Mesoporous silica MCM-41 with rod-shaped morphology: Synthesis and characterization

Applied Clay Science

Volumn 54, Issue 2, 2011, Pages 138-143

  Jana, Sreyashi ^a   Dutta, Buddhadeb ^a   Honda, Hisashi ^b   Koner, Subratanath ^a  

^a JADAVPUR UNIVERSITY   (India)

^b YOKOHAMA CITY UNIVERSITY   (Japan)

Author keywords

29Si NMR; Hydrothermal synthesis; Mesoporous silica; SEM; Tetra alkylammonium bromide

Indexed keywords

HEXAGONAL VOID; LONG RANGE; LONG-RANGE ORDERING; MESOPOROSITY; MESOPOROUS SILICA; MESOPOROUS SILICA MATERIALS; NITROGEN SORPTION; NMR MEASUREMENTS; NMR STUDIES; ROD-LIKE MORPHOLOGY; ROD-SHAPED; ROD-SHAPED PARTICLES; SEM STUDY; SMALL-ANGLE X-RAY DIFFRACTION; STRUCTURAL ORDERING; SYNTHESIS ROUTE; TETRA-ALKYLAMMONIUM BROMIDE; XRD STUDIES;

BROMINE COMPOUNDS; HYDROTHERMAL SYNTHESIS; MATERIALS; MORPHOLOGY; SCANNING ELECTRON MICROSCOPY; SILICA; SILICON; SINGLE CRYSTALS; SORPTION; SURFACE ACTIVE AGENTS; TRANSMISSION ELECTRON MICROSCOPY; X RAY DIFFRACTION;

MESOPOROUS MATERIALS;

CHEMICAL REACTION; MINERAL SYNTHESIS; NUCLEAR MAGNETIC RESONANCE; SCANNING ELECTRON MICROSCOPY; SILICA; SORPTION; TRANSMISSION ELECTRON MICROSCOPY; X-RAY DIFFRACTION;

TETRA;

EID: 80053587800     PISSN: 01691317     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.clay.2011.07.018     Document Type: Article

References (37)

1. Barrett E.P., Joyner L.G., Halenda P.P. The determination of pore volume and area distributions in porous substances. I. Computations from nitrogen isotherms. J. Am. Chem. Soc. 1951, 73:373-380.
2. Beck J.S., Vartuli J.C., Roth W.J., Leonowizc M.E., Kresge C.T., Schmitt K.D., Chu C.T.-W., Olson D.H., Shepard E.W., McCullen S.B., Higgins J.B., Schlenker J.L. A new family of mesoporous molecular sieves prepared with liquid crystal templates. J. Am. Chem. Soc. 1992, 114:10834.
3. Brunauer S., Emmett P.H., Teller E. Adsorption of gases in multimolecular layers. J. Am. Chem. Soc. 1938, 60:309-319.
4. Cai Q., Luo Z.-S., Pang W.-Q., Fan Y.-W., Chen X.-H., Cui F.-Z. Dilute solution routes to various controllable morphologies of MCM-41 silica with a basic medium. Chem. Mater. 2001, 13:258-263.
5. Chen C.-Y., Li H.-X., Davis M.E. Studies on mesoporous materials: I. Synthesis and characterization of MCM-41. Microporous Mater. 1993, 2:17-26.
6. Coustel N., Renzo F.Di, Fajula F. Improved stability of MCM-41 through textural control. J. Chem. Soc. Chem. Commun. 1994, 967-968.
7. Das D., Tsai C.-M., Cheng S. Improvement of hydrothermal stability of MCM-41 mesoporous molecular sieve. Chem. Commun. 1999, 473-474.
8. Davis S.A., Burkett S.L., Mendelson N.H., Mann S. Bacterial templating of ordered macrostructures in silica and silica-surfactant mesophases. Nature 1997, 385:420-423.
9. Elder K.J., White J.W. Further improvements in the long-range order of MCM-41 materials. Chem. Mater. 1997, 9:1226-1233.
10. Galarneau A., Desplantier D., Dutartre R., Renzo F.Di Micelle-templated silicates as a test bed for methods of mesopore size evaluation. Micropor. Mesopor. Mater. 1999, 27:297-308.
11. Grün M., Lauer I., Unger K.K. The synthesis of micrometer- and submicrometer-size spheres of ordered mesoporous oxide MCM-41. Adv. Mater. 1997, 9:254-257.
12. Hou Q., Margolese D.I., Stucky G.D. Surfactant control of phases in the synthesis of mesoporous silica-based materials. Chem. Mater. 1996, 8:1147-1160.
13. Huo Q., Margolese D.I., Ciesla U., Feng P., Gier T., Sieger P., Leon R., Petroff P.M., Schüth F., Stucky G.D. Generalized synthesis of periodic surfactant/inorganic composite materials. Nature 1994, 368:317-321.
14. Huo Q., Margolese D.I., Ciesla U., Demuth D.G., Feng P., Gier T.E., Sieger P., Firouzi A., Chmelka B.F. Organization of organic molecules with inorganic molecular species into nanocomposite biphase arrays. Chem. Mater. 1994, 6:1176-1191.
15. Kruk M., Jaroniec M., Sayari A. Adsorption study of surface and structural properties of MCM-41 materials of different pore sizes. J. Phys. Chem. B 1997, 101:583-589.
16. Kruk M., Jaroniec M., Ryoo R., Kim J.M. Monitoring of the structure of siliceous mesoporous molecular sieves tailored using different synthesis conditions. Microporous Mater. 1997, 12:93-106.
17. Kumar R., Bhaumik A., Ahedi R.K., Ganapathy S. Promoter-induced enhancement of the crystallization rate of zeolites and related molecular sieves. Nature 1996, 381:298-300.
18. Lin H.-P., Mou C.-Y. "Tubules-Within-a-Tubule" hierarchical order of mesoporous molecular sieves in MCM-41. Science 1996, 273:765-768.
19. Lin H.-P., Cheng Y.-R., Mou C.-Y. Hierarchical order in hollow spheres of mesoporous silicates. Chem. Mater. 1998, 10:3772-3776.
20. Mann S., Ozin G.A. Synthesis of inorganic materials with complex form. Nature 1996, 382:313-318.
21. Marler B., Oberhagemann U., Vortmann S., Gies H. Influence of the sorbate type on the XRD peak intensities of loaded MCM-41. Microporous Mater. 1996, 6:375-383.
22. Mokaya R. Observation of some pore wall ordering in mesoporous silica. Chem. Commun. 2001, 1092-1093.
23. Mokaya R. On the extended recrystallisation of mesoporous silica: characterization of restructured pure silica. MCM-41. J. Mater. Chem. 2002, 12:3027-3033.
24. Mokaya R., Zhou W., Jones W. A method for the synthesis of high quality large crystal MCM-41. Chem. Commun. 1999, 51-52.
25. 29Si MAS NMR and powder X-ray diffraction studies. Chem. Commun. 2002, 2404-2405.
26. Oliver S., Kuperman A., Coombs N., Lough A., Ozin G.A. Lamellar aluminophosphates with surface patterns that mimic diatom and radiolarian microskeletons. Nature 1995, 378:47-50.
27. Pauwels B., Tendeloo G.V., Thoelen C.W., Rhijn V., Jacobs P.A. Structure determination of spherical MCM-41 particles. Adv. Mater. 2001, 13:1317-1320.
28. Ryoo R., Jun S. Improvement of hydrothermal stability of MCM-41 using salt effects during the crystallization process. J. Phys. Chem. 1997, 101:317-320.
29. Sayari A., Yang Y. Highly ordered MCM-41 silica prepared in the presence of decyltrimethylammonium bromide. J. Phys. Chem. B 2000, 104:4835-4839.
30. 2. Ind. Eng. Chem. Res. 1998, 37:2271-2283.
31. Stöber W., Fink A., Bohn E. Controlled growth of monodisperse silica spheres in the micron size range. J. Colloid Interface Sci. 1968, 26:62-69.
32. Tanev P.T., Pinnavaia T.J. Mesoporous silica molecular sieves prepared by ionic and neutral surfactant templating: a comparison of physical properties. Chem. Mater. 1996, 8:2068-2079.
33. Unger K.K., Kumar D., Grün M., Büchel G., Lüdtke S., Adam T., Schumacher K., Renker S. Synthesis of spherical porous silicas in the micron and submicron size range: challenges and opportunities for miniaturized high-resolution chromatographic and electro-kinetic separations. J. Chromatogr. A 2000, 892:47-55.
34. Vallet-Regí M., Francisco B., Daniel A. Mesoporous materials for drug delivery. Angew. Chem. Int. Ed. 2007, 46:7548-7558.
35. Wang B., Chi C., Shan W., Zhang Y., Ren N., Yang W., Tang Y. Chiral mesostructured silica nanofibers of MCM-41. Angew. Chem. Int. Ed. 2006, 45:2088-2090.
36. Yang H., Coombs N., Ozin G.A. Morphogenesis of shapes and surface patterns in mesoporous silica. Nature 1997, 386:692-695.
37. Zhao X.S., Lu G.Q. Modification of MCM-41 by surface silylation with trimethylchlorosilane and adsorption study. J. Phys. Chem. B 1998, 102:1556-1561.