Silane-based hydrogen storage materials for fuel cell application: Hydrogen release via methanolysis and regeneration by hydride reduction from organosilanes

International Journal of Hydrogen Energy

Volumn 36, Issue 19, 2011, Pages 12305-12312

  Han, Won Sik ^a   Kim, Tae Jin ^a   Kim, Sung Kwan ^a   Kim, Yongmin ^b   Kim, Yeongcheon ^b   Nam, Suk Woo ^b   Kang, Sang Ook ^a  

^a Korea University   (South Korea)

^b Korea Institute of Science and Technology   (South Korea)

Author keywords

Hydrogen storage material; Hydrosilane; PEMFC; Regeneration

Indexed keywords

ALUMINUM COMPOUNDS; LITHIUM COMPOUNDS; METHANOL; PROTON EXCHANGE MEMBRANE FUEL CELLS (PEMFC); SILANES; FUEL STORAGE; HYDROGEN; SILICON;

FUEL CELL APPLICATION; FUEL CELL OPERATION; HYDRIDE REDUCTION; HYDROGEN SOURCES; HYDROGEN STORAGE CAPACITIES; HYDROSILANES; POTENTIAL HYDROGENS; REGENERATION; HYDROGEN STORAGE MATERIALS;

HYDROGEN STORAGE;

EID: 80052796441     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2011.06.118     Document Type: Article

References (45)

1. M.S. Dresselhaus, and I.L. Thomas Alternative energy technologies Nature 414 2001 332 337 (Pubitemid 33097815)
2. S.C. Amendola, S.L. Sharp-Goldman, M. Saleem Janjua, N.C. Spencer, M.T. Kelly, and P.J. Petillo A safe, portable, hydrogen gas generator using aqueous borohydride solution and Ru catalyst Int J Hydrogen Energy 25 10 2000 969 975
3. J. Turner, G. Sverdrup, K.M.K. Mann, P.C. Maness, B. Kroposki, and M. Ghirardi Renewable hydrogen production Int J Energy Res 32 2008 379 407 (Pubitemid 351516696)
4. W.C. Annemieke, and C.O. Berg van den Arean Materials for hydrogen storage: current research trends and perspectives Chem Commun 2008 668 681
5. L. Barreto, A. Makihira, and K. Riahi The hydrogen economy in the 21st century: a sustainable development scenario Int J Hydrogen Energy 28 2007 267 284
6. T. Umegaki, J.M. Yan, X.B. Zhang, H. Shioyama, N. Kuriyama, and Q. Xu Boron- and nitrogen-based chemical hydrogen storage materials Int J Hydrogen Energy 34 2009 2303 2311
7. N. Zhang, and N. Lior A novel Brayton cycle with the integration of liquid hydrogen cryogenic exergy utilization Int J Hydrogen Energy 33 2008 214 224
8. K. Takeno, K. Okabayashi, A. Kouchi, T. Nonaka, K. Hashiguchi, and K. Chitose Dispersion and explosion field tests for 40 MPa pressurized hydrogen Int J Hydrogen Energy 32 2007 2144 2153 (Pubitemid 47302644)
9. N.L. Rosi, J. Eckert, M. Eddaoudi, D.T. Vodak, J. Kim, and M. O'Keeffe Hydrogen storage in microporous metal-organic frameworks Science 300 2003 1127 1129 (Pubitemid 36583092)
10. L. Schlapbach, and A. Zuttel Hydrogen-storage materials for mobile applications Nature 414 2001 353 358 (Pubitemid 33097818)
11. Energy Information Administration Annual energy Outlook 2005 with projections to 2025 see also February 2005 www.eia.doe.gov/oiaf/aeo/pdf/ 0383(2005).pdf
12. Y. Okada, E. Sasaki, E. Watanabe, S. Hyodo, and H. Nishijima Development of dehydrogenation catalyst for hydrogen generation in organic chemical hydride method Int J Hydrogen Energy 31 2006 1348 1356 (Pubitemid 44183760)
13. B. Sakintunaa, F. Lamari-Darkrimb, and M. Hirscherc Metal hydride materials for solid hydrogen storage: a review Int J Hydrogen Energy 32 2007 1121 1140
14. 3 J Alloys Compd 290 1999 250 256
15. B.H. Liu, and Z.P. Li A review: hydrogen generation from borohydride hydrolysis reaction J Power Sources 187 2009 527 534
16. - in lithium aluminohydride Chem Commun 2000 1665 1666
17. H.C. Brown, and C.A. Brown New, highly active metal catalysts for the hydrolysis of borohydride J Am Chem Soc 84 1962 1493 1494
18. 4 hydrolysis Int J Hydrogen Energy 34 2009 4780 4787
19. Y. Kojima, K. Suzuki, K. Fukumoto, M. Sasaki, T. Yamamoto, and Y. Kawai Hydrogen generation using sodium borohydride solution and metal catalyst coated on metal oxide Int J Hydrogen Energy 27 2002 1029 1034 (Pubitemid 34704402)
20. 4 solution using the high-performance Co-B catalyst J Power Sources 144 2005 129 134
21. M. Zahmakiran, F. Durap, and S. Ozkar Zeolite confined copper(0) nanoclusters as cost-effective and reusable catalyst in hydrogen generation from the hydrolysis of ammonia-borane Int J Hydrogen Energy 35 2010 187 197
22. S. Basu, Y. Zheng, A. Varma, W.N. Delgass, and J.P. Gore Catalytic hydrolysis of ammonia borane: Intrinsic parameter estimation and validation J Power Sources 195 2010 1957 1963
23. F. Durap, M. Zahmakiran, and S. Ozkar Water soluble laurate-stabilized ruthenium(0) nanoclusters catalyst for hydrogen generation from the hydrolysis of ammonia-borane: high activity and long lifetime Int J Hydrogen Energy 34 2009 7223 7230
24. J.M. Yan, X.B. Zhang, S. Han, H. Shioyama, and Q. Xu Synthesis of longtime water/air-stable Ni nanoparticles and their high catalytic activity for hydrolysis of ammonia-borane for hydrogen generation Inorg Chem 48 2009 7389 7393
25. M. Chandra, and Q. Xu A high-performance hydrogen generation system: Transition metal-catalyzed dissociation and hydrolysis of ammonia-borane J Power Sources 156 2006 190 194 (Pubitemid 43775655)
26. H.C. Kelly, and V.B. Marriott Reexamination of the mechanism of acid-catalyzed amine-borane hydrolysis. The hydrolysis of ammonia-borane Inorg Chem 18 1979 2875 2878
27. R.E. Davis, and J.A. Gottbrath Boron Hydrides. V. Methanolysis of sodium borohydride J Am Chem Soc 84 1962 895 898
28. P.V. Ramachandran, and P.D. Gagare Preparation of ammonia borane in high yield and purity, methanolysis, and regeneration Inorg Chem 46 2007 7810 7817
29. J. Zhang, T.S. Fisher, J.P. Gore, D. Hazra, and P.V. Ramachandran Heat of reaction measurements of sodium borohydride alcoholysis and hydrolysis Int J Hydrogen Energy 31 2006 2292 2298 (Pubitemid 44751991)
30. H.B. Dai, Kang XDong, and P. Wang Ruthenium nanoparticles immobilized in montmorillonite used as catalyst for methanolysis of ammonia borane Int J Hydrogen Energy 35 2010 10317 10323
31. E.A. Ison, R.A. Corbin, and M.M. Abu-Omar Hydrogen production from hydrolytic oxidation of organosilanes using a cationic oxorhenium catalyst J Am Chem Soc 127 2005 11938 11939 (Pubitemid 41233708)
32. J.M. Brunel New efficient hydrogen process production from organosilane hydrogen carriers derivatives Int J Hydrogen Energy 35 2010 3401 3405
33. J.J. Baschuk, and X. Li Modelling of polymer electrolyte membrane fuel cells with variable degrees of water flooding J Power Sources 86 2000 181 196 (Pubitemid 30587054)
34. 2 via silylene and silene intermediates Organometallics 29 2010 687 691
35. --catalyzed reactions of trichlorosilane and dichloromethylsilane with vinyltrichlorosilane: new synthetic method for 1,1,4,4-Tetrachloro-2,5-bis(trichlorosilyl)-1,4- disilacyclohexane compounds Organometallics 29 2010 3054 3057
36. I.N. Jung, B.R. Yoo, J.S. Han, and S.H. Kang Organosilicon Compound and Method for Producing organisilicon compound by double silylation reaction Jpn Kokai Tokkyo Koho 2003 2003321477
37. B.S. Furniss, A.T. Hannaford, V. Rogers, P.W.G. Smith, and A.R. Tatchell Vogel's Textbook of practical organic Chemistry 4th ed. 1978 Longman London
38. C.G. De Kruif, T. Kuipers, J.C.V. MIçtenburg, R.C.F. Schaake, and G. Stevnes The vapour pressure of solid and liquid naphthalene J Chem Thermodyn 13 1981 1081 1086
39. Even under the condition of stoichiometric amount of MeOH was used, the reaction rate was same. However, the amounts hydrogen released were slightly less as shown below because methanol evaporated considerably at the given exothermic reaction. For This Reason we used 2 equiv MeOH ensure completion Dehydrogenation. (see supplementary data Fig. S13).
40. C. Eaborn Organosilicon compounds 1960 Butterworths London
41. G. Fritz, and E. Matern Carbosilanes: synthesis and reactions 1986 Springer New York
42. E. Lukevics, and M. Dzintara The alcoholysis of hydrosilanes J Organomet Chem 295 1985 265 315
43. - J Am Chem Soc 108 1986 3139 3140
44. W.H. Stevenson, S. Wilson, J.C. Martin, and W.B. Famham Pseudorotational mechanism for the inversion of 10-Si-5 siliconates: ligand structure and reactivity J Am Chem Soc 107 1985 6340 6352
45. A. Hosomi, H. Hayashida, S. Kohra, and Y. Tominaga Pentaco-ordinate silicon compounds in synthesis: chemo- and stereo-selective reduction of carbonyl compounds using trialkoxy-substituted silanes and alkali metal alkoxides J Chem Soc Chem Commun 1986 1411 1412