Experimental and theoretical investigations of adsorption hysteresis and criticality in MCM-41: Studies with O2, Ar, and CO2

Industrial and Engineering Chemistry Research

Volumn 37, Issue 6, 1998, Pages 2271-2283

  Sonwane, C G ^a   Bhatia, S K ^a   Calos, N ^a  

^a UNIVERSITY OF QUEENSLAND   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION ISOTHERMS; ARGON; CARBON DIOXIDE; CONDENSATION; DENSITY MEASUREMENT (SPECIFIC GRAVITY); HYSTERESIS; MATHEMATICAL MODELS; NEUTRON SCATTERING; OXYGEN; POROUS MATERIALS; TRANSMISSION ELECTRON MICROSCOPY; X RAY DIFFRACTION ANALYSIS;

HELIUM PYCNOMETRY; SMALL ANGLE NEUTRON SCATTERING;

GAS ADSORPTION;

EID: 0032097591     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie970883b     Document Type: Article

References (40)

1. Alfredsson, V.; Keung M.; Monnier, A.; Stucky, G. D.; Unger, K. K.; Schuth, F. High-Resolution Transmission Electron Microscopy of Mesoporous MCM-41 Type Materials. J. Chem. Soc., Chem. Commun. 1994, 924.
2. Beck, J. S.; Vartuli, J. C.; Roth, W. J.; Leonowicz, M. E.; Kresge, C. T.; Schmitt, K. D.; Chu, G. T.-W.; Olsen, D. H.; Sheppard, E. W.; McCullen, S. B.; Higgins, J. B.; Schlenker, J. L. A New Family of Mesoporous Molecular Sieves Prepared with Liquid Crystal Templates. J. Am. Chem. Soc. 1992, 114, 10835.
3. Bhatia, S. K.; Sonwane, C. G. Capillary Coexistence and Criticality in Mesopores: Modification of the Kelvin Theory. Langmuir 1998, 14, 1521.
4. Branton, P. J.; Hall, P. G.; Sing, K. S. W. Physisorption of Nitrogen and Oxygen by MCM-41, a Model Mesoporous Adsorption J. Chem. Soc., Chem. Commun. 1993, 1257.
5. Branton, P. J.; Hall, P. G.; Sing, K. S. W.; Reichert, H.; Schuth, F.; Unger, K. K. Physisorption of Argon, Nitrogen and Oxygen by MCM-41, A Model Mesoporous Adsorbent. J. Chem. Soc., Faraday Trans. 1994, 90, 2965.
6. Branton, P. J.; Hall, P. G.; Sing, K. S. W. Physisorption of Alcohols and Water Vapour by MCM-41, A Model Mesoporous Adsorbent. Adsorption 1995a, 1, 77.
7. Branton, P. J.; Hall, P. G.; Treguer, M.; Sing, K. S. W. Adsorption of Carbon Dioxide, Sulfur Dioxide and Water Vapor by MCM-41, A Model Mesoporous Adsorbent. J. Chem. Soc., Faraday Trans. 1995b, 91, 2041.
8. Brindley, G. W. Long-Spacing Organics for Calibrating Long Spacings of Interstratified Clay Minerals. Clays Clay Miner. 1981, 29, 67.
9. Brindley, G. W.; Wan, H. M. Use of Long-spacing Alcohols and Alkenes for Calibration of Long Spacings from Layer Silicates, Particularly Clay Minerals. Clays Clay Miner. 1974, 22, 313.
10. Burgess, C. G. V.; Everett, D. H. The Lower Closure Point in Adsorption Hysteresis of the Capillary Condensation Type. J. Colloid Interface Sci. 1970, 33, 611.
11. Casci, J. L. The Preparation and Potential Applications of Ultra Large Pore Molecular Sieves: A Review. In Advanced Zeolite Science and Applications, Studies in Surface Science and Catalysis; Jenson, J. C., Stocker, M., Karge, H. G., Weitkamp, J., Eds.; Elsevier: New York, 1994; Vol. 85.
12. Chen, C. Y.; Li, H. X.; Davis, M. E. Studies on Mesoporous Materials. I Synthesis and Characterisation of MCM-41. Microporous Mater. 1993, 2, 17.
13. Edler, K J.; Reynolds, P. A.; White, J. W.; Cockson, D. Diffuse Wall Structure and Narrow Mesopores in Highly Crystalline MCM-41 Materials Studied by X-ray Diffraction. J. Chem. Soc. Faraday Trans. 1997, 93, 199.
14. Evans, R.; Marconi, V. M. B.; Tarazona, P. Capillary Condensation and Adsorption in Cylindrical and Slitlike Pores. J. Chem. Soc., Faraday Trans. 2 1986, 82, 1763.
15. Feuston, B. P.; Higgins, J. B. Model Structures for MCM-41 Materials - A Molecular Dynamics Simulation. J. Phys. Chem. 1994, 98, 4459.
16. Franke, O.; Schulz-Ekloff, G.; Rathousky, J.; Starek, J.; Zukal, A. Unusual Type of Adsorption Isotherm Describing Capillary Condensation without Hysteresis J. Chem. Soc., Chem. Commun. 1993, 724.
17. Gregg, S. J.; Sing, K. S. W. Adsorption Surface Area and Porosity; Academic Press: New York, 1982.
18. Inagaki, S.; Fukushima, Y.; Kuroda, K Adsorption Isotherm of Water Vapor and Its Large Hysteresis on Highly Ordered Mesoporous Silica. J. Colloid Interface Sci. 1996, 180, 623.
19. Karykowski, K.; Rzysko, W.; Patrykiejew, A.; Sokolowski, S. Grand Canonical Ensemble Monte Carlo Simulations of Adsorption in Energetically Heterogeneous Slitlike Pores. This Solid Films 1994, 249, 236.
20. Keefer, K. D.; Schaefer, D. W. Growth of Fractally Rough Colloids. Phys. Rev. Lett. 1986, 56.
21. Khushalani, D.; Kuperman, A.; Ozin, G. A.; Tanaka, K.; Garces, J.; Olken, J. J.; Coombs, N. Metamorphic Materials-Restructuring Siliceous Mesoporous Materials. Adv. Mater. 1995, 7, 842.
22. Kresge, C. T.; Leonowicz, M. E.; Roth, W. J.; Vartuli, J. C.; Beck, J. S. Ordered Mesoporous Molecular Sieves Synthesised by a Liquid-Crystal Template Mechanism. Nature 1992, 359, 710.
23. Kruk, M.; Jaroniec, M.; Sayari, A. Adsorption Study of Surface and Structural Properties of MCM-41 Materials of Different Pore Sizes. J. Phys. Chem. B 1997, 101, 583.
24. Llewellyn, P. L.; Grillet, Y.; Schuth, F.; Reichert, H.; Unger, K. K. Effect of Pore Size on Adsorbate Condensation and Hysteresis within a Potential Model Adsorbent: M41S. Microporous Mater. 1994, 3, 345.
25. Llewellyn, P. L.; Grillet, Y.; Rouquerol, J.; Martin, C.; Coulomb, J. P. Thermodynamic and Structural Properties of Physiosorbed Phases within the Model Mesoporous Adsorbent M41S (pore diameter 2.5 nm). Surf. Sci. 1996, 352-354, 468.
26. Maddox, M. W.; Gubbins, K. E. Molecular Simulation of Fluid Adsorption in Buckytubes and MCM-41. Int. J. Thermophys. 1994, 15, 1115.
27. Maddox, M. W.; Olivier, J. P.; Gubbins, K. E. Characterisation of MCM-41 Using Molecular Simulation: Heterogeneity Effects. Langmuir 1997, 13, 1737.
28. Morishige, K.; Fujii, H.; Uga, M.; Kinukawa, D. Capillary Critical Point of Argon, Nitrogen, Oxygen, Ethylene, and Carbon Dioxide . in MCM-41. Langmuir 1997, 13, 3494.
29. Naona, H.; Hakuman, M.; Shiono, T. Analysis of Nitrogen Adsorption Isotherm for a Series of Porous Silicas with Uniform and Cylindrical Pores: A New Method of Calculating Pore Size Distribution of Pore Radius 1-3 nm. J. Colloid Interface Sci. 1997, 186, 360.
30. Rathousky, J.; Zukul, A.; Franke, O.; Schulz-Ekloff, G. Adsorption on MCM-41 Mesoporous Molecular Sieves Part. 1. Nitrogen Isotherms and Parameters of the Porous Structure. J. Chem. Soc., Faraday Trans. 1994, 90, 2821.
31. Rathousky, J.; Zukul, A.; Franke, O.; Schulz-Ekloff, G. Adsorption on MCM-41 Mesoporous Molecular Sieves, Part 2. Cyclopentane Isotherm and their Temperature Dependence. J. Chem. Soc., Faraday Trans. 1995, 91, 937.
32. Ravikovitch, P. I.; O'Domhnaill, S. C.; Neimark, A. V.; Schuth, F.; Unger, K. K. Capillary Hysteresis in Nanopores: Theoretical and Experimental Studies of Nitrogen Adsorption on MCM-41. Langmuir 1995, 11, 4765.
33. Reid, R. C.; Prausnitz, J. M.; Poling, B. E. The Properties of Gases and Liquids; McGraw-Hill: New York, 1987.
34. Saito, A.; Foley, H. C. Curvature and Parametric Sensitivity in Models for Adsorption in Micropores. AIChE J. 1991, 37, 923.
35. Schulz-Ekloff, G.; Rathousky, J.; Zukul, A. A Simple Geometric Modelling of the Porosity of MCM-41 Type Materials. In Synthesis of Porous Materials, Zeolites, Clays and Nanostructures; Occelli, M. L., Kessler, H., Eds.; Marcel Dekker Inc.: New York, 1997.
36. Sonwane, C. G.; Bhatia, S. K. Adsorption in Mesopores: A Molecular-Continuum Model with Application to MCM-41. Chem. Eng. Sci. 1998, in press.
37. Taylor, D. The Thermal Expansion Behaviour of the Framework Silicates. Mineral. Mag. 1972, 38, 593.
38. White, K. J.; Reynolds, P. A.; White, J. W.; Cookson, D. Diffuse wall structure and narrow mesopores in highly crystalline MCM-41 materials studied by X-ray diffraction. J. Chem. Soc., Faraday Trans. 1997, 93, 199.
39. Yanagisawa, T.; Shimizu, T.; Kuroda, K.; Kato, C. The Preparation of Alkyltrimethylammonium-Kanemite Complexes and their Conversion to Mesoporous Materials. Bull. Chem. Soc. Jpn. 1990, 63, 988.
40. Zhao, X. S.; Lu, G. Q. M.; Miller, G. J. Advances in Mesoporous Molecular Sieve MCM-41 [Review]. Ind. Eng. Chem. Res. 1996, 35, 2075.