Synthesis of poly(aminopropyl/methyl)silsesquioxane particles as effective Cu(II) and Pb(II) adsorbents

Journal of Hazardous Materials

Volumn 196, Issue , 2011, Pages 234-241

  Lu, Xin ^a   Yin, Qiangfeng ^a   Xin, Zhong ^a   Li, Yang ^a   Han, Ting ^a  

^a EAST CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

Author keywords

Adsorption; Copper; Lead; Particle; Poly(aminopropyl methyl)silsesquioxane

Indexed keywords

3-AMINOPROPYLTRIETHOXYSILANE; ADSORBABILITIES; ADSORPTION PHENOMENA; ADSORPTION PROCESS; ADSORPTION TIME; AMINO FUNCTIONALITY; AMINOPROPYL; AQUEOUS MEDIUM; BASE CATALYST; FEED RATIOS; FTIR SPECTROSCOPY; HYDROLYTIC CO-CONDENSATION; KINETIC STUDY; LANGMUIR ISOTHERM; METHYLTRIMETHOXYSILANE; ORGANOSILANES; PB ADSORPTIONS; POLYSILSESQUIOXANES; PSEUDO SECOND ORDER KINETICS; SILSESQUIOXANES;

LEAD; METAL IONS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PH EFFECTS; SILANES; SILICON COMPOUNDS; SOLUTIONS;

ADSORPTION;

3 AMINOPROPYLTRIETHOXYSILANE; ADSORBENT; COPPER; LEAD; METAL ION; SILICON; SILSESQUIOXANE DERIVATIVE; UNCLASSIFIED DRUG;

ADSORPTION; AQUEOUS SOLUTION; CATALYST; CHEMICAL COMPOSITION; CONCENTRATION (COMPOSITION); CONDENSATION; COPPER; FTIR SPECTROSCOPY; HYDROLYSIS; ISOTHERM; LEAD; NUCLEAR MAGNETIC RESONANCE; PARTICULATE MATTER; PH;

ADSORPTION; AQUEOUS SOLUTION; ARTICLE; CATALYST; CHEMICAL COMPOSITION; CONCENTRATION (PARAMETERS); HYDROLYSIS; INFRARED SPECTROSCOPY; KINETICS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PH; SYNTHESIS;

ADSORPTION; COPPER; ENVIRONMENTAL POLLUTANTS; KINETICS; LEAD; MICROSCOPY, ELECTRON, SCANNING; MODELS, THEORETICAL; ORGANOSILICON COMPOUNDS; PROPYLAMINES; SILANES; SOLUTIONS; SPECTROSCOPY, FOURIER TRANSFORM INFRARED; SURFACE PROPERTIES; TIME FACTORS; WASTE DISPOSAL, FLUID;

EID: 80455164514     PISSN: 03043894     EISSN: 18733336     Source Type: Journal    
DOI: 10.1016/j.jhazmat.2011.09.020     Document Type: Article

References (45)

1. Li X.G., Ma X.L., Sun J., Huang M.R. Powerful reactive sorption of silver(I) and mercury(II) onto poly(o-phenylenediamine) microparticles. Langmuir 2009, 25:1675-1684.
2. Kim I.B., Bunz U.H.F. Modulating the sensory response of a conjugated polymer by proteins: an agglutination assay for mercury ions in water. J. Am. Chem. Soc. 2006, 128:2818-2819.
3. + sorption on natural and Na-exchanged clinoptilolite from Eastern Rhodopes, Bulgaria. Micropor. Mesopor. Mater. 2010, 130:32-37.
4. 20. Chem. Eur. J. 2007, 13:51-58.
5. Pollet B., Lorimer J.P., Phull S.S., Hihn J.Y. Sonoelectrochemical recovery of silver from photographic processing solutions. Ultrason. Sonochem. 2000, 7:69-76.
6. Ladhe A.R., Frailie P., Hua D., Darsillo M., Bhattacharyya D. Thiol-functionalized silica-mixed matrix membranes for silver capture from aqueous solutions: experimental results and modeling. J. Membr. Sci. 2009, 326:460-471.
7. Vassileva P., Tzvetkova P., Lakov L., Peshev O. Thiouracil modified activated carbon as a sorbent for some precious and heavy metal ions. J. Porous Mater. 2008, 15:593-599.
8. Chen C.Y., Lin M.S., Hsu K.R. Recovery of Cu(II) and Cd(II) by a chelating resin containing aspartate groups. J. Hazard. Mater. 2008, 152:986-993.
9. Zakhama S., Dhaouadi H., M'Henni F. Nonlinear modelisation of heavy metal removal from aqueous solution using Ulva lactuca algae. Bioresour. Technol. 2011, 102:786-796.
10. Yang H., Xu R., Xue X.M., Li F.T., Li G.T. Hybrid surfactant-templated mesoporous silica formed in ethanol and its application for heavy metal removal. J. Hazard. Mater. 2008, 152:690-698.
11. Pearson R.G. Hard and soft acids and bases. J. Am. Chem. Soc. 1963, 85:3533.
12. Lam K.F., Yeung K.L., McKay G. A rational approach in the design of selective mesoporous adsorbents. Langmuir 2006, 22:9632-9641.
13. Yantasee W., Lin Y.H., Fryxell G.E., Alford K.L., Busche B.J., Johnson C.D. Selective removal of copper(II) from aqueous solutions using fine-grained activated carbon functionalized with amine. Ind. Eng. Chem. Res. 2004, 43:2759-2764.
14. El-Ashgar N., El-Nahhal I. Preconcentration and separation of copper(II) by 3-aminopropylpolysiloxane immobilized ligand system. J. Sol-Gel Sci. Technol. 2005, 34:165-172.
15. El-Ashgar N.M., El-Nahhal I.M. Separation of Cu(II), Ni(II), and Co(II) ions using iminobis(N-2-aminoethylacetamide) polysiloxane-immobilized ligand system. J. Disper. Sci. Technol. 2006, 27:915-919.
16. El-Ashgar N.M., El-Nahhal I.M., Chehimi M.M., Babonneau F., Livage J. Extraction of Co, Ni, Cu, Zn and Cd ions using 2-aminophenylaminopropylpolysiloxane. Environ. Chem. Lett. 2010, 8:311-316.
17. El-Nahhal I.M., El-Ashgar N.M. A review on polysiloxane-immobilized ligand systems: synthesis, characterization and applications. J. Organomet. Chem. 2007, 692:2861-2886.
18. El-Nahhal I.M., El-Ashgar N.M., Chehimi M.M., Bargiela P., Maquet J., Babonneau F., Livage J. Metal uptake by porous iminobis(N-2-aminoethylacetamide)-modified polysiloxane ligand system. Micropor. Mesopor. Mater. 2003, 65:299-310.
19. Mori H., Lanzendorfer M.G., Muller A.H.E., Klee J.E. Silsesquioxane-based nanoparticles formed via hydrolytic condensation of organotriethoxysilane containing hydroxy groups. Macromolecules 2004, 37:5228-5238.
20. Liu S.M., Lang X.M., Ye H., Zhang S.J., Zhao J.Q. Preparation and characterization of copolymerized aminopropyl/phenylsilsesquioxane microparticles. Eur. Polym. J. 2005, 41:996-1001.
21. Du H.W., Hamilton P.D., Reilly M.A., d'Avignon A., Biswas P., Ravi N. A facile synthesis of highly water-soluble, core-shell organo-silica nanoparticles with controllable size via sol-gel process. J. Colloid Interface Sci. 2009, 340:202-208.
22. Lu X., Yin Q.F., Xin Z., Zhang Z.Q. Powerful adsorption of silver(I) onto thiol-functionalized polysilsesquioxane microspheres. Chem. Eng. Sci. 2010, 65:6471-6477.
23. Beari F., Brand M., Jenkner P., Lehnert R., Metternich H.J., Monkiewicz J., Siesler H.W. Organofunctional alkoxysilanes in dilute aqueous solution: new accounts on the dynamic structural mutability. J. Organomet. Chem. 2001, 625:208-216.
24. Sankaraiah S., Lee J.M., Kim J.H., Choi S.W. Preparation and characterization of surface-functionalized polysilsesquioxane hard spheres in aqueous medium. Macromolecules 2008, 41:6195-6204.
25. Noda I., Kamoto T., Yamada M. Size-controlling synthesis of narrowly distributed particles of methylsilsesquioxane derivatives. Chem. Mater. 2000, 12:1708-1714.
26. Arkhireeva A., Hay J.N., Oware W. A versatile route to silsesquioxane nanoparticles from organically modified silane precursors. J. Non-Cryst. Solids 2005, 351:1688-1695.
27. Caravajal L.D.G.S., Quinting G.R., Maciel G.E. Structural characterization of (3-aminopropyl)triethoxysilane-modified silicas by silicon-29 and carbon-13 nuclear magnetic resonance. Anal. Chem. 1988, 60:1776-1786.
28. Arkhireeva A., Hay J.N. Synthesis of sub-200nm silsesquioxane particles using a modified Stober sol-gel route. J. Mater. Chem. 2003, 13:3122-3127.
29. Matsumoto T., Takayama Y., Wada N., Onoda H., Kojima K., Yamada H., Wakabayashi H. Acid-free synthesis of poly-organo-siloxane spherical particles using a W/O emulsion. J. Mater. Chem. 2003, 13:1764-1770.
30. Nair B.P., Pavithran C. Bifunctionalized hybrid silica spheres by hydrolytic cocondensation of 3-aminopropyltriethoxysilane and vinyltriethoxysilane. Langmuir 2010, 26:730-735.
31. Ho Y.S., McKay G. The kinetics of sorption of basic dyes from aqueous solution by sphagnum moss peat. Can. J. Chem. Eng. 1998, 76:822-827.
32. Shahbazi A., Younesi H., Badiei A. Functionalized SBA-15 mesoporous silica by melamine-based dendrimer amines for adsorptive characteristics of Pb(II), Cu(II) and Cd(II) heavy metal ions in batch and fixed bed column. Chem. Eng. J. 2011, 168:505-518.
33. Tian Y.A., Yin P., Qu R.J., Wang C.H., Zheng H.G., Yu Z.X. Removal of transition metal ions from aqueous solutions by adsorption using a novel hybrid material silica gel chemically modified by triethylenetetraminomethylenephosphonic acid. Chem. Eng. J. 2010, 162:573-579.
34. Tzvetkova P., Vassileva P., Nickolov R. Modified silica gel with 5-amino-1,3,4-thiadiazole-2-thiol for heavy metal ions removal. J. Porous Mater. 2010, 17:459-463.
35. El-Ashgar N.M., El-Nahhal I.M., Chehimi M.M., Babonneau F., Livage J. Preparation of ethylenediaminetriacetic acid silica-gel immobilised ligand system and its application for trace metal analysis in aqueous samples. Int. J. Environ. Anal. Chem. 2009, 89:1057-1069.
36. Pereira A.S., Ferreira G., Caetano L., Castro R.S.D., dos Santos A., Padilha P.M., Castro G.R. 4-Amine-2-mercaptopyrimidine modified silica gel applied in Cd(II) and Pb(II) extraction from an aqueous medium. Pol. J. Chem. Technol. 2010, 12:7-11.
37. Kannamba B., Reddy K.L., AppaRao B.V. Removal of Cu(II) from aqueous solutions using chemically modified chitosan. J. Hazard. Mater. 2010, 175:939-948.
38. Neghlani P.K., Rafizadeh M., Taromi F.A. Preparation of aminated-polyacrylonitrile nanofiber membranes for the adsorption of metal ions: comparison with microfibers. J. Hazard. Mater. 2011, 186:182-189.
39. Xu F.Q., Zhang N.N., Long Y., Si Y.M., Liu Y., Mi X., Wang X.D., Xing F.B., You X.D., Gao J.P. Porous CS monoliths and their adsorption ability for heavy metal ions. J. Hazard. Mater. 2011, 188:148-155.
40. Wang L.Y., Yang L.Q., Li Y.F., Zhang Y., Ma X.J., Ye Z.F. Study on adsorption mechanism of Pb(II) and Cu(II) in aqueous solution using PS-EDTA resin. Chem. Eng. J. 2010, 163:364-372.
41. He Q., Hu Z., Jiang Y., Chang X.J., Tu Z.F., Zhang L.N. Preconcentration of Cu(II), Fe(III) and Pb(II) with 2-((2-aminoethylamino)methyl)phenol-functionalized activated carbon followed by ICP-OES determination. J. Hazard. Mater. 2010, 175:710-714.
42. Phuengprasop T., Sittiwong J., Unob F. Removal of heavy metal ions by iron oxide coated sewage sludge. J. Hazard. Mater. 2011, 186:502-507.
43. Ofomaja A.E., Naidoo E.B., Modise S.J. Biosorption of copper(II) and lead(II) onto potassium hydroxide treated pine cone powder. J. Environ. Manage. 2010, 91:1674-1685.
44. El Nahhal I.M., Chehimi M.M., Cordier C., Dodin G. XPS, NMR and FTIR structural characterization of polysiloxane-immobilized amine ligand systems. J. Non-Cryst. Solids 2000, 275:142-146.
45. 2+. Colloids Surf. A 2009, 349:61-68.