    scopus 로고
    • Reactive and catalytic distillation from an industrial perspective
    • Schoenmakers, H.; Beßling, B. Reactive and Catalytic Distillation from an Industrial Perspective. Chem. Eng. Process. 2003, 42, 145.
    • (2003) Chem. Eng. Process. , vol.42 , pp. 145
    • Schoenmakers, H.1    Beßling, B.2
  • 3
    • 0030131397 scopus 로고    scopus 로고
    • Development of a new catalytic distillation process for fuel ethers via a detailed nonequilibrium model
    • Sundmacher, K.; Hoffmann, U. Development of a New Catalytic Distillation Process for Fuel Ethers via a Detailed Nonequilibrium Model. Chem. Eng. Sci. 1996, 51, 2359.
    • (1996) Chem. Eng. Sci. , vol.51 , pp. 2359
    • Sundmacher, K.1    Hoffmann, U.2
  • 4
    • 0025378137 scopus 로고
    • High-purity methyl acetate via reactive distillation
    • Agreda, V. H.; Partin, L. R.; Heise, W. H. High-Purity Methyl Acetate via Reactive Distillation. Chem. Eng. Prog. 1990, 86, 40.
    • (1990) Chem. Eng. Prog. , vol.86 , pp. 40
    • Agreda, V.H.1    Partin, L.R.2    Heise, W.H.3
  • 5
    • 84860765640 scopus 로고    scopus 로고
    • Reactive distillation as a multipurpose reactor for controlling selectivity in multiple reaction systems
    • Presented at the, Chicago, IL, March; Paper No. 107d
    • Keller, T.; Górak, A. Reactive Distillation as a Multipurpose Reactor for Controlling Selectivity in Multiple Reaction Systems. Presented at the AIChE Spring Meeting, Chicago, IL, March 2011; Paper No. 107d.
    • (2011) AIChE Spring Meeting
    • Keller, T.1    Górak, A.2
  • 6
    • 34547929250 scopus 로고    scopus 로고
    • Simultaneous production of diacetone alcohol and mesityl oxide from acetone using reactive distillation
    • Thotla, S.; Agarwal, V.; Mahajani, S. M. Simultaneous Production of Diacetone Alcohol and Mesityl Oxide from Acetone using Reactive Distillation. Chem. Eng. Sci. 2007, 62, 5567.
    • (2007) Chem. Eng. Sci. , vol.62 , pp. 5567
    • Thotla, S.1    Agarwal, V.2    Mahajani, S.M.3
  • 7
    • 79960863799 scopus 로고    scopus 로고
    • Mixed succinic acid/acetic acid esterification with ethanol by reactive distillation
    • Orjuela, A.; Kolah, A.; Lira, C. T.; et al. Mixed Succinic Acid/Acetic Acid Esterification with Ethanol by Reactive Distillation. Ind. Eng. Chem. Res. 2011, 50, 9209.
    • (2011) Ind. Eng. Chem. Res. , vol.50 , pp. 9209
    • Orjuela, A.1    Kolah, A.2    Lira, C.T.3
  • 9
    • 0032535847 scopus 로고    scopus 로고
    • A comparison of the equilibrium and nonequilibrium models for a multicomponent reactive distillation column
    • Lee, J.-H.; Dudukovic, M. A Comparison of the Equilibrium and Nonequilibrium Models for a Multicomponent Reactive Distillation Column. Comput. Chem. Eng. 1998, 23, 159.
    • (1998) Comput. Chem. Eng. , vol.23 , pp. 159
    • Lee, J.-H.1    Dudukovic, M.2
  • 10
    • 34547697759 scopus 로고    scopus 로고
    • Hybrid separation processes-combination of reactive distillation with membrane separation
    • Buchaly, C.; Kreis, P.; Górak, A. Hybrid Separation Processes-Combination of Reactive Distillation with Membrane Separation. Chem. Eng. Process. 2007, 46, 790.
    • (2007) Chem. Eng. Process. , vol.46 , pp. 790
    • Buchaly, C.1    Kreis, P.2    Górak, A.3
  • 11
    • 0346116581 scopus 로고    scopus 로고
    • Wiley-VCH: Weinheim, Germany
    • Otera, J. Esterification; Wiley-VCH: Weinheim, Germany, 2003.
    • (2003) Esterification
    • Otera, J.1
  • 12
    • 0035032804 scopus 로고    scopus 로고
    • A reactive distillation process for a cascade and azeotropic reaction system: Carbonylation of ethanol with dimethyl carbonate
    • Luo, H.-P.; Xiao, W.-D. A Reactive Distillation Process for a Cascade and Azeotropic Reaction System: Carbonylation of Ethanol with Dimethyl Carbonate. Chem. Eng. Sci. 2001, 56, 403.
    • (2001) Chem. Eng. Sci. , vol.56 , pp. 403
    • Luo, H.-P.1    Xiao, W.-D.2
  • 13
    • 0024070593 scopus 로고
    • Continuous-flow processes under gas-liquid phase-transfer catalysis (GL-PTC) Conditions: The reaction of dialkyl carbonates with phenols, alcohols, and mercaptans
    • Tundo, P.; Trotta, F.; Moraglio, G.; et al. Continuous-Flow Processes under Gas-Liquid Phase-Transfer Catalysis (GL-PTC) Conditions: The Reaction of Dialkyl Carbonates with Phenols, Alcohols, and Mercaptans. Ind. Eng. Chem. Res. 1988, 27, 1565.
    • (1988) Ind. Eng. Chem. Res. , vol.27 , pp. 1565
    • Tundo, P.1    Trotta, F.2    Moraglio, G.3
  • 14
    • 33646086235 scopus 로고    scopus 로고
    • Zeolite and other heterogeneous catalysts for the transesterification reaction of dimethyl carbonate with ethanol
    • Zielinska-Nadolska, I.; Warmuzinski, K.; Richter, J. Zeolite and Other Heterogeneous Catalysts for the Transesterification Reaction of Dimethyl Carbonate with Ethanol. Catal. Today 2006, 114, 226.
    • (2006) Catal. Today , vol.114 , pp. 226
    • Zielinska-Nadolska, I.1    Warmuzinski, K.2    Richter, J.3
  • 15
    • 84860146217 scopus 로고    scopus 로고
    • Preparation of acyclic carbonic acid esters by transesterification with alcohols over group IIIB metal oxides
    • Jpn. Patent 9,118,652
    • Inaba, M.; Hasegawa, K.; Kiyomi, N. et al. Preparation of Acyclic Carbonic Acid Esters by Transesterification with Alcohols over Group IIIB Metal Oxides. Jpn. Patent 9,118,652, 1997.
    • (1997)
    • Inaba, M.1    Hasegawa, K.2    Kiyomi, N.3
  • 16
    • 62449100182 scopus 로고    scopus 로고
    • Lanthanum nitrate as an efficient and recoverable homogeneous catalyst for the transesterification of dimethyl carbonate with ethanol
    • Mei, F.; Chen, E.; Li, G. Lanthanum Nitrate as an Efficient and Recoverable Homogeneous Catalyst for the Transesterification of Dimethyl Carbonate with Ethanol. React. Kinet. Catal. Lett. 2009, 96, 27.
    • (2009) React. Kinet. Catal. Lett. , vol.96 , pp. 27
    • Mei, F.1    Chen, E.2    Li, G.3
  • 18
    • 0033740952 scopus 로고    scopus 로고
    • A low-temperature electrolyte for lithium and lithium-ion batteries
    • Plichta, E. J.; Behl, W. K. A Low-temperature Electrolyte for Lithium and Lithium-ion Batteries. J. Power Sources 2000, 88, 192.
    • (2000) J. Power Sources , vol.88 , pp. 192
    • Plichta, E.J.1    Behl, W.K.2
  • 19
    • 70349169539 scopus 로고    scopus 로고
    • Carbonate-modified siloxanes as solvents of electrolyte solutions for rechargeable lithium cells
    • Takeuchi, T.; Noguchi, S.; Morimoto, H.; et al. Carbonate-Modified Siloxanes as Solvents of Electrolyte Solutions for Rechargeable Lithium Cells. J. Power Sources 2010, 195, 580.
    • (2010) J. Power Sources , vol.195 , pp. 580
    • Takeuchi, T.1    Noguchi, S.2    Morimoto, H.3
  • 20
    • 84860211562 scopus 로고
    • Secondary nonaqueous-electrolyte battery
    • U.S. Patent 5,521,027
    • Okuno, H.; Koshina, H.; Morita, A. Secondary Nonaqueous-Electrolyte Battery. U.S. Patent 5,521,027, 1993.
    • (1993)
    • Okuno, H.1    Koshina, H.2    Morita, A.3
  • 22
    • 0001100862 scopus 로고    scopus 로고
    • Change of conductivity with salt content, solvent composition, and temperature for electrolytes of LiPF6 in ethylene carbonate-ethyl methyl carbonate
    • Ding, M. S.; Xu, K.; Zhang, S. S.; et al. Change of Conductivity with Salt Content, Solvent Composition, and Temperature for Electrolytes of LiPF6 in Ethylene Carbonate-Ethyl Methyl Carbonate. J. Electrochem. Soc. 2001, 148, A1196.
    • (2001) J. Electrochem. Soc. , vol.148
    • Ding, M.S.1    Xu, K.2    Zhang, S.S.3
  • 23
    • 0030736233 scopus 로고    scopus 로고
    • Review of Dimethyl Carbonate (DMC) manufacture and its characteristics as a fuel additive
    • Pacheco, M. A.; Marshall, C. L. Review of Dimethyl Carbonate (DMC) Manufacture and Its Characteristics as a Fuel Additive. Energy Fuels 1997, 11, 2.
    • (1997) Energy Fuels , vol.11 , pp. 2
    • Pacheco, M.A.1    Marshall, C.L.2
  • 24
    • 0036165217 scopus 로고    scopus 로고
    • Production of diethyl carbonate from ethanol and carbon monoxide over a heterogeneous catalyst
    • Dunn, B. C.; Guenneau, C.; Hilton, S. A.; et al. Production of Diethyl Carbonate from Ethanol and Carbon Monoxide over a Heterogeneous Catalyst. Energy Fuels 2002, 16, 177.
    • (2002) Energy Fuels , vol.16 , pp. 177
    • Dunn, B.C.1    Guenneau, C.2    Hilton, S.A.3
  • 26
    • 0016437957 scopus 로고
    • Statistical thermodynamics of liquid mixtures: A new expression for the excess energy of partly or completely miscible systems
    • Abrams, D. S.; Prausnitz, J. M. Statistical Thermodynamics of Liquid Mixtures: A New Expression for the Excess Energy of Partly or Completely Miscible Systems. AlChE J. 1975, 21, 116.
    • (1975) AlChE J. , vol.21 , pp. 116
    • Abrams, D.S.1    Prausnitz, J.M.2
  • 27
    • 0001798404 scopus 로고    scopus 로고
    • Don't gamble with physical properties for simulations
    • Carlson, E. C. Don't Gamble with Physical Properties for Simulations. Chem. Eng. Prog. 1996, 92, 35.
    • (1996) Chem. Eng. Prog. , vol.92 , pp. 35
    • Carlson, E.C.1
  • 30
    • 0034351224 scopus 로고    scopus 로고
    • Isobaric vapor-liquid equilibria of alkyl carbonates with alcohols
    • Luo, H.-P.; Xiao, W.-D.; Zhu, K.-H. Isobaric Vapor-liquid Equilibria of Alkyl Carbonates with Alcohols. Fluid Phase Equilib. 2000, 175, 91.
    • (2000) Fluid Phase Equilib. , vol.175 , pp. 91
    • Luo, H.-P.1    Xiao, W.-D.2    Zhu, K.-H.3
  • 31
    • 0037199879 scopus 로고    scopus 로고
    • Vapour-liquid equilibria of dimethyl carbonate with linear alcohols and estimation of interaction parameters for the UNIFAC and ASOG method
    • Rodríguez, A.; Canosa, J.; Domínguez, A.; et al. Vapour-liquid Equilibria of Dimethyl Carbonate with Linear Alcohols and Estimation of Interaction Parameters for the UNIFAC and ASOG Method. Fluid Phase Equilib. 2002, 201, 187.
    • (2002) Fluid Phase Equilib. , vol.201 , pp. 187
    • Rodríguez, A.1    Canosa, J.2    Domínguez, A.3
  • 32
    • 78449280205 scopus 로고    scopus 로고
    • Experimental isobaric vapor-liquid equilibrium for binary systems of ethyl methyl Carbonate + Methanol, + Ethanol, + Dimethyl Carbonate, or + Diethyl carbonate at 101.3 kPa
    • Zhang, X.; Zuo, J.; Jian, C. Experimental Isobaric Vapor-liquid Equilibrium for Binary Systems of Ethyl Methyl Carbonate + Methanol, + Ethanol, + Dimethyl Carbonate, or + Diethyl Carbonate at 101.3 kPa. J. Chem. Eng. Data 2010, 55, 4896.
    • (2010) J. Chem. Eng. Data , vol.55 , pp. 4896
    • Zhang, X.1    Zuo, J.2    Jian, C.3
  • 33
    • 0037208019 scopus 로고    scopus 로고
    • Isobaric phase equilibria of diethyl carbonate with five alcohols at 101.3 kPa
    • Rodríguez, A.; Canosa, J.; Domínguez, A.; et al. Isobaric Phase Equilibria of Diethyl Carbonate with Five Alcohols at 101.3 kPa. J. Chem. Eng. Data 2003, 48, 86.
    • (2003) J. Chem. Eng. Data , vol.48 , pp. 86
    • Rodríguez, A.1    Canosa, J.2    Domínguez, A.3
  • 34
    • 0347537973 scopus 로고    scopus 로고
    • A new catalytic transesterification for the synthesis of ethyl methyl carbonate
    • Shen, Z. L.; Jiang, X. Z.; Zhao, W. J. A New Catalytic Transesterification for the Synthesis of Ethyl Methyl Carbonate. Catal. Lett. 2003, 91, 63.
    • (2003) Catal. Lett. , vol.91 , pp. 63
    • Shen, Z.L.1    Jiang, X.Z.2    Zhao, W.J.3
  • 36
    • 64549094966 scopus 로고    scopus 로고
    • Reaction from dimethyl carbonate (DMC) to Diphenyl Carbonate (DPC). 2. Kinetics of the reactions from DMC via methyl phenyl carbonate to DPC
    • Haubrock, J.; Wermink, W.; Versteeg, G. F.; et al. Reaction from Dimethyl Carbonate (DMC) to Diphenyl Carbonate (DPC). 2. Kinetics of the Reactions from DMC via Methyl Phenyl Carbonate to DPC. Ind. Eng. Chem. Res. 2008, 47, 9862.
    • (2008) Ind. Eng. Chem. Res. , vol.47 , pp. 9862
    • Haubrock, J.1    Wermink, W.2    Versteeg, G.F.3
  • 40
    • 1542541575 scopus 로고    scopus 로고
    • Thermodynamics of reactive separations
    • Sundmacher, K., Kienle, A., Eds.; Wiley-VCH: Weinheim, Germany
    • Hasse, H. Thermodynamics of Reactive Separations. In Reactive Distillation; Sundmacher, K., Kienle, A., Eds.; Wiley-VCH: Weinheim, Germany, 2003.
    • (2003) Reactive Distillation
    • Hasse, H.1
  • 41
    • 0025545355 scopus 로고
    • Kinetics of methyl tertiary butyl ether liquid phase synthesis catalyzed by ion exchange resin
    • Rehfinger, A.; Hoffmann, U. Kinetics of Methyl Tertiary Butyl Ether Liquid Phase Synthesis Catalyzed by Ion Exchange Resin. Chem. Eng. Sci. 1990, 45, 1605.
    • (1990) Chem. Eng. Sci. , vol.45 , pp. 1605
    • Rehfinger, A.1    Hoffmann, U.2
  • 44
    • 0742287043 scopus 로고    scopus 로고
    • Theory and practice of simultaneous data reconciliation and gross error detection for chemical processes
    • Oezyurt, D. B.; Pike, R. W. Theory and Practice of Simultaneous Data Reconciliation and Gross Error Detection for Chemical Processes. Comput. Chem. Eng. 2004, 28, 381.
    • (2004) Comput. Chem. Eng. , vol.28 , pp. 381
    • Oezyurt, D.B.1    Pike, R.W.2
  • 45
    • 0030199114 scopus 로고    scopus 로고
    • An efficient formulation for batch reactor data reconciliation
    • Fillon, M.; Meyer, M.; Pingaud, H.; et al. An Efficient Formulation for Batch Reactor Data Reconciliation. Ind. Eng. Chem. Res. 1996, 35, 2288.
    • (1996) Ind. Eng. Chem. Res. , vol.35 , pp. 2288
    • Fillon, M.1    Meyer, M.2    Pingaud, H.3
  • 46
    • 0017949075 scopus 로고
    • Design and testing of a generalized reduced gradient code for nonlinear programming
    • Lasdon, L. S.; Waren, A. D.; Jain, A.; et al. Design and Testing of a Generalized Reduced Gradient Code for Nonlinear Programming. ACM Trans. Math. Software 1978, 4, 34.
    • (1978) ACM Trans. Math. Software , vol.4 , pp. 34
    • Lasdon, L.S.1    Waren, A.D.2    Jain, A.3
  • 49
    • 0242497822 scopus 로고    scopus 로고
    • Transesterification processes by combination of reactive distillation and pervaporation
    • Steinigeweg, S.; Gmehling, J. Transesterification Processes by Combination of Reactive Distillation and Pervaporation. Chem. Eng. Process. 2004, 43, 447.
    • (2004) Chem. Eng. Process. , vol.43 , pp. 447
    • Steinigeweg, S.1    Gmehling, J.2


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