The activity of individual ions. A conceptual discussion of the relation between the theory and the experimentally measured values

Fluid Phase Equilibria

Volumn 312, Issue 1, 2011, Pages 79-84

  Wilczek Vera, Grazyna ^a   Vera, Juan H ^a  

^a MCGILL UNIVERSITY   (Canada)

Author keywords

Electrochemical cells with liquid junction; Electrolyte solutions; Ion selective electrodes; Ionic activities; Junction potential

Indexed keywords

CLOSED SYSTEMS; ELECTROLYTE SOLUTIONS; ELECTROLYTE SYSTEMS; EXPERIMENTAL DATA; INDIVIDUAL ION; IONIC ACTIVITIES; IONIC ACTIVITY; ITS EVALUATION; JUNCTION POTENTIAL; LIQUID JUNCTIONS; PARTIAL MOLAR PROPERTIES; PHYSICAL WORLD;

CHEMICAL POTENTIAL; CHEMICALS; ELECTROLYTIC CELLS; ION SELECTIVE ELECTRODES; THERMODYNAMICS;

ELECTROLYTES;

EID: 80054747198     PISSN: 03783812     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.fluid.2011.09.009     Document Type: Article

References (28)

1. Zarubin D.P. J. Chem. Thermodyn. 2011, 43(8):1135-1152.
2. J.H. Vera, G. Wilczek-Vera, J. Chem. Thermodyn., to be published.
3. D.P. Zarubin, J. Chem. Thermodyn., to be published.
4. Wilczek-Vera G., Vera J.H. Fluid Phase Equilib. 2005, 236:96-110.
5. Malatesta F. Fluid Phase Equilib. 2010, 295:244-248.
6. Malatesta F. Chem. Eng. Sci. 2010, 65:675-679.
7. Malatesta F. J. Chem. Eng. Data 2009, 5:2978.
8. Taylor P.B. J. Phys. Chem. 1927, 31:1478-1500.
9. Prausnitz J.M., Lichtenthaler R.M., de Azevedo A.E. Molecular Thermodynamics of Fluid-Phase Equilibria 1999, Prentice Hall. third ed.
10. Lewis G.N., Randall M. Thermodynamics and the Free Energy of Chemical Substances 1923, McGraw-Hill, N.Y.
11. J.W. Gibbs, in: J.W Gibbs, W.R. Longley, R.G. Van Name (Eds.), The Collected Works, Yale University Press, New Haven, reprinted 1957.
12. De Donder T. Thermodynamic Theory of Affinity: A Book of Principles 1936, Oxford University Press, Oxford (England).
13. Lewis G.N., Randall M. J. Am. Chem. Soc. 1921, 43:1112-1154.
14. Schrödinger E. What is Life? With Mind and Matter and Autobiographical Sketches 2010, Canto, Cambridge University Press, N.Y.
15. Wilczek-Vera G., Vera J.H. Chem. Eng. Sci. 2011, 66:3782-3791.
16. Wilczek-Vera G., Rodil E., Vera J.H. AIChE J. 2004, 50:445-462.
17. Rodil E., Vera J.H. Fluid Phase Equilib. 2003, 205:115-132. (211 (2003) 289).
18. Wilczek-Vera G., Rodil E., Vera J.H. Fluid Phase Equilib. 2006, 244:33-45.
19. Wilczek-Vera G., Rodil E., Vera J.H. Fluid Phase Equilib. 2006, 241:59-69.
20. Pitzer K.S., Brewer L. Thermodynamics 1961, McGraw-Hill, NY, revised. 2nd ed. M. Randall, G.N. Lewis (Eds.).
21. Wilczek-Vera G., Vera J.H. Ind. Eng. Chem. Res. 2009, 48:6436-6440.
22. Cheluget E., Wilczek-Vera G., Vera J.H. Can. J. Chem. Eng. 1992, 70:313-319.
23. Lin C.-l., Lee L.-s. Fluid Phase Equilib. 2003, 205:69-88.
24. Malatesta F. J. Chem. Eng. Data 2009, 54:2978.
25. Harned H.S. J. Phys. Chem. 1926, 30:433-456.
26. Guggenheim E.A. J. Phys. Chem. 1929, 33:842-849.
27. Wisniak J., Segura H. Ind. Eng. Chem. Res. 2008, 47:5758-5760. Erratum: Ind. Eng. Chem. Res., 48 (2008) 2738.
28. Wilczek F., Devine B. Longing for the Harmonies. Themes and variations from Modern Physics 1987, W.W. Norton & Company, N.Y. and London.