Hydrogen production by electrochemical decomposition of formic acid via solid polymer electrolyte

Fuel Processing Technology

Volumn 90, Issue 1, 2009, Pages 158-163

  Kiliç, Ebru Önder ^a   Koparal, Ali Savaş ^b   Öǧütveren, Ülker Bakir ^b  

^a Kucuk ve Orta Olcekli Sanayi Geliptirme ve Destekleme Ydaresi Bapkanlyoy Ankara   (Turkey)

^b ANADOLU UNIVERSITY   (Turkey)

Author keywords

Electrochemical decomposition; Formic acid; Hydrogen production; Organic pollutant; Solid polymer electrolyte

Indexed keywords

CARBON DIOXIDE; CARBON FIBERS; CARBON NANOFIBERS; CATALYSIS; CATALYST SUPPORTS; CHEMICAL OXYGEN DEMAND; ELECTRIC REACTORS; ELECTROCHEMICAL OXIDATION; ELECTROLYSIS; ELECTROLYTES; FORMIC ACID; GAS FUEL MANUFACTURE; GAS PRODUCERS; HYDROGEN; IRIDIUM; IRIDIUM COMPOUNDS; ORGANIC ACIDS; ORGANIC POLLUTANTS; PH EFFECTS; PLATINUM; POLYELECTROLYTES; POLYMERS; PROTON EXCHANGE MEMBRANE FUEL CELLS (PEMFC); REMOVAL; SOLAR RADIATION; TITANIUM; TITANIUM OXIDES;

ACID SOLUTIONS; AMBIENT TEMPERATURES; APPLIED CURRENTS; CARBON FIBRES; CHEMICAL ADDITIONS; COD REMOVAL EFFICIENCIES; ELECTROCHEMICAL DECOMPOSITION; ELECTROCHEMICAL DECOMPOSITIONS; ELECTROCHEMICAL REACTORS; HPLC ANALYSES; IRIDIUM OXIDES; MEMBRANE THICKNESSES; PT CATALYSTS; SOLID POLYMER ELECTROLYTE; SOLID POLYMER ELECTROLYTES; SUPPORTING ELECTROLYTES; TEMPERATURE INCREASES;

HYDROGEN PRODUCTION;

EID: 57049093833     PISSN: 03783820     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.fuproc.2008.08.011     Document Type: Article

References (18)

1. Temeev A.A., Belokopytov V.P., and Temeev S.A. An integrated system of the floating wave energy, converter and electrolytic hydrogen producer. Renew. Energy 31 (2006) 225-239
2. Nagai N., Takeuchi M., Kimura T., and Oka T. Existence of optimum space between electrodes on hydrogen production by water electrolysis. Int. J. Hydrogen Energy 28 (2003) 35-41
3. Navarro-Flores E., and Omanovic S. Hydrogen evolution on nickel incorporated in three-dimensional conducting polymer layers. J Mol. Catal. A: Chem 242 (2005) 182-194
4. Barbir F. PEM electrolysis for production of hydrogen from renewable energy sources. Sol. Energy 78 (2005) 661-669
5. Choi P., Bessarabov D.G., and Data R. A simple model for solid polymer electrolyte (SPE) water electrolysis. Solid State Ion. 175 (2004) 535-539
6. Cheng H., Scott K., and Christensen P.A. Paired electrolysis in a solid polymer electrolyte reactor-simultaneously reduction of nitrate and oxidation of ammonia. Chem. Eng. J. 108 (2005) 257-268
7. Rasten E., Hagen G., and Tunold R. Electrocatalysis in water electrolysis with solid polymer electrolyte. Electrochim. Acta 48 (2003) 3945-3952
8. Kato T., Kubota M., Kobayashi N., and Suzuoki Y. Effective utilization of by-product oxygen from electrolysis hydrogen production. Energy 30 (2005) 2580-2595
9. Soler L., Macanás J., Munoz M., and Casado J. Electrocatalytic production of hydrogen boosted by organic pollutants and visible light. Int. J. Hydrogen Energy 31 (2006) 129-139
10. Rajkumar D., and Palanivelu K. Electrochemical treatment of industrial wastewater. J. Hazard. Mater. 113 (2004) 123-129
11. K oparal A.S., Önder E., and Baki{dotless}r Öǧütveren Ü. Removal of linear alkylbenzene sulfonate (LAS) from a model solution by continuous electrochemical oxidation. Desalination 197 (2006) 262-272
12. Panizza M., Kapakla A., and Comninellis Ch. Oxidation of organic pollutants on BDD anodes using modulated current electrolysis. Electrochim. Acta 53 (2008) 2289-2295
13. Shen Z.M., Wu D., Yang J., Yuan T., Wang W.H., and Jia J.P. Methods to improve electrochemical treatment effect of dye wastewater. J. Hazard. Mater. 131 (2006) 90-97
14. Gogate P.R., Pandit A.B., Wilhelm A., Ratsimba B., and Delmas H. Destruction of formic acid using high frequency cup horn reactor. Water. Res. 40 (2006) 1697-1705
15. Gogate P.R., Mujumdar S., and Pandit A.B. Sonochemical reactors for waste water treatment: comparison using formic acid degradation as a model reaction. Adv. Environ. Res. 7 (2003) 283-299
16. Yoo Y.E., Takenaka N., Bandow H., Nagata Y., and Maeda Y. Characteristics of volatile fatty acids degradation in aqueous solutions by the action of ultrasound. Water Res 31 (1997) 1532-1535
17. Bhirud U.S., Gogate P.R., Wilhelm A.M., and Pandit A.B. Ultrasonic bath with longitudinal vibrations: a novel configuration for efficient wastewater treatment. Ultrason. Sonochem. 11 (2004) 143-147
18. 2 anodes using nafion as electrolyte. Electrochim. Acta 42 (1997) 2013-2018