Separation and purification processes for lignocellulose-to-bioalcohol production

Bioalcohol Production: Biochemical Conversion of Lignocellulosic Biomass

Volumn , Issue , 2010, Pages 246-277

  Huang, H J ^a   Ramaswamy, S ^a   Tschirner, U W ^a   Ramarao, B V ^b  

^a UNIVERSITY OF MINNESOTA   (United States)

^b SUNY UPSTATE MEDICAL UNIVERSITY   (United States)

Author keywords

Bioalcohol; Biorefinery; Ethanol; Extractive fermentation; Membrane separation bioreactor hybrid; Separation and purification

Indexed keywords

BIOCONVERSION; BIOREACTORS; DISTILLATION; ETHANOL; FERMENTATION; IONIC LIQUIDS; MOLECULAR SIEVES; PURIFICATION; REFINING;

BIOALCOHOL; BIOREFINERIES; EXTRACTIVE FERMENTATION; MEMBRANE SEPARATION BIOREACTOR; SEPARATION AND PURIFICATION;

SEPARATION;

EID: 80052383671     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1533/9781845699611.3.246     Document Type: Chapter

References (137)

1. Aden A., Ruth M., Ibsen K., Jechura J., Neeves K., Sheehan J., Wallace B., Montague L., Slayton A., Lukas J. 'Lignocellulosic biomass to ethanol process design and economics utilizing co-current dilute acid prehydrolysis and enzymatic hydrolysis for corn stover', NREL report TP-510-32438 Available at. http://www.nrel.gov/docs/fy02osti/32438.pdf.
2. Ahn H., Lee H., Lee S.B., Lee Y. Pervaporation of an aqueous ethanol solution through hydrophilic zeolite membranes. Desalination 2006, 193:244-251. 10.1016/j.desal.2005.06.062.
3. Am Al-Amer Investigating polymeric entrainers for azeotropic distillation of the ethanol/water and MTBE/methanol systems. Ind Eng Chem Res 2000, 39(10):3901-3906. 10.1021/ie0000515.
4. Al-Asheh S., Ganat F., Al-Lagtah N. Separation of ethanol-water mixtures using molecular sieves and biobased adsorbents. Chem Eng Res Design 2004, 82(A7):855-864. 10.1205/0263876041596779.
5. Amidon T. The Biorefinery in New York: Woody biomass into commercial ethanol. Pulp Pap Mag Can 2006, 107(6):47.
6. Arlt M., Seiler M., Jork C., Schneider T. DE Patent No. 2001, 10114734.
7. Barba D., Brandani V., Giacomo G. Hyperazeotropic ethanol salted-out by extractive distillation, Theoretical evaluation and experimental check. Chem Eng Sci 1985, 40:2287-2292.
8. Bausa J., Marquardt W. Shortcut design methods for hybrid membrane-distillation processes for the separation of nonideal multicomponent mixtures. Ind Eng Chem Res 2000, 39:1658-1672. 10.1021/ie990703t.
9. Beery K.E., Ladisch M.R. Chemistry and properties of starch based desiccants. Enzyme Microb Technol 2001, 28:573-581. 10.1016/S0141-0229(00)00345-8.
10. Beery K.E., Ladisch M.R. Adsorption of water from liquid-phase ethanol-water mixtures at room temperature using starch-based adsorbents. Ind Eng Chem Res 2001, 40:2112-2115. 10.1021/ie0009381.
11. Benson T.J., George C.E. Cellulose based adsorbent materials for the dehydration of ethanol using thermal swing adsorption. Chem Mat Sci 2005, 11(1):697-701. 10.1007/s10450-005-6009-1.
12. Berthold J., Rinaudo M., Salmen L. Association of water to polar groups; estimations by an adsorption model for ligno-cellulosic materials. Colloids and Surfaces A: Physicochemical and Engineering Aspects 1996, 112(2):117-129. 10.1016/0927-7757(95)03419-6.
13. Boluda N., Gomis V., Ruiz F., Bailador H. The influence of temperature on the liquid- liquid-solid equilibria of the ternary system water+ethanol+1-dodecanol. Fluid Phase Equilibria 2005, 235:99-103. 10.1016/j.fluid.2005.06.027.
14. Boudreau T.M., Hill G.A. Improved ethanol-water separation using fatty acids. Process Biochem 2006, 41:980-983. 10.1016/j.procbio.2005.11.006.
15. Bowen T.C., Li S., Tuan V.A., Falconer J.L., Noble R.D. Pervaporation of aqueous organic mixtures through Ge-ZSM-5 zeolite membranes. Desalination 2002, 147:327-329. 10.1016/S0011-9164(02)00560-X.
16. Bowen T.C., Li S., Kalipcilar H., Falconer J.L., Noble R.D. Pervaporation of organic/water mixtures through B-ZSM-5 zeolite membranes on monolith supports. J Membr Sci 2003, 215:235-247. 10.1016/S0376-7388(02)00617-8.
17. Bowen T.C., Noble R.D., Falconer J.L. Fundamentals and applications of pervaporation through zeolite membranes. J Membr Sci 2004, 245:1-33. 10.1016/j.memsci.2004.06.
18. Carmo M.J., Gubulin J.C. Ethanol-water adsorption on commercial 3a zeolites: kinetic and thermodynamic data. Brazilian J Chem Eng 1997, 14(3):1-10. 10.1590/S0104-66321997000300004.
19. Carmo M.J., Adeodato M.G., Moreira A.M., Parente E.J.S., Vieira R.S. Kinetic and Thermodynamic study on the liquid phase adsorption by starchy materials in the alcohol-water system. Adsorption 2004, 10(3):211-218. 10.1023/B:ADSO.0000046357.86218.16.
20. Caro J., Noack M. Zeolite membranes - recent developments and progress. Microporous and Mesoporous Materials 2008, 115:215-233. 10.1016/j.micromeso.2008.03.008.
21. Chang C.L., Chang M.S. Preparation of multi-layer silicone/PVDF composite membranes for pervaporation of ethanol aqueous solutions. J Membr Sci 2004, 238(1-2):117-122. 10.1016/j.memsci.2004.03.026.
22. Chang H., Yuan X.-G., Tian H., Zeng A.-W. Experimental investigation and modeling of adsorption of water and ethanol on cornmeal in an ethanol-water binary vapor system. Chem Eng Technol 2006, 29(4):454-461. 10.1002/ceat.200500384.
23. Chang H., Yuan X.-G., Tian H., Zeng A.-W. Experimental study on the adsorption of water and ethanol by cornmeal for ethanol dehydration. Ind Eng Chem Res 2006, 45:3916-3921. 10.1021/ie051043x.
24. Chapman P.D., Oliveira T., Livingston A.G., Li K. Membranes for the dehydration of solvents by pervaporation. J Membr Sci 2008, 318:5-37. 10.1016/j.memsci.2008.02.061.
25. Chen S.H., Yu K.C., Lin S.S., Chang D.J., Liou R.M. Pervaporation separation of water/ethanol mixture by sulfonated polysulfone membrane. J Membr Sci 2001, 183:29. 10.1016/S0376-7388(00)00544-5.
26. Chen X., Ping Z.H., Long Y.C. Separation properties of alcohol-water mixture through silicalite-I-filled silicone rubber membranes by pervaporation. J Appl Polym Sci 1998, 67:629-636. 10.1002/(SICI)1097-4628(19980124)67.
27. Chianese A., Zinnamosca F. Ethanol dehydration by azeotropic distillation with a mixed-solvent entrainer. Chem Eng J 1990, 43:59-65.
28. Cook R.A., Furter W.F. Extractive distillation employing a dissolved salt as separating agent. Can J Chem Eng 1968, 46:119-123.
29. Crawshaw J.P., Hills J.H. Sorption of ethanol and water by starchy materials. Ind Eng Chem Res 1990, 29:307-309. 10.1021/ie00098a023.
30. Cui Y., Kita H., Okamoto K.I. Zeolite T membrane: preparation, characterization, pervaporation of water/organic liquid mixtures and acid stability. J Membr Sci 2004, 236:17-27. 10.1016/j.memsci.2003.12.018.
31. Delta-T Company (2009), http://www.deltatcorp.com/molsieve.aspx.
32. Dong Y.Q., Zhang L., Shen J.N., Song M.Y., Chen H.L. Preparation of poly(vinyl alcohol)-sodium alginate hollow-fiber composite membranes and pervaporation dehydration characterization of aqueous alcohol mixtures. Desalination 2006, 193:202-210. 10.1016/j.desal.2005.08.023.
33. Duan Z.T., Lei L.H., Zhou R.Q. Study on extractive distillation with salt(I). Petrochem Technol (China) 1980, 9:350-353.
34. Feng G., Fan L.T., Friedler F. Synthesizing alternative sequences via a P-graph-based approach in azeotropic distillation systems. Waste Management 2000, 20:639-643. 10.1016/S0956-053X(00)00051-9.
35. Furter W.F. Extractive distillation by salt effect. Chem Eng Commun 1992, 116:35-40. 10.1080/00986449208936042.
36. Furter W.F. 'Extractive distillation by salt effect', in: Gould R F (eds). Extractive and Azeotropic Distillation, Advances in Chemistry Series 1972, 115:35-45.
37. Ge Y., Zhang L., Yuan X., Geng W., Ji J. Selection of ionic liquids as entrainers for separation of (water+ethanol). J Chem Thermodynamics 2008, 40:1248-1252. 10.1016/j.jct.2008.03.016.
38. Gomis V., Font A., Pedraza R., Saquete M.D. Isobaric vapor-liquid and vapor- liquid-liquid equilibrium data for the system water+ethanol+cyclohexane. Fluid Phase Equilibria 2005, 235:7-10. 10.1016/j.fluid.2005.07.015.
39. González-Velasco J.R., Gonzalez-Marcos J.A., Lopez-Dehesa C. Pervaporation of ethanol-water mixtures through poly(1-trimethylsilyl-1-propyne) (PTMSP) membranes. Desalination 2002, 149:61-65. 10.1016/S0011-9164(02)00692-6.
40. Gostoli C., Sarti G.C. Separation of liquid mixtures by membrane distillation. J Membr Sci 1989, 41:211-224.
41. Gryta M., Morawski A.W., Tomaszewska M. Ethanol Production in membrane distillation bioreactor. Catalysis Today 2000, 56:159-165. 10.1016/S0920-5861(99)00272-2.
42. Gyamerah M., Glover J. Production of ethanol by continuous fermentation and liquid-liquid extraction. J Chem Tech Biotechnol 1996, 66:145-152. 10.1002/(SICI)1097-4660(199606)66.
43. Hu X., Xie W. Fixed-Bed adsorption and fluidized-bed regeneration for breaking the azeotrope of ethanol and water. Sep Sci Technol 2001, 36(1):125-136.
44. Huang H.-J., Chen X.D., Yuan W.K. Microencapsulation based on emulsification for producing pharmaceutical products: a literature review. Dev Chem Eng Mineral Process 2006, 14:515-544. 10.1002/apj.5500140318.
45. Huang H.-J., Ramaswamy S., Tschirner U.W., Ramarao B.V. A review of separation technologies in current and future biorefineries. Sep Purif Technol 2008, 62(1):1-21. 10.1016/j.seppur.2007.12.011.
46. Huang H.-J., Ramaswamy S., Al-Dajani W., Tschirnera U., Cairncross R.A. Effect of biomass species and plant size on cellulosic ethanol: A comparative process and economic analysis. Biomass Bioenergy 2009, 33(2):234-246. 10.1016/j.biombioe.2008.05.007.
47. Huang H.-J., Lin W., Ramaswamy S., Tschirner U. Process modeling of comprehensive integrated forest biorefinery - an integrated approach. Appl Biochem Biotechnol 2009, 154(1-3):26-37. 10.1007/s12010-008-8478-7.
48. Huang H.-J., Ramaswamy S., Al-Dajani W., Tschirner U. Process modeling and analysis of pulp mill-based integrated biorefinery with hemicellulose pre-extraction for ethanol production: a comparative study. Biores Technol 2010, 101(2):624-631. 10.1016/j.biortech.2009.07.092.
49. Huang Z., Guan H.-M., Tan W.L., Qiao X.-Y., Kulprathipanja S. Pervaporation study of aqueous ethanol solution through zeolite-incorporated multilayer poly(vinyl alcohol) membranes: Effect of zeolites. J Membr Sci 2006, 276:260-271. 10.1016/j.memsci.2005.09.056.
50. Hung M.Y., Chen S.H., Liou R.M., Hsu C.S., Lai J.Y. Pervaporation separation of a water/ethanol mixture by a sodium sulfonate polysulfone membrane. J Appl Polym Sci 2003, 90:3374. 2283. 10.1002/app.12947.
51. Ikegami T., Yanagishita H., Kitamoto D., Haraya K., Nakane T., Matsuda H., Koura T., Sano N. Production of highly concentrated ethanol in a coupled fermentation/pervaporation process using silicalite membranes. Biotechnol Tech 1997, 11:921-924. 10.1023/A:1018474603027.
52. Ikegami T., Yanagishita H., Kitamoto D., Haraya K., Nakane T., Matsuda H., Koura N., Sano T. Highly concentrated aqueous ethanol solutions by pervaporation using silicalite membrane - improvement of ethanol selectivity by addition of sugars to ethanol solution. Biotechnol Lett 1999, 21:1037-1041. 10.1023/A:1005627421221.
53. Ikegami T., Yanagishita H., Kitamotoa T., Negishi H., Haraya K., Sano T. Concentration of fermented ethanol by pervaporation using silicalite membranes coated with silicone rubber. Desalination 2002, 149:49-54. 10.1016/S0011-9164(02)00690-2.
54. Ikegami T., Kitamoto D., Negishi H., Haraya K., Matsuda H., Nitanai Y., Koura N., Sano T., Yanagish H. Drastic improvement of bioethanol recovery using a pervaporation separation technique employing a silicone rubber-coated silicalite membrane. J Chem Technol Biotechnol 2003, 78:1006-1010. 10.1002/jctb.897.
55. Izquierdo-Gil M.A., Jonsson G. Factors affecting flux and ethanol separation performance in vacuum membrane distillation (VMD). J Membr Sci 2003, 214:113-130. 10.1016/S0376-7388(02)00540-9.
56. Jia M.D., Peinemann K.V., Behling R.D. Preparation and characterization of thin-film zeolite-PDMS composite membranes. J Membr Sci 1992, 73:119.
57. Jiang L.Y., Wang Y., Chung T.-S., Qiao X.Y., Lai J.-Y. Polyimides membranes for pervaporation and biofuels separation. Prog Polym Sci 2009, 10.1016/j.progpolymsci.2009.06.001.
58. Jiraratananon R., Chanachai A., Huang R.Y.M., Uttapap D. Pervaporation dehydration of ethanol-water mixtures with chitosan/hydroxyethylcellulose (CS/HEC) composite membranes. 1. Effect of operating conditions. J Membr Sci 2002, 195:143. 10.1016/S0376-7388(01)00563-4.
59. Karakane H., Tsuyumoto M., Maeda Y., Honda Z. Separation of Water-Ethanol by Pervaporation through Polyion Complex Composite Membrane. J Appl Polym Sci 1991, 42:3229.
60. Kim J.H., Lee K.H., Kim S.Y. Pervaporation separation of water from ethanol through polyimide composite membranes. J Membr Sci 2000, 169:81-93. 10.1016/S0376-7388(99)00335-X.
61. Kita H., Fuchida K., Horita T., Asamura H., Okamoto K.I. Preparation of Faujasite membranes and their permeation properties. Sep Purif Technol 2001, 25:261-268.
62. Kondo M., Komori M., Kita H., Okamoto K. Tubular type pervaporation module with zeolite NaA membrane. J Membr Sci 1997, 133:133-141. 10.1016/S0376-7388(97)00087-2.
63. Koros W.J. Evolving beyond the thermal age of separation processes: Membranes can lead the way. AIChE J 2004, 50:2326-2334. 10.1002/aic.10330.
64. Koullas D.P., Umealu O.S., Koukios E.G. Solvent selection for the extraction of ethanol from aqueous solutions. Sep Sci Technol 1999, 34(11):2153-2163. 10.1021/bp00008a006.
65. Kovach J.W., Seider W.D. Heterogeneous azeotropic distillaion-homotopy-continuation methods. Comput Them Engng 1987, 11(6):593-605.
66. Krea M., Roizard D., Moulai-Mostefa N., Sacco D. New copolyimide membranes with high siloxane content designed to remove polar organics from water by pervaporation. J Membr Sci 2004, 241:55-64. 10.1016/j.memsci.2004.03.040.
67. Kuhn J., Sutanto S., Gascon J., Gross J., Kapteijn F. Performance and stability of multi-channel MFI zeolite membranes detemplated by calcination and ozonication in ethanol/water pervaporation. J Membr Sci 2009, 339:261-274. 10.1016/j.memsci.2009.05.006.
68. Ladisch M.R., Dyck K. Dehydration of ethanol: new approach gives positive energy balance. Science 1979, 205:898-900. 10.1126/science.205.4409.898.
69. Ladisch M.R., Tsao G.T. Vapor phase dehydration of aqueous alcohol mixtures 1982, US Patent 4 345 973.
70. Ladisch M.R., Voloch M., Hong J., Bienkowski P., Tsao G.T. Cornmeal adsorber for dehydrating ethanol vapors. Ind Eng Chem Process Des Dev 1984, 23:437-443. 10.1021/i200026a005.
71. Lai J.Y., Li S.H., Lee K.R. Permselectivities of polysiloxaneimide membrane for aqueous ethanol mixture in pervaporation. J Membr Sci 1994, 93:273-282.
72. Lee F.-M., Pahl R.H. Solvent screening study and conceptual extractive distillation process to produce anhydrous ethanol from fermentation broth. Ind Eng Chem Process Des Dev 1985, 24:168-172. 10.1021/i200028a029.
73. Lee K.R., Teng M.Y., Lee H.H., Lai J.Y. Dehydration of ethanol/water mixtures by pervaporation with composite membranes of polyacrylic acid and plasma-treated polycarbonate. J Membr Sci 2000, 164:13-23. 10.1016/S0376-7388(99)00097-6.
74. Lee Y.M., Nam S.Y., Woo D.J. Pervaporation of ionically surface crosslinked chitosan composite membranes for water-alcohol mixtures. J Membr Sci 1997, 133:103-110. 10.1016/S0376-7388(97)00089-6.
75. Lei Z., Chen B., Ding Z. Special Distillation Processes, Amsterdam, Elsevier. Study on extractive distillation with salt(II) 2005, 11:404-409. Petrochem Technol, China, (1982),. L.H. Lei, Z.T. Duan, Y.F. Xu (Eds.).
76. Lei Z., Wang H., Zhou R., Duan Z. Influence of salt added to solvent on extractive distillation. Chem Eng J 2002, 87:149-156. 10.1016/S1385-8947(01)00211-X.
77. Lewandowska W., Kujawski W. Ethanol production from lactose in a fermentation/pervaporation system. J Food Eng 2007, 79:430-437. 10.1016/j.jfoodeng.2006.01.071.
78. Li C.L., Lee K.R. Dehydration of ethanol/water mixtures by pervaporation using soluble polyimide membranes. Polym Int 2006, 55:505-512. 10.1002/pi.1991.
79. Ligero E.L., Ravagnani T.M.K. Dehydration of ethanol with salt extractive distillation - a comparative analysis between processes with salt recovery. Chem Eng Proc 2003, 42(7):543-552. 10.1016/S0255-2701(02)00075-2.
80. Lin X., Kita H., Okamoto K. Silicalite membrane preparation, characterization, and separation performance. Ind Eng Chem Res 2001, 40:4069-4078. 10.1021/ie0101947.
81. Lin X., Chen X., Kita H., Okamoto K. Synthesis of silicalite tubular membranes by in situ crystallization. AIChE J 2003, 49(1):237-247. 10.1002/aic.690490122.
82. Lipnizki F., Hausmanns S., Laufenberg G., Field R., Kunz B. Use of pervaporation-bioreactor hybrid processes in biotechnology. Chem Eng Technol 2000, 23:569-577. 10.1002/1521-4125(200007)23.
83. Liu S., Amidon T.E., Francis R.C., Ramarao B.V., Lai Y.Z., Scott G.M. From forest biomass to chemicals and energy. Ind Biotechnol 2006, 2(2):113-120. 10.1089/ind.2006.2.113.
84. Llano-Restrepo M., Aguilar-Arias J. Modeling and simulation of saline extractive distillation columns for the production of absolute ethanol. Computers Chem Eng 2003, 27:527-549. 10.1016/S0098-1354(02)00215-6.
85. Luyben W.L. Control of a multiunit heterogeneous azeotropic distillation process. AIChE J 2006, 52(2):623-637. 10.1002/aic.10650.
86. Lynd L.R., Grethlein H.E. IHOSR/Extractive distillation for ethanol separation. Chem Eng Prog 1984, 80:59-62.
87. Maciel M.R.W., Brito R.P. Evaluation of the dynamic behavior of an extractive distillation column for dehydration of aqueous ethanol mixtures. Computers Chem Eng 1995, 19(Suppl):S405-S408.
88. Martin C.R., Aranda P., Chen W.J. Pervaporation separation of ethanol/water mixtures by polystyrenesulfonate/alumina composite membranes. J Membr Sci 1995, 107:199-207. 10.1016/0376-7388(95)00066-4.
89. Matsuda H., Yanagishita H., Kitamoto D., Nakane T., Haraya K., Koura N., Sano T. Preparation of silicalite pervaporation membrane with high ethanol permselectivity. Membrane 1998, 23:259.
90. Moermans B., De Beuckelaer W., Vankelecom I.F.J., Ravishankar R., Martens J.A., Jacobs P.A. Incorporation of nano-sized zeolites in membranes. Chem Commun 2000, 2467-2468. 10.1039/b007435g.
91. Morigami Y., Kondo M., Abe J., Kita H., Okamoto K. The first large-scale pervaporation plant using tubular-type module with zeolite NaA membrane. Sep Purif Technol 2001, 25(1-3):251-260. 10.1016/S1383-5866(01)00109-5.
92. Moritz J.W., Duff S.J.B. Simultaneous saccharification and extractive fermentation of cellulosic substrates. Biotechnol Bioeng 1996, 49:504-511. 10.1002/(SICI)1097-0290(19960305)49.
93. Nagase Y., Takamura Y., Matsui K. Chemical modification of poly(substituted-acetylene): V. Alkylsilylation of poly(1-trimethylsilyl-1-propyne) and improved liquid separating property at pervaporation. J Appl Polym Sci 1991, 42:185-190. 10.1002/app.1991.070420122.
94. Namboodiri, Vane L.M. High permeability membranes for the dehydration of low water content ethanol by pervaporation. J Membr Sci 2007, 306:209-215. doi: 10.1016/j.memsci.2007.08.050.
95. Navajas A., Mallada R., Tellez C., Coronas J., Menendez M., Santamaria J. Study on the reproducibility of mordenite tubular membranes used in the dehydration of ethanol. J Membr Sci 2007, 299:166-173. 10.1016/j.memsci.2007.04.038.
96. Nomura M., Bin T., Nakao S. Selective ethanol extraction from fermentation broth using a silicalite membrane. Sep Purif Technol 2002, 27(1):59-66.
97. Nomura M., Yamaguchi T., Nakao S. Ethanol/water transport through silicalite membranes. J Membr Sci 1998, 144:161-171. 10.1016/S0376-7388(98)00043-X.
98. Nomura M., Yamaguchi T., Nakao S. Transport phenomena through intercrystalline and intracrystalline pathways of silicalite zeolite membranes. J Membr Sci 2001, 187(1-2):203-212. 10.1016/S0376-7388(01)00350-7.
99. O'Brien D.J., Craig J.C. Ethanol production in a continuous fermentation/membrane pervaporation system. Appl Microbiol Biotechnol 1996, 44:699-704. 10.1007/s002530050619.
100. Offeman R.D., Stephenson S.K., Franqui D., Cline J.L., Robertson G.H., Orts W.J. Extraction of ethanol with higher alcohol solvents and their toxicity to yeast. Sep Purif Technol 2008, 63(2):444-451. 10.1016/j.seppur.2008.06.005.
101. Okamoto K.I., Kita H., Horii K., Tanaka K. Zeolite NaA membrane: preparation, single-gas permeation, and pervaporation and vapor permeation of water/organic liquid mixtures. Ind Eng Chem Res 2001, 40:163-175. 10.1021/ie0006007.
102. Partin L.R. 'A case study in applying pc software: Flowsheet synthesis', Proceedings of Chemputers 4: Computer Tools for the Chemical Process Industries, Houston. Texas. 1996, 11-13.
103. Pinto R.T.P., Wolf-Maciel M.R., Lintomen L. Saline extractive distillation process for ethanol purification. Computers Chem Eng 2000, 24:1689-1694. 10.1016/S0098-1354(00)00455-5.
104. Qiu W., Kosuri M., Zhou F., Koros W.J. Dehydration of ethanol-water mixtures using asymmetric hollow fiber membranes from commercial polyimides. J Membr Sci 2009, 327:96-103. 10.1016/j.memsci.2008.11.029.
105. Rakshit S.K., Ghosh P., Bisaria V.S. Ethanol separation by selective adsorption of water. Bioprocess Biosys Eng 1993, 8(5-6):279-282. 10.1007/BF00369841.
106. Ruckenstein E., Liang L. Pervaporation of ethanol-water mixtures through polydimethylsiloxane-polystyrene interpenetrating polymer network supported membranes. J Membr Sci 1996, 114:227-234. 10.1016/0376-7388(95)00319-3.
107. Ruthven D.M. Principles of Adsorption and Adsorption Processes 1984, John Wiley, New York.
108. Sano T., Yanagishita H., Kiyozumi Y., Mizukami F., Haraya K. Separation of ethanol-water mixture by silicalite membrane on pervaporation. J Membr Sci 1994, 95(3):221-228.
109. Sato K., Nakane T. A high reproducible fabrication method for industrial production of high flux NaA zeolite membrane. J Membr Sci 2007, 301:151-161. 10.1016/j.memsci.2007.06.010.
110. Seiler M., Jork C., Kavarnou A., Arlt W., Hirsch R. Separation of azeotropic mixtures using hyperbranched polymers or ionic liquids. AIChE J 2004, 50(10):2439-2454. 10.1002/aic.10249.
111. Sekulic J., Elshof J.E.T., Blank D.H.A. Separation mechanism in dehydration of water/organic binary liquids by pervaporation through microporous silica. J Membr Sci 2005, 254:267-274.
112. Shah D., Kissick K., Ghorpade A., Hannah R., Bhattacharyya D. Pervaporation of alcohol-water and dimethylformamide-water mixtures using hydrophilic zeolite NaA membranes: mechanisms and experimental results. J Membr Sci 2000, 179:185-205. 10.1016/S0376-7388(00)00515-9.
113. Shao P., Huang R.Y.M. Polymeric membrane pervaporation. J Membr Sci 2007, 287:162-179. 10.1016/j.memsci.2006.10.043.
114. Shi Y., Wang X., Chen G., Golemme G., Zhang S., Drioli E. Preparation and characterization of high-performance dehydrating pervaporation alginate membranes. J Appl Polym Sci 1998, 68:959-968.
115. Shieh J.J., Huang R.Y.M. Pervaporation with chitosan membranes, II. Blend membranes of chitosan and polyacrylic acid and comparison of homogeneous and composite membrane based on polyelectrolyte complexes of chitosan and polyacrylic acid for the separation of ethanol-water mixtures. J Membr Sci 1997, 127:185-202. 10.1016/S0376-7388(96)00279-7.
116. Slater C.S., Hickey P.J., Juricic F.P. Pervaporation of aqueous ethanol mixtures through poly(dimethyl siloxane) membranes. Sep Sci Technol 1990, 25:1063-1077.
117. Sommer S., Melin T. 'Zeolite membranes in chemical industry', The 2000 18th Annual Membrane Technology/Separations Planning Conference 2000, Massachusetts, USA, Boston.
118. Sommer S., Melin T. Performance evaluation of microporous inorganic membranes in the dehydration of industrial solvents. Chem Eng Process 2005, 44(10):1138-1156. 10.1016/j.cep.2005.02.006.
119. Takegami S., Yamada H., Tsujii S. Pervaporation of ethanol/water mixtures using novel hydrophobicmembranes containing polydimethylsiloxane. J Membr Sci 1992, 75:93-105.
120. Uragami T., Matsugi H., Miyata T. Pervaporation characteristics of organic-inorganic hybrid membranes composed of poly(vinyl alcohol-co-acrylic acid) and tetraethoxysilane forwater/ethanol separation. Macromolecules 2005, 38:8440-8446. 10.1021/ma051450k.
121. Vane L.M. A review of pervaporation for product recovery from biomass fermentation processes. J Chem Technol Biotechnol 2005, 80:603-629. 10.1002/jctb.l265.
122. Vankelecom I.F.J., Depre D., De Beukelaer S., Uytterhoeven J.B. Influence of zeolites in PDMS membranes: pervaporation of water/alcohol mixtures. J Phys Chem 1995, 99:13193-13197. 10.1021/j100035a024.
123. Vankelecom I.F.J., De Beukelaer S., Uytterhoeven J.B. Sorption and pervaporation of aroma compounds using zeolitefilled PDMS membranes. J Phys Chem B 1997, 101:5186-5190. 10.1021/jp962273f.
124. van Veen H.M., van Delft Y.C., Engelen C.W.R., Pex P.P.A.C. Dewatering of organics by pervaporation with silica membranes. Sep Purif Technol 2001, 22-23:361-366. 10.1016/S1383-5866(00)00119-2.
125. Verhoef A., Figoli A., Bram Leen, Bettens B., Drioli E., Bruggen B.V. Performance of a nanofiltration membrane for removal of ethanol from aqueous solutions by pervaporation. Sep Purif Technol 2008, 60:54-63. 10.1016/j.seppur.2007.07.044.
126. Volkov V.V., Fadeev A.G., Khotimsky V.S., Litvinova E.G., Selinskaya Y.A., McMillan J.D., Kelley S.S. Effects of synthesis conditions on the pervaporation properties of poly[1-(trimethylsilyl)-1-propyne] useful for membrane bioreactors. J Appl Polym Sci 2004, 91(4):2271-2277. 10.1002/app.13358.
127. Wang J.F., Li C.X., Wang Z.H., Li Z.J., Jiang Y.B. Vapor pressure measurement for water, methanol, ethanol, and their binary mixtures in the presence of an ionic liquid 1-ethyl-3-methylimidazolium dimethylphosphate. Fluid Phase Equilibria 2007, 255:186-192. 10.1016/j.fluid.2007.04.010.
128. Wasylkiewicz S.K., Kobylka L.C., Castillo F.J.L. Synthesis and design of heterogeneous separation systems with recycle streams. Chem Eng J 2003, 92:201-208. 10.1016/S1385-8947(02)00256-5.
129. Weilnhammer C., Blass E. Continuous fermentation with product recovery by in-situ extraction. Chem Eng Technol 1994, 17:365-373. 10.1002/ceat.270170602.
130. Wyman C.E. Ethanol production from lignocellulosic biomass: overview. Handbook on Bioethanol: Product Ion and Utilization 1996, 1-18. Taylor & Francis, Washington DC. C.E. Wyman (Ed.).
131. Yanagishita H., Maejima C., Kitamoto D., Nakane T. Preparation of asymmetric polyimide membrane for water/ethanol separation in pervaporation by the phase inversion process. J Membr Sci 1994, 86:231.
132. 2 nanocomposite pervaporation membranes for ethanol dehydration. Chem Eng Sci 2009, 64:3130-3137. 10.1016/j.ces.2009.03.042.
133. Yeom C.K., Lee S.H., Lee J.M. Pervaporative permeations of homologous series of alcohol aqueous mixtures through a hydrophilic membrane. J Appl Polym Sci 2001, 79:703-713. 10.1002/1097-4628(20010124)79.
134. Zhang Q.K., Qian W.C., Jian W.J. Study on extractive distillation with salt (III). Petrochem Technol (China) 1984, 13:1-9.
135. Zhang W., Li G.W., Fang Y.J., Wang X.P. Maleic anhydride surface-modification of crosslinked chitosan membrane and its pervaporation performance. J Membr Sci 2007, 295:130-138. 10.1016/j.memsci.2007.03.001.
136. Zhao J., Dong C.C., Li C.X., Meng H., Wang Z.H. Isobaric vapor-liquid equilibria for ethanol-water system containing different ionic liquids at atmospheric pressure. Fluid Phase Equilibria 2006, 242:147-153. 10.1016/j.fluid.2006.01.023.
137. Zhao Q., Qian J., An Q., Gao C., Gui Z., Jin H. Synthesis and characterization of soluble chitosan/sodium carboxymethyl cellulose polyelectrolyte complexes and the pervaporation dehydration of their homogeneous membranes. J Membr Sci 2009, 333:68-78. 10.1016/j.memsci.2009.02.001.