Thermochemistry of the initial steps of methylaluminoxane formation. Aluminoxanes and cycloaluminoxanes by methane elimination from dimethylaluminum hydroxide and its dimeric aggregates

Journal of the American Chemical Society

Volumn 133, Issue 34, 2011, Pages 13323-13336

  Glaser, Rainer ^a   Sun, Xinsen ^a  

^a UNIVERSITY OF MISSOURI   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AB INITIO STUDY; ALUMINOXANE; BONDING PROPERTY; COCATALYST; DIMETHYL ETHERS; ETHYLENE POLYMERIZATION CATALYSTS; HETEROCUMULENES; KINETIC STABILITY; LEWIS ACID SITE; METHYLALUMINOXANE; REACTION FREE ENTHALPIES; REVERSIBLE FORMATION; RING OPENING; SMALL CONCENTRATION; TRANSITION METAL CATALYSTS; TRIMETHYLALUMINUM;

ALUMINUM; CATALYSTS; ETHYLENE; ISOMERS; METHANE; OLIGOMERIZATION; OLIGOMERS; OXYGEN; THERMOCHEMISTRY; TRANSITION METALS;

AGGREGATES;

ALUMINUM; ALUMINUM DERIVATIVE; CYCLOALUMINOXANE; DIMER; DIMETHYLALUMINUM HYDROXIDE; ETHYLENE; LEWIS ACID; METAL COMPLEX; METHANE; METHYLALUMINOXANE; OXYGEN; TRIALUMINOXANE; UNCLASSIFIED DRUG; WATER;

ARTICLE; CATALYST; CHEMICAL BINDING; COMPLEX FORMATION; DIMERIZATION; ELIMINATION REACTION; ENTHALPY; ISOMER; KINETICS; OLIGOMERIZATION; PHASE TRANSITION; PHYSICAL CHEMISTRY; POLYMERIZATION; RING OPENING; THERMOCHEMISTRY; THERMODYNAMICS;

EID: 80052092883     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja109457j     Document Type: Article

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