Biomass pyrolysis in a heated-grid reactor: Visualization of carbon monoxide and formaldehyde using Laser-Induced Fluorescence

Journal of Analytical and Applied Pyrolysis

Volumn 92, Issue 2, 2011, Pages 280-286

  Prins, M J ^a   Li, Z S ^b   Bastiaans, R J M ^a   Van Oijen, J A ^a   Alden M ^b   De Goey, L P H ^a  

^a EINDHOVEN UNIVERSITY OF TECHNOLOGY   (Netherlands)

^b LUND UNIVERSITY   (Sweden)

Author keywords

Biomass pyrolysis; CFD; Devolatilization; In situ laser spectroscopy

Indexed keywords

BIOCONVERSION; BIOMASS; CARBON MONOXIDE; COMPUTATIONAL FLUID DYNAMICS; FLUORESCENCE QUENCHING; FORMALDEHYDE; HEATING RATE; LASER OPTICS; LASER PRODUCED PLASMAS; LASER SPECTROSCOPY; REACTION RATES; VISUALIZATION;

BIOMASS CONVERSION; BIOMASS PYROLYSIS; DEVOLATILIZATION; LASER INDUCED FLUORESCENCE; NON-INTRUSIVE METHOD; QUENCHING OF THE FLUORESCENCE; SECONDARY REACTIONS; TWO-PHOTON EXCITATIONS;

PYROLYSIS;

EID: 80054047836     PISSN: 01652370     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jaap.2011.06.008     Document Type: Article

References (27)

1. A. Broido Kinetics of solid phase cellulose pyrolysis F. Shafizadeh, K.V. Sarkanen, D.A. Tillman, Thermal Uses and Properties of Carbohydrates and Lignins 1976 Academic Press New York (chapter 19)
2. F. Shafizadeh Pyrolytic reactions and products of biomass R.P. Overend, T.A. Milne, L.K. Mudge, Fundamentals of Biomass Thermochemical Conversion 1985 Elsevier London 183 217
3. G. Várhegyi, M.J. Antal, T. Szekely, and P. Szabo Kinetics of the thermal decomposition of cellulose, hemicellulose, and sugar cane bagasse Energy Fuels 3 1989 329 335
4. G. Várhegyi, M.J. Antal, E. Jakab, and P. Szabó Kinetic modeling of biomass pyrolysis J. Anal. Appl. Pyrol. 42 1997 73 87 (Pubitemid 127395283)
5. M.J. Antal Biomass pyrolysis: a review of the literature. Part II-lignocellulose pyrolysis K.W. Boer, J.A. Duffie, Advances in Solar Energy vol. 2 1985 American Solar Energy Society Boulder, CO 175 255
6. J. Svenson, J.B.C. Pettersson, and K.O. Davidsson Fast pyrolysis of the main components of birch wood Combust. Sci. Technol. 176 2004 977 990
7. P.R. Solomon, M.A. Serio, D.G. Hamblen, Z.Z. Yu, and S. Charpenay Advances in the FG-DVC model of coal devolatilization ACS Div. Fuel Chem. Preprints 35 1990 479
8. T.H. Fletcher, A.R. Kerstein, R.J. Pugmire, and D.M. Grant Chemical percolation model for devolatilization. 2. Temperature and heating rate effects on product yields Energy Fuels 4 1990 54
9. S. Niksa, and A.R. Kerstein FLASHCHAIN theory for rapid devolatilization kinetics. 1. Formulation Energy Fuels 5 1991 647
10. J.D. Freihaut, and W.M. Proscia Tar evolution in heated-grid apparatus Energy Fuels 3 1989 625 635
11. J.R. Gibbins, PhD thesis, Imperial College, London, 1988.
12. P.E. Unger, and E.M. Suuberg Molecular weight distributions of tars produced by flash pyrolysis of coals Fuel 63 1984 606 611
13. E.M. Suuberg, W.A. Peters, and J.B. Howard Product composition and kinetics of lignite pyrolysis Ind. Eng. Chem. Process Des. Dev. 17 1978 37 46
14. 3 from the pyrolysis of bark and nitrogen-containing model compounds Combust. Flame 137 2004 265 277 (Pubitemid 38507570)
15. P.K Agarwal, J.B. Agnew, N. Ravindran, and R. Weimann Distributed kinetic parameters for the evolution of gaseous species in the pyrolysis of coal Fuel 66 1987 1097 1106 (Pubitemid 17618301)
16. J.H.J. Moors, Pulverized char combustion and gasification at high temperatures and pressures, PhD thesis, Eindhoven University of Technology, 1999.
17. J. Guo, Pyrolysis of wood powder and gasification of wood-derived char, PhD thesis, Eindhoven University of Technology, 2004.
18. A. Toland, R.J.M. Bastiaans, A. Holten, and L.P.H. de Goey Kinetics of CO release from bark and medium density fibre board pyrolysis Biomass Bioenergy 34 2010 771 779
19. 3 in flames with the use of two-photon excitation Appl. Spectrosc. 44 1990 881 886 (Pubitemid 20707433)
20. M. Richter, Z.S. Li, and M. Aldén Application of two-photon laser-induced fluorescence for single-shot visualization of carbon monoxide in a spark ignited engine Appl. Spectrosc. 61 2007 1 5 (Pubitemid 46191628)
21. C. Brackmann, M. Aldén, P.-E. Bengtsson, K.O. Davidsson, and J.B.C. Pettersson Optical and mass spectrometric study of the pyrolysis gas of wood particles Appl. Spectrosc. 57 2003 216 222
22. C. Brackmann, Development and application of rotational coherent anti-stokes Raman spectroscopy and laser-induced fluorescence for combustion diagnostics, PhD thesis, Lund Institute of Technology, 2004.
23. M.J. Prins, Z.S. Li, R.J.M. Bastiaans, J.A. van Oijen, M. Aldén, L.P.H. de Goey, Biomass pyrolysis in a heated grid reactor: visualization of carbon monoxide release using laser-induced fluorescence, in: Proceedings of the 15th European Biomass Conference and Exhibition: From Research to Market Deployment, 7-11 May 2007, Berlin, Germany, ETA Renewable Energies and WIP-Renewable Energies, Florence, pp. V.2.3.i.11-1339/1345.
24. Z.S. Li, M. Afzelius, J. Zetterberg, and M. Aldén Applications of a single-longitudinal-mode alexandrite laser for diagnostics of parameters of combustion interest Rev. Sci. Instrum. 75 2004 3208 3215
25. A.V. Mokhov, A.P. Nefedov, B.V. Rogov, V.A. Sinel'shchikov, A.D. Usachev, A.V. Zobnin, and H.B. Levinsky CO behavior in laminar boundary layer of combustion product flow Combust. Flame 199 1999 161 173 (Pubitemid 29398502)
26. D.B. Anthony, J.B. Howard, H.C. Hottel, and H.P. Meissner Fifteenth Symposium on Combustion 1975 The Combustion Institute Pittsburgh, PA 1303 1317
27. W. de Jong, A. Pirone, and M.A. Wójtowicz Pyrolysis of Miscanthus Giganteus and wood pellets: TG-FTIR analysis and reaction kinetics Fuel 82 2003 1139 1147