Sorption reversibility kinetics in the ternary system radionuclide-bentonite colloids/nanoparticles-granite fracture filling material

Applied Geochemistry

Volumn 26, Issue 12, 2011, Pages 2226-2237

  Huber, F ^a,b   Kunze, P ^a   Geckeis, H ^a   Schafer T ^a,b  

^a KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

^b FREIE UNIVERSITÄT BERLIN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

DATA YIELDS; DRIVING FORCES; FRACTURE FILLING; GROUND WATER CONDITION; ION DESORPTION; MINERAL SURFACES; MINERALOGICAL COMPOSITIONS; RADIONUCLIDE MIGRATION; SIZE FRACTION; SURFACE AREA; SWITZERLAND;

BENTONITE; COLLOID CHEMISTRY; COLLOIDS; DESORPTION; FILLING; FRACTURE; GROUNDWATER; MATERIALS; METAL IONS; RADIOISOTOPES; TERNARY SYSTEMS;

SURFACES;

BENTONITE; COLLOID; DESORPTION; FRACTURE NETWORK; GROUNDWATER POLLUTION; GROUNDWATER RESOURCE; KINETICS; MINERALOGY; NANOTECHNOLOGY; PH; RADIONUCLIDE; SORPTION; SURFACE AREA;

BERN [SWITZERLAND]; GRIMSEL; SWITZERLAND;

EID: 82155196430     PISSN: 08832927     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.apgeochem.2011.08.005     Document Type: Article

References (40)

1. Alexander, W.R., Ota, K., Frieg, B., 2001. The NAGRA-JNC in situ study of safety relevant radionuclide retardation in fractured crystalline rock II: the RRP project methodology development, field and laboratory tests. NAGRA Technical Report Series NTB 00-06, Wettingen, Switzerland.
2. 2 solution. Radiochim. Acta 2004, 92:537-543.
3. 137Cs on reference minerals, with and without inorganic and organic surface coatings. J. Environ. Radioact. 2008, 99:831-840.
4. 3)(aq.) species. Radiochim. Acta 2001, 89:511-518.
5. Bouby, M., Geckeis, H., Lützenkirchen, J., Mihai, S., Schäfer, T., 2009. Interaction of bentonite colloids with Eu and Th in presence of humic acid: a flow field-flow fractionation study. In: 4th Ann. Workshop Proc. Integrated Project Fundamental Processes of Radionuclide Migration - 6th EC FP IP FUNMIG, FZKA Report 7461, pp. 271-279.
6. Bouby, M., Geckeis, H., Lützenkirchen, J., Mihai S., Schäfer, T., 2010. Interaction of bentonite colloids with Eu, Th and U in presence of humic acid: a flow field-flow fractionation study. Geochim. Cosmochim. Acta, submitted.
7. Cama J., Ganor J., Ayora C., Lasaga A. Smectite dissolution kinetics at 80°C and pH 8 8. Geochim. Cosmochim. Acta 2000, 64:2701-2717.
8. Comans R.N.J. Adsorption, desorption and isotopic exchange of cadmium on illite: evidence for complete reversibility. Water Res. 1987, 21:1573-1576.
9. Comans R.N.J., Haller M., Depreter P. Sorption of cesium on illite - nonequilibrium behavior and reversibility. Geochim. Cosmochim. Acta 1991, 55:433-440.
10. Coppin F., Castet S., Berger G., Loubet M. Microscopic reversibility of Sm and Yb sorption onto smectite and kaolinite: experimental evidence. Geochim. Cosmochim. Acta 2003, 67:2515-2527.
11. De Koning A., Comans R.N.J. Reversibility of radiocaesium sorption on illite. Geochim. Cosmochim. Acta 2004, 68:2815-2823.
12. Denison F.H., Garnier-Laplace J. The effects of database parameter uncertainty on uranium(VI) equilibrium calculations. Geochim. Cosmochim. Acta 2005, 69:2183-2191.
13. Flügge, J., Küntzel, M., Schäfer, T., Gaus, I., Noseck, U., 2010. Modeling colloid-bound radionuclide transport at the Grimsel Test Site. In: International Groundwater Symp. IAHR. 2010. Valencia, Spain.
14. Galunin E., Alba M.D., Avilés M.A., Santos M.J., Vidal M. Reversibility of La and Lu sorption onto smectites: implications for the design of engineered barriers in deep geological repositories. J. Hazard. Mater. 2009, 172:1198-1205.
15. Geckeis H., Schäfer T., Hauser W., Rabung T., Missana T., Degueldre C., Möri A., Eikenberg J., Fierz T., Alexander W.R. Results of the Colloid and Radionuclide Retention experiment (CRR) at the Grimsel Test Site (GTS), Switzerland - impact of reaction kinetics and speciation on radionuclide migration. Radiochim. Acta 2004, 92:765-774.
16. Grenthe I., Stumm W., Laaksuharju M., Nilsson A.C., Wikberg P. Redox potentials and redox reactions in deep ground water systems. Chem. Geol. 1992, 98:131-150.
17. Guillaumont R., Fanghänel T., Fuger J., Grente I., Neck V., Palmer D.A., Rand M.H. Update on the Chemical Thermodynamics of Uranium, Neptunium, Plutonium, Americium and Technetium 2003, Elsevier, Amsterdam.
18. Kersting A.B., Efurd D.W., Finnegan D.L., Rokop D.J., Smith D.K., Thompson J.L. Migration of plutonium in ground water at the Nevada Test Site. Nature 1999, 397:56-59.
19. Kim J.I., Buckau G., Baumgärtner F., Moon H., Lux D. Colloid generation and the actinide migration in Gorleben ground waters. Mater. Res. Soc. Symp. Proc. 1984, 26:31-40.
20. Latrille C., Ly J., Herbette M. Retention of Sn(IV) and Pu(IV) onto four argillites from the Callovo-Oxfordian level at Bure (France) from eight equilibrated sedimentary waters. Radiochim. Acta 2006, 94:421-427.
21. Lührmann, L., 1999. Modellierung des kolloidgetragenen Schadstofftransports unter Berücksichtigung von Sorptions- und Filtrationsprozessen. PhD Thesis. Univ. Erlangen-Nürnberg.
22. McCarthy J.F., Zachara J.M. Subsurface transport of contaminants: mobile colloids in the subsurface environment may alter the transport of contaminants. Environ. Sci. Technol. 1989, 23:497-502.
23. Missana, T., Geckeis, H. (Eds.), 2006. Grimsel Test Site - Investigation Phase V. The CRR Final Project Report Series II: Supporting Laboratory Experiments with Radionuclides and Bentonite Colloids NAGRA Technical Report Series NTB 03-02, Wettingen, Switzerland.
24. Missana T., Alonso U., Garcia-Gutierrez M., Mingarro M. Role of bentonite colloids on europium and plutonium migration in a granite fracture. Appl. Geochem. 2008, 23:1484-1497.
25. Möri A., Alexander W.R., Geckeis H., Hauser W., Schäfer T., Eikenberg J., Fierz T., Degueldre C., Missana T. The colloid and radionuclide retardation experiment at the Grimsel Test Site: influence of bentonite colloids on radionuclide migration in a fractured rock. Colloids Surf. A - Physicochem. Eng. Aspects 2003, 217:33-47.
26. Neck V., Altmaier M., Fanghänel Th. Solubility of plutonium hydroxides/hydrous oxides under reducing conditions and in the presence of oxygen. CR Chim. 2007, 10:959-977.
27. Neck, V., Altmaier, M., Fellhauer, D., Runke, J., Fanghänel, T., 2009. Quantification of the redox potential for the reduction of Np(V) in non-complexing aqueous solutions at pH 5-10. In: 1st Ann. Workshop Proc. 7th EC FP - Recosy CP, Barcelona 10-12th.
28. Neck, V., Fanghänel, Th., Kim, J.I., 1999. Thermodynamische Modellierung von Technetium in natürlichen aquatischen Systemen. FZKA 6340, Forschungszentrum Karlsruhe, Karlsruhe.
29. Noseck, U., Klotz, D., 2002. Modelling of colloid-facilitated contaminant transport with the computer code TRAPIC: theoretical basis and application. Radionuclide Retention in Geologic Media. Workshop Proc. pp. 231-239.
30. Plaschke M., Schäfer T., Bundschuh T., Manh T.N., Knopp R., Geckeis H., Kim J.I. Size characterization of bentonite colloids by different methods. Anal. Chem. 2001, 73:4338-4347.
31. Puigdomenech, I., 2004. HYDRA and MEDUSA chemical equilibrium software. Software and documentation. http://web.telia.com/~u15651596/.
32. Rabung T., Pierret M.C., Bauer A., Geckeis H., Bradbury M.H., Baeyens B. Sorption of Eu(III)/Cm(III) on Ca-montmorillonite and Na-illite. Part 1: Batch sorption and time-resolved laser fluorescence spectroscopy experiments. Geochim. Cosmochim. Acta 2005, 69:5393-5402.
33. Rand M., Fuger J., Grenthe I., Neck V., Rai D. Chemical Thermodynamics of Thorium 2009, OECD, Nuclear Energy Agency. OECD Publishing.
34. Rothe J., Walther C., Brendebach B., Büchner S., Fuss M., Denecke M.A., Geckeis H. A combined XAFS, ESI TOF-MS and LIBD study on the formation of polynuclear Zr(IV), Th(IV) and Pu(IV) species. J. Phys.: Conf. Ser. 2009, 190 012188.
35. Schäfer, T., Noseck, U. (Eds), 2010. Colloid/ Nanoparticle formation and mobility in the context of deep geological nuclear waste disposal. Project KOLLORADO-1; Final report. FZKA 7515, Forschungszentrum Karlsruhe, Karlsruhe.
36. Schäfer T., Geckeis H., Bouby M., Fanghänel T. U, Th, Eu and colloid mobility in a granite fracture under near-natural flow conditions. Radiochim. Acta 2004, 92:731-737.
37. Stumm W., Morgan J. Aquatic Chemistry: Chemical Equilibria and Rates in Natural Waters 1996, John Wiley and Sons, Inc., New York. 3rd ed.
38. Turner N.B., Ryan J.N., Saiers J.E. Effect of desorption kinetics on colloid-facilitated transport of contaminants: cesium, strontium, and illite colloids. Water Resour. Res. 2006, 42:W12509. 10.1029/2006WR004972.
39. Villar, M.V., Martin, P.L., Pelayo, M., Ruiz, B., Rivas, P., Alonso, E., Lloret, A., Pintado, X., Gens, A., Linares, J., Huertas, F., Caballero, E., Jimenz de Cisneros, C., Obis, J., Perez, A., Velasco, J., 1998. FEBEX bentonite: origin, properties and fabrication of blocks (full-scale engineered barriers experiment in crystalline host rock). 05/98, Enresa (empresa nacional de residuos radiactivos, s.a.), Madrid, Spain.
40. Wold, S., 2010. Sorption of prioritized elements on montmorillonite colloids and their potential to transport radionuclides. SKB Technical Report TR-10-20 Swedish Nuclear Fuel and Waste Management Co (SKB), Stockholm, Sweden.