Selectivity of chemisorbed oxygen in C-H bond activation and CO oxidation and kinetic consequences for CH4-O2 catalysis on Pt and Rh clusters

Journal of Catalysis

Volumn 283, Issue 1, 2011, Pages 10-24

  Chin, Ya Huei ^a   Buda, Corneliu ^b   Neurock, Matthew ^b,c   Iglesia, Enrique ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b University of Virginia   (United States)

^c UNIVERSITY OF VIRGINIA   (United States)

Author keywords

C H bond activation; Catalytic partial oxidation; CH4; CO oxidation; Density functional theory; Methane combustion; Oxygen selectivity; Platinum; Rhodium; Transition state theory

Indexed keywords

CATALYTIC PARTIAL OXIDATION; CH-BOND ACTIVATION; CH4; CO OXIDATION; DENSITY FUNCTIONALS; METHANE COMBUSTION; OXYGEN SELECTIVITY; TRANSITION STATE THEORIES;

ADSORPTION; ATOMS; BINDING ENERGY; CARBON DIOXIDE; CATALYSIS; CATALYTIC OXIDATION; CHEMICAL BONDS; CHEMISORPTION; DENSITY FUNCTIONAL THEORY; DISSOCIATION; KINETICS; METHANE; OXIDATION; OXYGEN; PLATINUM; RATE CONSTANTS; RHODIUM; SURFACE REACTIONS;

PLATINUM COMPOUNDS;

EID: 80052813195     PISSN: 00219517     EISSN: 10902694     Source Type: Journal    
DOI: 10.1016/j.jcat.2011.06.011     Document Type: Article

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