Single-molecule magnet behavior with a single metal center enhanced through peripheral ligand modifications

Journal of the American Chemical Society

Volumn 133, Issue 40, 2011, Pages 15814-15817

  Jurca, Titel ^a   Farghal, Ahmed ^a   Lin, Po Heng ^a   Korobkov, Ilia ^a   Murugesu, Muralee ^a   Richeson, Darrin S ^a  

^a UNIVERSITY OF OTTAWA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

BASAL PLANES; ISOTHIOCYANATES; METAL CENTERS; PINCER LIGANDS; SINGLE-MOLECULE MAGNET; SLOW RELAXATIONS; SPIN-ORBIT COUPLINGS; SQUARE-PYRAMIDAL GEOMETRY;

COBALT COMPOUNDS; MAGNETS;

LIGANDS;

COBALT COMPLEX; ISOTHIOCYANIC ACID; PYRIDINE;

ANISOTROPY; ARTICLE; CHEMICAL PARAMETERS; CHEMICAL REACTION; CHEMICAL STRUCTURE; GEOMETRY; MAGNET; SINGLE MOLECULAR MAGNET; SPIN ORBIT COUPLING; TEMPERATURE DEPENDENCE;

EID: 80053484718     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja204562m     Document Type: Article

References (35)

1. Milios, C. J.; Vinslava, A.; Wernsdorfer, W.; Moggach, S.; Parsons, S.; Perlepes, S. P.; Christou, G.; Brechin, E. K. J. Am. Chem. Soc. 2007, 129, 2754
2. Christou, G.; Gatteschi, D.; Hendrickson, D. N.; Sessoli, R. MRS Bull. 2000, 25, 66
3. Thomas, L.; Lionti, L.; Ballou., R.; Gatteschi, D.; Sessoli, R.; Barbara, B. Nature 1996, 383, 145
4. Sokol, J. J.; Hee, A. G.; Long, J. R. J. Am. Chem. Soc. 2002, 124, 7656
5. Maheswaran, S.; Chastanet, G.; Teat, S. J.; Mallah, T.; Sessoli, R.; Wernsdorfer, W.; Winpenny, R. E. P. Angew. Chem. 2005, 44, 5044
6. Ishikawa, N.; Sugita, M.; Wernsdorfer, W. J. Am. Chem. Soc. 2005, 127, 3650
7. Jiang, S.-D.; Wang, B.-W.; Sun, H.-L.; Wang, Z.-M.; Gao, S. J. Am. Chem. Soc. 2011, 133, 4730
8. Li, D. P.; Wang, T. W.; Li, C. H.; Liu, D. S.; Li, Y. Z.; You, X. Z. Chem. Commun. 2010, 46, 2929
9. AlDamen, M. A.; Clemente-Juan, J. M.; Coronado, E.; Marti-Gastaldo, C.; Gaita-Arino, A. J. Am. Chem. Soc. 2008, 130, 8874
10. Rinehart, J. D.; Long, J. R. J. Am.Chem. Soc. 2009, 131, 12558
11. Jiang, S. D.; Wang, B. W.; Su, G.; Wang, Z. M.; Gao, S. Angew. Chem., Int. Ed. 2010, 49, 7448
12. Magnani, N.; Apostolidis, C.; Morgenstern, A.; Colineau, E.; Griveau, J.-C.; Bolvin, H.; Walter, O.; Caciuffo, R. Angew. Chem. 2011, 50, 1696
13. Rinehart, J. D.; Meihaus, K. R.; Long, J. R. J. Am. Chem. Soc. 2010, 132, 7572
14. Harman, W. H.; Harris, T. D.; Freedman, D. E.; Fong, H.; Chang, A; Rinehart, J. D.; Ozarowski, A.; Sougrati, M. T.; Grandjean, F.; Long, G. J.; Long, J. R.; Chang, C. J. J. Am. Chem. Soc. 2010, 132, 18115
15. Freedman, D. E.; Harman, W. H.; Harris, T. D.; Long, G. J.; Chang, C. J.; Long, J. R. J. Am. Chem. Soc. 2010, 132, 1224
16. A recent organometallic Fe(II) SMM is reported in Weismann, D.; Sun, Y.; Lan, Y.; Wolmershauser, G.; Powell, A. K.; Sitzmann, H. Chem.-Eur. J. 2011, 17, 4700
17. Small, B. L.; Brookhart, M. J. Am. Chem. Soc. 1998, 120, 7143
18. Britovsek, G. J. P.; Gibson, V. C.; Kimberley, B. S.; Maddox, S. J.; Solan, G. A.; White, A. J. P.; Williams, D. J. Chem. Commun. 1998, 849
19. Bowman, A. C.; Milsmann, C.; Hojilla Atienza, C. C.; Lobkovsky, E.; Wieghardt, K.; Chirik., P. J. J. Am. Chem. Soc. 2010, 132, 1676
20. Hojilla Atienza, C. C.; Bowman, A. C.; Lobkovsky, E.; Chirik, P. J. J. Am. Chem. Soc. 2010, 132, 16343
21. Jurca, T.; Korobkov, I.; Yap, G. P. A.; Gorelsky, S. I.; Richeson, D. S. Inorg. Chem. 2010, 49, 10635
22. Jurca, T.; Dawson, K.; Mallov, I.; Burchell, T. J.; Yap, G. P. A.; Richeson, D. S. Dalton Trans. 2010, 39, 1266
23. Jurca, T.; Lummis, J.; Burchell, T. J.; Gorlesky, S. I.; Richeson, D. S. J. Am. Chem. Soc. 2009, 131, 4608
24. Cirera, J.; Ruiz, E.; Alvarez, S.; Neese, F.; Kortus, J. Chem.-Eur. J. 2009, 15, 4078
25. 2 complexes are reported in Sacconi, L.; Morassi, R.; Midollini, S. J. Chem. Soc. A 1968, 1510
26. Mabbs, F. E.; Machin, D. J. Magnetism and Transition Metal Complexes; Dover Publications: 2008.
27. Kooistra, T. M.; Hekking, K. F. W.; Knijnenburg, Q.; de Bruin, B.; Budzelaar, P. H. M.; de Gelder, R.; Smits, J. M. M.; Gal, A. W. Eur. J. Inorg. Chem. 2003, 648
28. Davidson, E. R. MAGNET; Indiana University: Bloomington, IN, 1999.
29. Chirico, R. D.; Carlin, R. L. Inorg. Chem. 1980, 19, 3031
30. Hung, S,-W.; Yang, F.-A.; Chen, J.-H.; Wang, S.-S.; Tung, J.-Y. Inorg. Chem. 2008, 47, 7202
31. Luis, F.; Mettes, F.; Evangelisti, M.; Morello, A.; de Jongh, L. J. J. Phys. Chem. Solids 2004, 65, 763
32. Wernsdorfer, W.; Bhaduri, S.; Boskovic, C.; Christou, G.; Hendrickson, D. N. Phys. Rev. B 2002, 65, No. 180403.
33. Wernsdorfer, W.; Chakov, N. E.; Christou, G. Phys. Rev. Lett. 2005, 95, No. 037203.
34. Orbach, R. Proc. R. Soc. London, Ser. A 1961, 264, 458
35. Orbach, R. Proc. R. Soc. London, Ser. A 1961, 264, 458