High permeability membranes for the dehydration of low water content ethanol by pervaporation

Journal of Membrane Science

Volumn 306, Issue 1-2, 2007, Pages 209-215

  Namboodiri, Vasudevan V ^a   Vane, Leland M ^a  

^a U S ENVIRONMENTAL PROTECTION AGENCY   (United States)

Author keywords

Degree of hydrolysis; Dehydration; Pervaporation; Poly(allylamine hydrochloride); PVA

Indexed keywords

DEGREE OF HYDROLYSIS; POLYALLYLAMINE HYDROCHLORIDE; PVA;

CROSSLINKING; DEHYDRATION; ETHANOL; PERVAPORATION;

MECHANICAL PERMEABILITY;

ALCOHOL; ALLYLAMINE; POLY(ALLYLAMINE); POLYVINYL ALCOHOL; UNCLASSIFIED DRUG; WATER;

CROSSLINKING; DEHYDRATION; ETHANOL; MECHANICAL PERMEABILITY; PERVAPORATION;

ARTICLE; CALCULATION; CROSS LINKING; DESICCATION; ENERGY; HYDROLYSIS; HYDROPHILICITY; PERMEABILITY BARRIER; PERVAPORATION; PRIORITY JOURNAL; REACTION ANALYSIS; WATER CONTENT; WATER PERMEABILITY;

EID: 35748950422     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.memsci.2007.08.050     Document Type: Article

References (26)

1. Standard specification for denatured fuel ethanol for blending with gasolines for use as automotive spark-ignition engine fuel. D4806-04a. 2004. ASTM International.
2. Feng X., and Huang R.Y.M. Liquid separation by membrane pervaporation: a review. Ind. Eng. Chem. Res. 36 (1997) 1048-1066
3. Wijmans J.G., and Baker R.W. The solution-diffusion model: a review. J. Membr. Sci. 107 (1995) 1-21
4. Kober P.A.J. Pervaporation, perstillation and percrystallization. J. Am. Chem. Soc. 39 (1917) 944-948
5. Yu J., Lee C.H., and Hong W.H. Performances of cross-linked asymmetric poly(vinyl alcohol) membranes for isopropanol dehydration by pervaporation. Chem. Eng. Process. 41 (2002) 693-698
6. Lee C.H., and Hong W.H. Influence of different degrees of hydrolysis of poly(vinyl alcohol) membrane on transport properties in pervaporation of IPA/water mixture. J. Membr. Sci. 135 (1997) 187-193
7. Nobrega R., Habert A.C., Garcia M.E.F., Esposito R.J., and Borges C.P. Separation of ethanol/water mixtures by pervaporation through polyvinylalcohol membranes. Proceedings of 3rd International Conference on Pervaporation Processes in the Chemical Industry (1988), Bakish Materials Corporation, Englewood, NJ, USA 326-337
8. Yeom C.K., Lee S.H., and Lee J.M. Pervaporative permeations of homologous series of alcohol aqueous mixtures through a hydrophilic membrane. J. Appl. Polym. Sci. 79 (2001) 703-713
9. Gallego-Lizon T., Ho Y.S., and dos Santos L.F. Comparative study of commercially available polymeric and microporous silica membranes for the dehydration of IPA/water mixtures by pervaporation/vapour permeation. Desalination 149 (2002) 3-8
10. Verkerk A.W., van Male P., Vorstman A.W., and Keurentjes J.T.F. Description of dehydration performance of amorphous silica pervaporation membranes. J. Membr. Sci. 193 (2001) 227-238
11. Wynn N. Dehydration with silica pervaporation membranes. Sulzer Tech. Rev. 82 (2000) 10-11
12. van Veen H.M., van Delft Y.C., Engelen C.W.R., and Pex P.P.A.C. Dewatering of organics by pervaporation with silica membranes. Sep. Purif. Technol. 22-23 (2001) 361-366
13. Li S., Tuan V.A., Noble R.D., and Falconer J.L. Pervaporation of water/THF mixtures using zeolite membranes. Ind. Eng. Chem. Res. 40 (2001) 4577-4585
14. Ahn H., Lee H., Lee S.B., and Lee Y. Pervaporation of an aqueous ethanol solution through hydrophilic zeolite membranes. Desalination 193 (2006) 244-251
15. Okamoto K.-I., Kita H., Horii K., Tanaka K., and Kondo M. Zeolite NaA membrane: preparation, single-gas permeation, and pervaporation and vapor permeation of water/organic liquid mixtures. Ind. Eng. Chem. Res. 40 (2001) 163-175
16. Van Hoof P.L., Dotremont C., and Buekenhoudt A. Performance of Mitsui NaA type zeolite membranes for the dehydration of organic solvents in comparison with commercial polymeric pervaporation membranes. Sep. Purif. Technol. 48 (2006) 304-309
17. Nam S.Y., Chun H.J., and Lee Y.M. Pervaporation separation of water-isopropanol mixture using carboxymethylated poly(vinyl alcohol) composite membranes. J. Appl. Polym. Sci. 72 (1999) 241-249
18. Dong Y.Q., Zhang L., Shen J.N., Song M.Y., and Chen H.L. Preparation of poly(vinyl alcohol)-sodium alginate hollow-fiber composite membranes and pervaporation dehydration characterization of aqueous alcohol mixtures. Desalination 193 (2006) 202-210
19. Peters T.A., Poeth C.H.S., Benes N.E., Buijs H.C.W.M., Vercauteren F.F., and Keurentjes J.T.F. Ceramic-supported thin PVA pervaporation membranes combining high flux and high selectivity; contradicting the flux-selectivity paradigm. J. Membr. Sci. 276 (2006) 42-50
20. Schehlmann M.S., Wiedemann E., and Lichtenthaler R.N. Pervaporation and vapor permeation at the azeotropic point or in the vicinity of the LLE boundary phases of organic/aqueous mixtures. J. Membr. Sci. 107 (1995) 277-282
21. van Baelen D., Van der Bruggen B., van den Dungen K., Degreve J., and Vandecasteele C. Pervaporation of water-alcohol mixtures and acetic acid-water mixtures. Chem. Eng. Sci. 60 (2005) 1583-1590
22. van Baelen D., Reyniers A., Van der Bruggen B., Vandecasteele C., and Degreve J. Pervaporation of binary and ternary mixtures of water with methanol and/or ethanol. Sep. Sci. Technol. 39 (2004) 563-580
23. Namboodiri V.V., Ponangi R., and Vane L.M. A novel hydrophilic polymer membrane for the dehydration of organic solvents. Eur. Polym. J. 42 (2006) 3390-3393
24. Mulder M. Basic Principles of Membrane Technology. 2nd ed. (1996), Kluwer Academic Publishers, Netherlands pp. 325-339
25. Wijmans J.G. Process performance = membrane properties + operating conditions. J. Membr. Sci. 220 (2003) 1-3
26. Shi Y.Q., Wang X.W., Chen G.W., Golemme G., Zhang S.M., and Drioli E. Preparation and characterization of high-performance dehydrating pervaporation alginate membranes. J. Appl. Polym. Sci. 68 (1998) 959-968