Synthesis and reactivity of a phosphine-stabilized monogermanium analogue of alkynes

Journal of the American Chemical Society

Volumn 133, Issue 40, 2011, Pages 15930-15933

  Berthe, Juliette ^a   Garcia, Juan Manuel ^b   Ocando, Edgar ^b   Kato, Tsuyoshi ^a   Saffon Merceron, Nathalie ^d   De Cózar, Abel ^c   Cossío, Fernando P ^c   Baceiredo, Antoine ^a  

^a CNRS   (France)

^b Centro de Quimica   (Venezuela)

^c UNIVERSITY OF THE BASQUE COUNTRY UPV EHU   (Spain)

^d Université Paul Sabatier   (France)

Author keywords

[No Author keywords available]

Indexed keywords

DOUBLE BONDS; GERMYLENES; N-HETEROCYCLIC; PHOSPHINE LIGANDS;

ACETYLENE; BOND LENGTH; GERMANIUM; LIGANDS; PHOSPHORUS COMPOUNDS; X RAY DIFFRACTION ANALYSIS;

CHELATION;

ALKYNE; CARBON; GERMANIUM; GERMANIUM DERIVATIVE; GERMYNE DERIVATIVE; MONOGERMANIUM; PHOSPHINE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; DIASTEREOISOMER; ISOMERIZATION; SYNTHESIS; X RAY DIFFRACTION;

EID: 80053468637     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja2073577     Document Type: Article

References (38)

1. Modern Acetylene Chemistry; Stang, P. J., Diederich, F., Eds.; VCH: Weinheim, Germany, 1995.
2. Fischer, R. C.; Power, P. P. Chem. Rev. 2010, 110, 3877
3. Sekiguchi, A.; Kinjo, R.; Ichinohe, M. Science 2004, 305, 1755
4. Wiberg, N.; Vasisht, S. K.; Fischer, G.; Mayer, P. Z. Anorg. Allg. Chem. 2004, 630, 1823
5. Sasamori, T.; Hironaka, K.; Sugiyama, T.; Takagi, N.; Nagase, S.; Hosoi, Y.; Furukawa, Y.; Tokitoh, N. J. Am. Chem. Soc. 2008, 130, 13856
6. Stender, M.; Phillips, A. D.; Wright, R. J.; Power, P. P. Angew. Chem., Int. Ed. 2002, 41, 1785
7. Stender, M.; Phillips, A. D.; Power, P. P. Chem. Commun. 2002, 1312
8. Pu, L.; Phillips, A. D.; Richards, A. F.; Stender, M.; Simons, R. S.; Olmstead, M. M.; Power, P. P. J. Am. Chem. Soc. 2003, 125, 11626
9. Sugiyama, Y.; Sasamori, T.; Hosoi, Y.; Furukawa, Y.; Takagi, N.; Nagase, S.; Tokitoh, N. J. Am. Chem. Soc. 2006, 128, 1023
10. Spikes, G. H.; Power, P. P. Chem. Commun. 2007, 85
11. Phillips, A. D.; Wright, R. J.; Olmstead, M. M.; Power, P. P. J. Am. Chem. Soc. 2002, 124, 5930
12. Pu, L.; Twamley, B.; Power, P. P. J. Am. Chem. Soc. 2000, 122, 3524
13. Power, P. P. Organometallics 2007, 26, 4362
14. Power, P. P. Nature 2010, 463, 7278
15. Sekiguchi, A. Pure Appl. Chem. 2008, 80, 447
16. Apeloig, Y.; Karni, M. Organometallics 1997, 16, 310
17. Karni, M.; Apeloig, Y.; Schröder, D.; Zummack, W.; Rabezzana, R.; Schwarz, H. Angew. Chem., Int. Ed. 1999, 38, 311
18. Danovich, D.; Ogliaro, F.; Karni, M.; Apeloig, Y.; Cooper, D. L.; Shaik, S. Angew. Chem., Int. Ed. 2001, 40, 4023
19. Lühmann, N.; Müller, T. Angew. Chem., Int. Ed. 2010, 49, 10042
20. Bibal, C.; Mazières, S.; Gornitzka, H.; Couret, C. Angew. Chem., Int. Ed. 2001, 40, 952
21. Liao, H.-Y.; Su, M.-D.; Chu, S.-Y. Inorg. Chem. 2000, 39, 3522
22. Liao, H.-Y.; Su, M.-D.; Chu, S.-Y. Chem. Phys. Lett. 2001, 341, 122
23. Wu, P.-C.; Su, M.-D. Dalton Trans. 2011, 40, 4253
24. Ploshnik, E.; Danovich, D.; Hiberty, P. C.; Shaik, S. J. Chem. Theory Comput. 2011, 7, 955
25. Setaka, W.; Hirai, K.; Tomioka, H.; Sakamoto, K.; Kira, M. J. Am. Chem. Soc. 2004, 126, 2696
26. Setaka, W.; Hirai, K.; Tomioka, H.; Sakamoto, K.; Kira, M. Chem. Commun. 2008, 6558
27. Wu, P.-C.; Su, M.-D. Inorg. Chem. 2011, 50, 6814
28. Wu, P.-C.; Su, M.-D. Organometallics 2011, 30, 3293
29. Gau, D.; Kato, T.; Saffon-Merceron, N.; De Cózar, A.; Cossío, F. P.; Baceiredo, A. Angew. Chem., Int. Ed. 2010, 49, 6585
30. Baceiredo, A.; Igau, A.; Bertrand, G.; Menu, M. J.; Dartiguenave, Y.; Bonnet, J. J. J. Am. Chem. Soc. 1986, 108, 7868
31. Vignolle, J.; Cattoën, X.; Bourissou, D. Chem. Rev. 2009, 109, 3333
32. Baines, K. M.; Stibbs, W. G. Coord. Chem. Rev. 1995, 145, 157
33. Regitz, M. Chem. Rev. 1990, 90, 191
34. Igau, A.; Baceiredo, A.; Grützmacher, H.; Pritzkow, H.; Bertrand, G. J. Am. Chem. Soc. 1989, 111, 6853
35. Guerret, O.; Bertrand, G. Acc. Chem. Res. 1997, 30, 486
36. Yao, S.; Zhang, X.; Xiong, Y.; Schwarz, H.; Driess, M. Organometallics 2010, 29, 5353
37. Kühl, O. Coord. Chem. Rev. 2004, 248, 411
38. Asay, M.; Jones, C.; Driess, M. Chem. Rev. 2011, 111, 354