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Most of the activation energies determined were significantly larger than the value of 38 kJ/mol reported by Głowinkowski et al. [33]and Hartwig [2]. The reason for these differences might lie in the measurement method, as both groups determined the activation energy by NMR, which seems not to produce comparable results with dynamic-mechanical measurements due to the different length scales being analyzed (see also part II of this series [19])
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Most of the activation energies determined were significantly larger than the value of 38 kJ/mol reported by Głowinkowski et al. [33]and Hartwig [2]. The reason for these differences might lie in the measurement method, as both groups determined the activation energy by NMR, which seems not to produce comparable results with dynamic-mechanical measurements due to the different length scales being analyzed (see also part II of this series [19]).
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