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Volumn 41, Issue 2, 2012, Pages 546-557
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Solution behavior of iron(iii) and iron(ii) porphyrins in DMSO and reaction with superoxide. Effect of neighboring positive charge on thermodynamics, kinetics and nature of iron-(su)peroxo product
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Author keywords
[No Author keywords available]
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Indexed keywords
ACTIVATION STEPS;
ANALOGOUS COMPLEXES;
BINDING CONSTANT;
DFT CALCULATION;
INNER-SPHERE ELECTRON;
IRON COMPLEX;
NMR STUDIES;
PORPHYRIN COMPLEXES;
POSITIVE CHARGES;
PRESSURE DEPENDENT;
PROTON SOURCE;
SOLUTION BEHAVIOR;
SPIN-STATE;
SUPEROXIDES;
UV/ VIS SPECTROSCOPY;
CROWN ETHERS;
DENSITY FUNCTIONAL THEORY;
ELECTRON SPIN RESONANCE SPECTROSCOPY;
ELECTRONIC STRUCTURE;
ETHERS;
IRON;
LIGANDS;
MASS SPECTROMETRY;
OXYGEN;
PORPHYRINS;
RATE CONSTANTS;
SPHERES;
THERMODYNAMICS;
ULTRAVIOLET VISIBLE SPECTROSCOPY;
IRON COMPOUNDS;
COORDINATION COMPOUND;
DIMETHYL SULFOXIDE;
FERRIC ION;
FERROUS ION;
HEME;
LIGAND;
PORPHYRIN;
PROTON;
SUPEROXIDE;
ARTICLE;
CHEMICAL MODEL;
CHEMICAL STRUCTURE;
CHEMISTRY;
ELECTROCHEMISTRY;
ELECTRON TRANSPORT;
ELECTROSPRAY MASS SPECTROMETRY;
KINETICS;
NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;
SOLUBILITY;
SYNTHESIS;
THERMODYNAMICS;
COORDINATION COMPLEXES;
DIMETHYL SULFOXIDE;
ELECTROCHEMISTRY;
ELECTRON TRANSPORT;
FERRIC COMPOUNDS;
FERROUS COMPOUNDS;
HEME;
KINETICS;
LIGANDS;
MAGNETIC RESONANCE SPECTROSCOPY;
MODELS, CHEMICAL;
MOLECULAR STRUCTURE;
PORPHYRINS;
PROTONS;
SOLUBILITY;
SPECTROMETRY, MASS, ELECTROSPRAY IONIZATION;
SUPEROXIDES;
THERMODYNAMICS;
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EID: 83455235327
PISSN: 14779226
EISSN: 14779234
Source Type: Journal
DOI: 10.1039/c1dt11521a Document Type: Article |
Times cited : (16)
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References (48)
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