Synthesis of poly(n-butyl acrylate) homopolymers by activators generated by electron transfer (AGET) ATRP using FeCl3·6H 2O/Succinic acid catalyst

Iranian Polymer Journal (English Edition)

Volumn 20, Issue 11, 2011, Pages 931-938

  Wang, Guoxiang ^a  

^a HUNAN INSTITUTE OF SCIENCE AND TECHNOLOGY   (China)

Author keywords

Atom transfer radical polymerization; Catalysts; Gel permeation chromatography; Living polymerization; Poly(n butyl acrylate)

Indexed keywords

ACID CATALYST; AGET ATRP; ASCORBIC ACIDS; CHAIN EXTENSION; DIFFERENT SOLVENTS; ELECTRON TRANSFER; ETHYL 2-BROMOISOBUTYRATE; FERRIC CHLORIDE HEXAHYDRATE; FTIR; GEL PERMEATION; MACROINITIATORS; MOLAR RATIO; MONOMER CONVERSIONS; N ,N-DIMETHYLFORMAMIDE; N-BUTYL ACRYLATE (NBA); NARROW DISTRIBUTION; NON-POLAR SOLVENTS; POLAR SOLVENTS; POLY(N-BUTYL ACRYLATE); POLYMER MOLECULAR WEIGHT; POLYMERIZATION RATES; POLYMERIZATION REACTION; POLYMERIZATION SYSTEMS;

BENZENE; CATALYSTS; CHLORINATION; CHLORINE COMPOUNDS; CHROMATOGRAPHY; DIMETHYLFORMAMIDE; ELECTRON TRANSITIONS; EXPERIMENTS; FREE RADICAL POLYMERIZATION; GEL PERMEATION CHROMATOGRAPHY; GELS; HOMOPOLYMERIZATION; KETONES; LIVING POLYMERIZATION; MOLECULAR WEIGHT; ORGANIC ACIDS; ORGANIC SOLVENTS; POLYDISPERSITY; POLYMERS; REACTION RATES; SOLVENTS; SYNTHESIS (CHEMICAL);

ATOM TRANSFER RADICAL POLYMERIZATION;

EID: 82955249370     PISSN: 10261265     EISSN: 17355265     Source Type: Journal    
DOI: None     Document Type: Article

References (25)

1. Hong SC, Matyjaszewski K, Fundamentals of supported catalysts for atom transfer radical polymerization (ATRP) and application of an immobilized/ soluble hybrid catalyst system to ATRP, Macromolecules, 35, 7592-7605, 2002.
2. Matyjaszewski K, Radical nature of Cu-catalyzed controlled radical polymerizations (atom transfer radical polymerization), 31, 4710-4717, 1998.
3. Wang JS, Matyjaszewski K, Controlled/''living'' radical polymerization. Atom transfer radical polymerization in the presence of transition-metal complexes, J Am Chem Soc, 117, 5614-5615, 1995.
4. Sawamoto M, Kamigaito M, Transition-metalcatalyzed living-radical polymerization, Chemtech, 29, 30-38, 1999.
5. Matyjaszewski K, Transition metal catalysis in controlled radical polymerization: Atom transfer radical polymerization, Chem Eur J, 5, 3095-3102, 1999. (Pubitemid 129611754)
6. Patten TE, Matyjaszewski K, Copper (I)-catalyzed atom transfer radical polymerization, Acc Chem Res, 32, 895-903, 1999.
7. Matyjaszewski K, Patten TE, Atom transfer radical polymerization and the synthesis of polymeric materials, Adv Mater, 10, 901-915, 1998. (Pubitemid 128539708)
8. Matyjaszewski K, Xia JH, Atom transfer radical polymerization, Chem Rev, 101, 2921-2990, 2001. (Pubitemid 35377809)
9. Coessens V, Pintauer T, Matyjaszewski K, Functional polymers by atom transfer radical polymerization, Prog Polym Sci, 26, 337-377, 2001. (Pubitemid 32427643)
10. Wu YF, Liu SQ, He L, Activators generated electron transfer for atom transfer radical polymerization for immunosensing, Biosens Bioelect, 26, 970-975, 2010.
11. Min K, Gao H, Matyjaszewski K, Preparation of homopolymers and block copolymers in miniemulsion by ATRP using activators generated by electron transfer (AGET), J Am Chem Soc, 127, 3825-3830, 2005. (Pubitemid 40411422)
12. Min K, Matyjaszewski K, Atom transfer radical polymerization in microemulsion, Macromolecules, 38, 8131-8134, 2005. (Pubitemid 41476073)
13. Jakubowski W, Matyjaszewski K, Activator generated electron transfer for atom transfer radical polymerization, Macromolecules, 38, 4139-4146, 2005. (Pubitemid 40751129)
14. Tsarevsky NV, Matyjaszewski K, ''Green'' atom transfer radical polymerization: From process design to preparation of well-defined environmentally friendly polymeric materials, Chem Rev, 107, 2270-2299, 2007. (Pubitemid 47029094)
15. Magenau AJD, Kwak Y, Matyjaszewski K, ATRP of methacrylates utilizing CuIIX2/L and copper wire, Macromolecules, 43, 9682-9689, 2010.
16. Seeliger F, Matyjaszewski K, Temperature effect on activation rate constants in ATRP: New mechanistic insights into the activation process, Macromolecules, 42, 6050-6055, 2009.
17. Matyjaszewski K, Wei M, Xia J, Xia JH, McDermott NE, Controlled/ ''living'' radical polymerization of styrene and methyl methacrylate catalyzed by iron complexes, Macromolecules, 30, 8161-8164, 1997. (Pubitemid 127569623)
18. Ando T, Kamigaito M, Sawamoto M, Iron(II) chloride complexes for living radical polymerization of methyl methacrylate, Macromolecules, 30, 4507-4510, 1997.
19. He D, Xue Z, Khan MY, Noh SK, Lyoo WS, Phosphorus ligands for iron(III)-mediated ATRP of styrene via generation of activators by monomer addition, J Polym Sci, Part A: Polym Chem, 48, 144-151, 2010.
20. Zhang LF, Cheng ZP, Lü YT, Zhu XL, A highly active iron-based catalyst system for the AGET ATRP of styrene, Macromol Rapid Commun, 30, 543-547, 2009.
21. Zhang LF, Cheng ZP, Shia SP, Lia QH, Zhu XL, AGETATRP of methyl methacrylate catalyzed by FeCl3/iminodiacetic acid in the presence of air, Polymer, 49, 3054-3059, 2008.
22. Matyjaszewski K, Nakagawa Y, Jasieczek CB, Polymerization of n-butyl acrylate by atom transfer radical polymerization. Remarkable effect of ethylene carbonate and other solvents, Macromolecules, 31, 1535-1541, 1998. (Pubitemid 128587223)
23. Sharma R, Goyal A, Caruthers JM, Won YY, Inhibitive chain transfer to ligand in the ATRP of n-butyl acrylate, Macromolecules, 39, 4680-4689, 2006. (Pubitemid 44106203)
24. Li WW, Min K, Matyjaszewski K, Stoffelbach F, Charleux B, PEO-based block copolymers and homopolymers as reactive surfactants for AGET ATRP of butyl acrylate in miniemulsion, Macromolecules, 41, 6387-6392, 2008.
25. Ohno S, Matyjaszewski K, Controlling grafting density and side chain length in poly(n-butyl acrylate) by ATRP copolymerization of macromonomers, J Polym Sci, Part A: Polym Chem, 44, 5454-5467, 2006. (Pubitemid 44519419)