Preparation and characterization of Cp-functionalized cycloheptatrienyl- cyclopentadienyl titanium sandwich complexes (troticenes)

Journal of Organometallic Chemistry

Volumn 696, Issue 26, 2012, Pages 4281-4292

  Tagne Kuate, Alain C ^a   Mohapatra, Swagat K ^a   Daniliuc, Constantin G ^a   Jones, Peter G ^a   Tamm, Matthias ^a  

^a TECHNICAL UNIVERSITY OF BRAUNSCHWEIG   (Germany)

Author keywords

Cycloheptatrienyl complexes; Cyclopentadienyl ligands; Sandwich complexes; Titanium

Indexed keywords

CROSS COUPLING REACTIONS; CYCLOHEPTATRIENYL COMPLEXES; CYCLOPENTADIENYL LIGANDS; CYCLOPENTADIENYLS; ELECTROPHILES; ETHOXIDES; FULVALENE COMPLEXES; HAFNOCENE; HETEROBIMETALLICS; IODOBENZENE; ORGANOTINS; OXO COMPLEXES; PARTIAL HYDROLYSIS; SANDWICH COMPLEXES; SINGLE CRYSTAL X-RAY DIFFRACTION ANALYSIS; UNSYMMETRICAL STRUCTURE; ZIRCONOCENES;

CHEMICAL REACTIONS; CHLORINE COMPOUNDS; HAFNIUM; METALLIC COMPOUNDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANOMETALLICS; SINGLE CRYSTALS; TIN; TITANIUM; X RAY DIFFRACTION; ZIRCONIUM; ZIRCONIUM COMPOUNDS;

X RAY DIFFRACTION ANALYSIS;

EID: 81355136251     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2011.10.005     Document Type: Article

References (70)

1. G. Wilkinson, M. Rosenblum, M.C. Whiting, and R.B. Woodward J. Am. Chem. Soc. 74 1952 2125
2. E.O. Fischer, and W. Pfab Z. Naturforsch 7b 1952 377
3. Special issue: 50th anniversary of the discovery of ferrocene R.D. Adams J. Organomet. Chem. 2001 637 639
4. B. Bildstein Coord. Chem. Rev. 206-207 2000 369
5. T.J. Colacot Platinium Met. Rev. 45 2001 22
6. R.G. Arrayás, J. Adrio, and J.C. Carretero Angew. Chem. Int. Ed. 45 2006 7674
7. J.N. Long, and K. Kowalski Ferrocene containing polymers and dendrimers S. Petr, Ferrocene: Ligands, Materials and Biomolecues 2008 Wiley Weinheim
8. V. Chandrasekhar Inorganic and Organometallic Polymers 2005 Springer Heidelberg
9. P. Nguyen, P. Gomez-Elipe, and I. Manners Chem. Rev. 99 1999 1515
10. G. Jaouen, and N. Metzler-Nolte Medicinal Organometallic Chemistry 2010 Springer Berlin
11. M. Salmain, and N. Metzler-Nolte Bioorganometallic chemistry of ferrocene S. Petr, Ferrocene: Ligands, Materials and Biomolecules 2008 Wiley Weinheim
12. Ferrocene ligands, part 1 S. Petr Ferrocene: Ligands, Materials and Biomolecues 2008 Wiley Weinheim
13. J. Heck, and M. Dede Ferrocene based electro-optical materials S. Petr, Ferrocene: Ligands, Materials and Biomolecues 2008 Wiley Weinheim
14. M.L.H. Green, and D.K.P. Ng Chem. Rev. 95 1995 439
15. for M = Hf, see S. Büschel, T. Bannenberg, C.G. Hrib, A. Glöckner, P.G. Jones, and M. Tamm J. Organomet. Chem. 694 2009 1244
16. for M = Ta, see W. Noh, and G.S. Girolami Inorg. Chem. 45 2008 535
17. C.J. Groenenboom, H.J. de Liefde Meijer, and F. Jellinek J. Organomet. Chem. 69 1974 235
18. L.B. Kool, M. Ogasa, M.D. Rausch, and R.D. Rogers Organometallics 8 1989 1785
19. M. Ogasa, M.D. Rausch, and R.D. Rogers J. Organomet. Chem. 403 1991 279
20. R. Fierro, M.D. Rausch, R.D. Rogers, and M. Herberhold J. Organomet. Chem. 472 1994 87
21. M. Tamm, A. Kunst, T. Bannenberg, E. Herdtweck, P. Sirsch, C.J. Elsevier, and J.M. Ernsting Angew. Chem. Int. Ed. 43 2004 5530
22. M. Tamm, A. Kunst, and E. Herdtweck Chem. Commun. 2005 1729
23. M. Tamm, A. Kunst, T. Bannenberg, S. Randoll, and P.G. Jones Organometallics 26 2007 417
24. M. Tamm Chem. Commun. 2008 3089
25. C. Elschenbroich, F. Paganelli, M. Nowotny, B. Neumüller, and O. Burghaus Z. Anorg. Allg. Chem. 630 2004 1599
26. H. Braunschweig, M. Lutz, K. Radacki, A. Schaumlöffel, F. Seeler, and C. Unkelbach Organometallics 25 2006 4433
27. A. Bartole-Scott, H. Braunschweig, T. Kupfer, M. Lutz, I. Manners, T.-I. Nguyen, K. Radacki, and F. Seeler Chem. Eur. J. 12 2006 1266
28. H. Braunschweig, T. Kupfer, M. Lutz, and K. Radacki J. Am. Chem. Soc. 129 2007 8893
29. H. Braunschweig, M. Friedrich, T. Kupfer, and K. Radacki Chem. Commun. 47 2011 3998
30. S.K. Mohapatra, S. Büschel, C. Daniliuc, P.G. Jones, and M. Tamm J. Am. Chem. Soc. 131 2009 17014
31. H. Braunschweig, M. Fuß, S.K. Mohapatra, K. Kraft, T. Kupfer, M. Lang, K. Radacki, C.G. Daniliuc, P.G. Jones, and M. Tamm Chem. Eur. J. 16 2010 11732
32. H.T. Verkouw, M.E.E. Veldman, C.J. Groenenboom, H.O. van Oven, and H.J. de Liefde Meijer J. Organomet. Chem. 102 1975 49
33. B. Demerseman, and P.H. Dixneuf J. Organomet. Chem. 210 1981 C20
34. B. Demerseman, P.H. Dixneuf, G. Douglade, and R. Merier Inorg. Chem. 21 1982 3942
35. S. Büschel, A.-K. Jungton, T. Bannenberg, S. Randoll, C.G. Hrib, P.G. Jones, and M. Tamm Chem. Eur. J. 15 2009 2176
36. G. Wilkinson, and J.M. Birmingham J. Chem. Soc. A 1954 4281
37. P. Geymayer, E.G. Rochow, and U. Wannagat Angew. Chem. Int. Ed. 3 1964 633
38. B.-L. Li, M.A. Goodman, and R.H. Neilson Inorg. Chem. 23 1984 1368
39. T. Hayashi, M. Konishi, and M. Kumada Tetrahedron Lett. 21 1979 1871
40. G.M. Sheldrick Acta. Crystallogr. A64 2008 112
41. A.L. Spek J. Appl. Cryst. 36 2003 7
42. R. Broussier, A. Da Rold, B. Gautheron, Y. Dromzee, and Y. Jeannin Inorg. Chem. 29 1990 1817
43. T.N. Mitchell J. Organomet. Chem. 49 1973 189
44. M. Kumar, F. Cervantes-Lee, K.H. Pannell, and J. Shao Organometallics 27 2008 4739
45. D. Gourier, and D. Samuel Inorg. Chem. 27 1988 3018
46. K.A. lyssenko, M.Y. Antipin, and S.Y. Ketkov Russ. Chem. Bull. Int. Ed. 50 2001 130
47. M.J. MacLachlan, J. Zheng, K. Thieme, A.J. Lough, I. Manners, C. Mordas, R. LeSuer, W.E. Geiger, L.M. Liable-Sands, and A.L. Rheingold Polyhedron 19 2000 275
48. F. Jäkle, A. Berenbaum, A.J. Lough, and I. Manners Chem. Eur. J. 6 2000 2762
49. J.A. Gamboa, A. Sundararaman, L. Kakalis, A.J. Lough, and F. Jäkle Organometallics 21 2002 4169
50. B. Ferber, S. Top, R. Welter, and G. Jaouen Chem. Eur. J. 112 2006 2081
51. C. Elschenbroich, O. Schiemann, O. Burghaus, K. Harms, and J. Pebler Organometallics 18 1999 3273
52. M. Wedler, H.W. Roesky, and F.T. Edelmann Z. Naturforsch. B. Chem. Sci. 43 1988 1461
53. V. Chandrasekhar, P. Sasikumar, P. Singh, R. Thirumoorthi, and T. Senapati J. Chem. Sci. 120 2008 105
54. V. Chandrasekhar, K. Gopal, S. Nagendran, P. Singh, A. Steiner, S. Zacchini, and J.F. Bickley Chem. Eur. J. 11 2005 5437
55. K. Jurkschat, C. Kruger, and J. Meunier-Piret Main Group Met. Chem. 15 1992 61
56. C. Glidewell, and D.C. Liles Acta Crystallogr. Sect. B. 34 1978 129
57. S. Kerschl, B. Wrackmeyer, D. Männig, H. Nöth, and R. Staudigl Z. Naturforsch. B. Chem. Sci. 42 1987 387
58. C. Glidewell, and D.C. Liles J. Chem. Soc. Chem. Commun. 1979 93
59. A. Houlton, R.M.G. Roberts, and J. Silver J. Chem. Soc. Dalton Trans. 1990 1543
60. G. Kehr, R. Fröhlich, B. Wibbeling, and G. Erker Chem. Eur. J. 6 2000 258
61. J.L. Calderon, F.A. Cotton, B.G. DeBoer, and J. Takats J. Am. Chem. Soc. 28 1971 3593
62. J.L. Calderon, F.A. Cotton, and J. Takats J. Am. Chem. Soc. 28 1971 3587
63. L.N. Zkharov, Y.T. Struchkov, V.V. Sharutin, and O.N. Suvorova Cryst. Struct. Commun. 8 1979 436
64. K.-H. Thiele, and C. Krüger Z. Anorg. All. Chem. 590 1990 55
65. W.E. Hunter, D.C. Hrncir, R.V. Bynum, R.A. Penttila, and J.L. Atwood Organometallics 2 1983 750
66. F.R. Fronczek, E.C. Baker, P.R. Sharp, K.N. Raymond, H.G. Alt, and M.D. Rausch Inorg. Chem. 15 1976 2285
67. A.C. McDonald, and J. Trotter Acta. Crystallogr. 17 1964 872
68. C. Elschenbroich, J. Plackmeyer, K. Harms, O. Burghaus, and J. Pebler Organometallics 22 2003 3367
69. J.D. Zeinstra, and J.L. De Boer J. Organomet. Chem. 54 1973 207
70. C. Bolm, and F.E. Hahn Activating Unreactive Substrates - The Role of Secondary Interactions 2009 WILEY-VCH Weinheim