Reactivity of chemisorbed oxygen atoms and their catalytic consequences during CH4-O2 catalysis on supported Pt clusters

Journal of the American Chemical Society

Volumn 133, Issue 40, 2011, Pages 15958-15978

  Chin, Ya Huei ^a   Buda, Corneliu ^b   Neurock, Matthew ^b   Iglesia, Enrique ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b UNIVERSITY OF VIRGINIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION BARRIERS; ACTIVATION STEPS; ACTIVE SITE; ACTIVE STRUCTURES; ADSORBED INTERMEDIATES; ADSORBED SPECIES; ADSORPTION DESORPTION; C-H BOND; C-H BOND DISSOCIATION; CATALYTIC SURFACES; CH-BOND ACTIVATION; CHEMISORBED OXYGEN; CLUSTER SIZE EFFECTS; CLUSTER SIZES; CLUSTER SURFACES; CONVERSION RATES; ELEMENTARY STEPS; FIRST-ORDER; H-ABSTRACTION; HYDROGEN ABSTRACTION; ISOTOPIC DATA; ISOTOPIC EXCHANGE; KINETIC COUPLING; KINETIC ISOTOPE EFFECTS; KINETIC REGIME; LARGE CLUSTERS; MECHANISTIC INTERPRETATIONS; OXIDATION REACTIONS; OXIDATIVE ADDITIONS; PT ATOMS; PT CLUSTERS; PT DISPERSION; RATE DEPENDENCY; RATE EQUATIONS; SMALL CLUSTERS; SUPPORTED PT; TRANSITION STATE; TURNOVER RATE; VACANCY CONCENTRATION; WEAK INTERACTIONS;

ABSTRACTING; ACTIVATION ENERGY; ADSORPTION; ATOMS; BINDING ENERGY; CARBON DIOXIDE; CARRIER MOBILITY; CATALYSIS; CATALYTIC OXIDATION; CHEMISORPTION; CLUSTER ANALYSIS; COORDINATION REACTIONS; DENSITY FUNCTIONAL THEORY; DESORPTION; DISPERSIONS; ENTROPY; EQUILIBRIUM CONSTANTS; HYDROGEN; HYDROGEN BONDS; ISOTOPES; KINETICS; OXIDANTS; OXYGEN; PLATINUM; PLATINUM COMPOUNDS; RATE CONSTANTS; SURFACE CHEMISTRY;

OXYGEN VACANCIES;

CARBON; HYDROGEN; ISOTOPE; OXIDIZING AGENT; OXYGEN; PLATINUM; RADICAL;

ADSORPTION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL BINDING; CHEMICAL INTERACTION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; DENSITY FUNCTIONAL THEORY; DESORPTION; DISPERSION; ENERGY; ENTROPY; MOLECULAR STABILITY; OXIDATION; OXYGEN TENSION; STEADY STATE; TURNOVER TIME;

EID: 80053500934     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja202411v     Document Type: Article

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