Clean hydrogen generation through the electrocatalytic oxidation of formic acid in a Proton Exchange Membrane Electrolysis Cell (PEMEC)

Electrochimica Acta

Volumn 60, Issue , 2012, Pages 112-120

  Lamy, Claude ^a   Devadas, Abirami ^a   Simoes, Mario ^a   Coutanceau, Christophe ^a  

^a UNIVERSITÉ DE POITIERS   (France)

Author keywords

Electrolysis; Formic acid; Gold; Hydrogen generation; Pd based catalysts

Indexed keywords

CARBON SUPPORT; CELL VOLTAGES; DECOMPOSITION ENERGY; ELECTRICAL ENERGY; ELECTRO-CATALYTIC OXIDATION; ELECTROCHEMICAL ACTIVITIES; ELECTROCHEMICAL DECOMPOSITION; HYDROGEN GENERATION; HYDROGEN GENERATIONS; MICROEMULSION METHOD; MODEL COMPOUND; MONOMETALLIC CATALYSTS; OVER-VOLTAGES; PD-BASED CATALYST; PHYSICOCHEMICAL METHODS; PROTON EXCHANGE MEMBRANES; VULCAN XC72; WATER DECOMPOSITION; WATER ELECTROLYSIS; WATER-IN-OIL; XRD;

CATALYST ACTIVITY; CYCLIC VOLTAMMETRY; ELECTROCATALYSIS; ELECTROCATALYSTS; ELECTROLYSIS; ELECTROLYTIC CELLS; FORMIC ACID; GOLD; HYDROGEN; HYDROGEN PRODUCTION; MICROEMULSIONS; PLATINUM; REACTION RATES;

ANODIC OXIDATION;

EID: 84655176695     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2011.11.006     Document Type: Article

References (38)

1. B. Srensen Hydrogen and Fuel Cell Emerging Technologies and Applications 2005 Elsevier Academic Press New York
2. S. Grigoriev, V. Porembsky, and V. Fateev Int. J. Hydrogen Energy 31 2006 171
3. Y. Nishimura, K. Yasuda, Z. Siroma, and K. Asaka Denki Kagaku Oyobi Kogyo Butsuri Kagaku 65 1997 1122
4. P. Millet, F. Andolfatto, and R. Durand Int. J. Hydrogen Energy 21 1996 87
5. A. Marshall, Characterisation of electrocatalysis for water electrolysis, Ph.D. Thesis, NTNU, Trondheim, Norway, 2005.
6. K.E. Ayers, C. Capuano, B. Carter, L. Dalton, G. Hanlon, J. Manco, and M. Niedzwiecki Polymer Electrolyte Fuel Cells 10 Symposium, 218th ECS Meeting Las Vegas, NV, October 10-15 2010 Abstract 603
7. A. Marshall, S. Sunde, M. Tsypkin, and R. Tunold Int. J. Hydrogen Energy 32 2007 2320
8. A. Tanksale, J.N. Beltramini, G. Qing, and M. Lu Renew. Sustain. Energy Rev. 14 2010 166
9. S. Therdthianwong, N. Srisiriwat, A. Therdthianwong, and E. Croiset J. Supercrit. Fluids 57 2011 58
10. M. Ni, D.Y.C. Leung, and M.K.H. Leung Int. J. Hydrogen Energy 32 2007 3238
11. A.F. Ghenciu Curr. Opin. Solid State Mater. Sci. 6 2002 389
12. D.A. Bulushev, S. Beloshapkin, and J.R.H. Ross Catal. Today 154 2010 7
13. T. Take, K. Tsurutani, and M. Umeda J. Power Sources 164 2007 9
14. Z. Hu, M. Wu, Z. Wei, S. Song, and P.K. Shen J. Power Sources 166 2007 458
15. S.R. Narayanan, W. Chun, B. Jeffries-Nakamura, T.I. Valdez, US Patent 6,533,919, March 18, 2003.
16. P.A. Selembo, J.M. Perez, W.A. Lloyd, and B.E. Logan Int. J. hydrogen energy 34 2009 5373
17. A.T. Marshall, and R.G. Haverkamp Int. J. Hydrogen Energy 33 2008 4649
18. E.Ö. Kilia, A.S. Koparal, and Ü.B. Öütveren Fuel Process. Technol. 90 2009 158
19. L. Aldous, and R.G. Compton Energy Environ. Sci. 3 2010 1587
20. W.L. Guo, L. Li, L.L. Li, S. Tian, S.L. Liu, and Y.P. Wu Int. J. Hydrogen energy 36 2011 9415
21. R. Larsen, S. Ha, J. Zakzeski, and R.I. Masel J. Power Sources 157 2006 78
22. F. Gloaguen, N. Andolfatto, R. Durand, and P. Ozil J. Appl. Electrochem. 24 1994 863
23. M. Simões, S. Baranton, and C. Coutanceau J. Phys. Chem. C 113 2009 13369
24. V. Mazumder, and S. Sun J. Am. Chem. Soc. 131 2009 4588
25. W. Zhou, and J.Y. Lee Electrochem. Commun. 9 2007 1725
26. A. Capon, and R. Parsons J. Electroanal. Chem. 44 1973 239
27. B. Beden, and C. Lamy R.J. Cale, Spectroelectrochemistry, Theory and Practice 1988 Plenum Press New York
28. X. Xia, and T.J. Iwasita J. Electrochem. Soc. 140 1993 2559
29. N. Markovic, H. Gaseiger, P. Ross, X. Jian, I. Villegas, and M. Weaver Electrochim. Acta 40 1995 91
30. T.D. Jarvi, and E.M. Stuve J. Lipkowski, P.N. Ross, Fundamental Aspects of Vacuum and Electrocatalytic Reactions of Methanol and Formic Acid on Platinum Surfaces 1998 Wiley New York
31. P.N. Ross J. Lipkowski, P.N. Ross, The Science of Electrocatalysis on Bimetallic Surfaces 1998 Wiley New York 63
32. G.Q. Lu, A. Crown, and A. Wieckowski J. Phys. Chem. B 103 1999 9700
33. C. Rice, S. Ha, R.I. Masel, and A. Wieckowski J. Power Sources 115 2003 229
34. G. Zhang, Y. Wang, X. Wang, Y. Chen, Y. Zhou, Y. Tang, L. Lu, J. Bao, and T. Lu Appl. Catal. B: Environ. 102 2011 614
35. R.L. Behrens, A. Lagutchev, D.D. Dlott, and A. Wieckowski J. Electroanal. Chem. 649 2010 32
36. X. Yu, and P.G. Pickup Electrochem. Commun. 11 2009 2012
37. X. Yu, and P.G. Pickup J. Power Sources 187 2009 493
38. A. Bewick, B. Beden, and C. Lamy J. Electroanal. Chem. 121 1981 115