Surface-inspired molecular vanadium oxide catalysts for the oxidative dehydrogenation of alcohols: Evidence for metal cooperation and peroxide intermediates

Chemistry - A European Journal

Volumn 17, Issue 43, 2011, Pages 12129-12135

  Werncke, C Gunnar ^a   Limberg, Christian ^a   Knispel, Christina ^a   Mebs, Stefan ^a  

^a HUMBOLDT UNIVERSITY   (Germany)

Author keywords

dehydrogenation; homogeneous catalysis; peroxo ligands; reaction mechanisms; vanadium

Indexed keywords

ACTIVATED ALCOHOLS; ACTIVE CATALYST; AS-LIGANDS; FUNCTIONAL MODEL; HOMOGENEOUS CATALYSIS; MONOMERIC FORMS; OXIDATIVE DEHYDROGENATIONS; PEROXIDE INTERMEDIATE; PEROXO LIGANDS; RE-OXIDATION; REACTION MECHANISM; SINGLE CRYSTAL X-RAY ANALYSIS; SURFACE SPECIES; THIACALIX[4]ARENE; THIACALIXARENES; THIOETHERS; TURNOVER NUMBER; VANADIA CATALYSTS; VANADIUM OXIDE CATALYSTS; VANADIUM OXIDES;

CATALYSIS; CATALYSTS; DEHYDROGENATION; DISSOLUTION; LIGANDS; OXIDATION; OXIDES; REACTION KINETICS; VANADIUM ALLOYS;

VANADIUM COMPOUNDS;

EID: 80054050094     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201101442     Document Type: Article

References (35)

1. A. Comite, A. Sorrentino, G. Capannelli, M. Di Serio, R. Tesser, E. Santacesaria, J. Mol. Catal. A: Chem. 2003, 198, 151-165
2. R. Zhou, Y. Cao, S. Yan, J. Deng, Y. Liao, B. Hong, Catal. Lett. 2001, 75, 107-112
3. T. Blasco, A. Galli, J. Lopez Nieto, F. Trifido, J. Catal. 1997, 169, 203-211
4. M. A. Chaar, D. Patel, H. H. Kung, J. Catal. 1988, 109, 463-467
5. A. Corma, J. M. Lopez Nieto, N. Paredes, J. Catal. 1993, 144, 425-438
6. F. D. Hardcastle, I. E. Wachs, J. Mol. Catal. 1988, 46, 173-186
7. G. Deo, I. E. Wachs, J. Haber, Crit. Rev. Surf. Chem. 1994, 4, 141-187
8. I. E. Wachs, B. M. Weckhuysen, Appl. Catal. A 1997, 157, 67-90
9. J. G. Eon, R. Olier, J. C. Volta, J. Catal. 1994, 145, 318-326
10. T. Balsko, J. M. Lopez Nieto, Appl. Catal. A 1997, 157, 117-142
11. A. Khodakov, B. Olthof, A. T. Bell, E. Iglesia, J. Catal. 1999, 181, 205-216
12. A. Khodakov, J. Yang, S. Su, E. Iglesia, A. T. Bell, J. Catal. 1998, 177, 343-351
13. E. V. Kondratenko, M. Baerns, Appl. Catal. A 2001, 222, 133-143
14. M. D. Argyle, K. Chen, E. Iglesia, A. T. Bell, J. Catal. 2002, 208, 139-149
15. L. Owens, H. H. Kung, J. Catal. 1993, 144, 202-213
16. O. R. Evans, A. T. Bell, T. D. Tilley, J. Catal. 2004, 226, 292-300.
17. E. Hoppe, C. Limberg, B. Ziemer, Inorg. Chem. 2006, 45, 8308-8317.
18. E. Hoppe, C. Limberg, B. Ziemer, C. Mügge, J. Mol. Catal. A: Chem. 2006, 251, 34-40.
19. E. Hoppe, C. Limberg, Chem. Eur. J. 2007, 13, 7006-7016.
20. C. Limberg, Eur. J. Inorg. Chem. 2007, 3303-3314.
21. C. Ohde, M. Brandt, C. Limberg, J. Döbler, B. Ziemer, J. Sauer, Dalton Trans. 2008, 326-331.
22. C. Ohde, C. Limberg, R. Stösser, S. Demeshko, Inorg. Chem. 2010, 49, 2479-2485.
23. C. Ohde, C. Limberg, Chem. Eur. J. 2010, 16, 6892-6899.
24. C. G. Werncke, C. Limberg, C. Knispel, R. Metzinger, B. Braun, Chem. Eur. J. 2011, 17, 2931-2938.
25. C. R. Waidmann, X. Zhou, E. A. Tsai, W. Kaminsky, D. A. Hrovat, W. T. Borden, J. M. Mayer, J. Am. Chem. Soc. 2009, 131, 4729-4743
26. M. H. V. Huynh, T. J. Meyer, Chem. Rev. 2007, 107, 5004-5064
27. J. M. Mayer, Annu. Rev. Phys. Chem. 2004, 55, 363-390.
28. H. Feng, J. W. Elam, J. A. Libera, M. J. Pellin, P. C. Stair, J. Catal. 2010, 269, 421-431.
29. J. E. Molinari, I. E. Wachs, J. Am. Chem. Soc. 2010, 132, 12559-12561.
30. X. Ding, W. Xue, Y. Ma, Y. Zhao, X. Wu, S. He, J. Phys. Chem. C 2010, 114, 3161-3169.
31. D. F. Evans, J. Chem. Soc. 1959, 2003-2005
32. E. M. Schubert, J. Chem. Ed. 1992, 69, 62
33. T. Ayers, R. Turk, C. Lane, J. Goins, D. Jameson, S. J. Slattery, Inorg. Chim. Acta 2004, 357, 202-206.
34. W. R. Busing, H. A. Levy, Acta Crystallogr. Sect. B 1967, 22, 457-464.
35. G. M. Sheldrick, Acta Crystallogr. Sect. A 2008, 64, 112-122.