Enzyme-like control of carbocation deprotonation regioselectivity in supramolecular catalysis of the nazarov cyclization

Angewandte Chemie - International Edition

Volumn 50, Issue 45, 2011, Pages 10570-10573

  Hastings, Courtney J ^a,b   Backlund, Mikael P ^a,b   Bergman, Robert G ^a,b   Raymond, Kenneth N ^a,b  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

Author keywords

cage compounds; carbocations; electrocyclic reactions; homogeneous catalysis; supramolecular chemistry

Indexed keywords

CAGE COMPOUNDS; CARBOCATIONS; ELECTROCYCLIC REACTIONS; HOMOGENEOUS CATALYSIS; NAZAROV CYCLIZATION; REGIO-SELECTIVE; REGIOCHEMISTRY; SUPRAMOLECULAR CATALYSIS;

CATALYSIS; POSITIVE IONS; REACTION KINETICS; REGIOSELECTIVITY; STEREOCHEMISTRY; SUPRAMOLECULAR CHEMISTRY;

DEPROTONATION;

CYCLOPENTANE DERIVATIVE; ENZYME; PROTON;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; CYCLIZATION; METABOLISM; STEREOISOMERISM;

CATALYSIS; CYCLIZATION; CYCLOPENTANES; ENZYMES; MODELS, MOLECULAR; PROTONS; STEREOISOMERISM;

EID: 80155125185     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201105325     Document Type: Article

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