Efficient stereoselective total synthesis of (+)-cryptofolione and the first synthesis of (-)-cryptocaryalactone

Synthesis

Volumn , Issue 22, 2011, Pages 3706-3710

  Balasubramanyam, P ^a   Chinna Reddy, Gandolla ^a   Salvanna, Nayaki ^a   Das, Biswanath ^a  

^a INDIAN INSTITUTE OF CHEMICAL TECHNOLOGY   (India)

Author keywords

Keck allylation; lactones; Mitsunobu center inversion; natural products; olefin cross metathesis; total synthesis

Indexed keywords

KECK ALLYLATION; LACTONES; MITSUNOBU CENTER INVERSION; NATURAL PRODUCTS; OLEFIN CROSS METATHESIS; TOTAL SYNTHESIS;

ALLYLATION; OLEFINS; PROPANE; STEREOCHEMISTRY;

STEREOSELECTIVITY;

1 (TERT BUTYLDIMETHYLSILOXY) 3 (TERT BUTYLDIPHENYLSILOXY)HEX 5 ENE; 1 (TERT BUTYLDIMETHYLSILOXY)HEX 5 EN 3 OL; 1 PHENYLOCTA 1,7 DIENE 3,5 DIOL; 2 PYRONE DERIVATIVE; 3 (TERT BUTYLDIMETHYLSILOXY)PROPAN 1 OL; 3 ACETOXY 1 PHENYLOCTA 1,7 DIEN 5 YL ACRYLATE; 5 (TERT BUTYLDIPHENYLSILOXY) 1 PHENYLOCT 7 EN 1 YN 3 OL; 5 (TERT BUTYLDIPHENYLSILOXY)HEX 5 EN 1 OL; 6 [ 3 (2,2 DIMETHYL 6 STYRYL 1,3 DIOXAN 4 YL)PROP 1 ENYL] 5,6 DIHYDRO 2H PYRAN 2 ONE P; CRYPTOCARYALACTONE; CRYPTOFOLIONE; LACTONE DERIVATIVE; UNCLASSIFIED DRUG;

ALLYLATION; ARTICLE; CHEMICAL MODIFICATION; CONTROLLED STUDY; DRUG STRUCTURE; DRUG SYNTHESIS; KECK ALLYLATION; MITSUNOBU CENTER INVERSION; OLEFIN CROSS METATHESIS; SOLVENT EFFECT; STEREOCHEMISTRY; STRUCTURE ACTIVITY RELATION;

EID: 80755138369     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0030-1260246     Document Type: Article

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