Trace metal composition of suspended particulate matter in the water column of the Black Sea

Marine Chemistry

Volumn 126, Issue 1-4, 2011, Pages 207-228

  Yigiterhan, Oguz ^a   Murray, James W ^b   Tugrul, Süleyman ^a  

^a MIDDLE EAST TECHNICAL UNIVERSITY   (Turkey)

^b UNIVERSITY OF WASHINGTON   (United States)

Author keywords

Anoxic; Anoxic basin; Biogenic material; Biogenic matter; Biogeochemical cycle; Biogeochemistry; Black Sea; Brackish water; Danube; Depletions; Enrichments; Geochemistry; Lithogenic; Oxic; Particulates; Plankton; Planktonic metal concentration; Redox environments; Redox metals; Redox reactions; Rivers; Sediment; Suboxic; Sulfidic; Suspended particulate matter; Terrestrial; Trace elements; Trace metals; Tracers; Turkish rivers; Water column

Indexed keywords

ANTHROPOGENIC EFFECT; BIOACCUMULATION; BIOGENIC MATERIAL; BIOGEOCHEMICAL CYCLE; BIOLOGICAL PRODUCTION; BRACKISH WATER; CHEMICAL COMPOSITION; OPEN OCEAN; PLANKTON; POLLUTION EXPOSURE; REDOX CONDITIONS; SCAVENGING (CHEMISTRY); SUSPENDED PARTICULATE MATTER; TRACE METAL; TRACER; VERTICAL DISTRIBUTION; WATER COLUMN;

BLACK SEA; DANUBE RIVER; TURKEY;

EID: 80051948519     PISSN: 03044203     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.marchem.2011.05.006     Document Type: Article

References (133)

1. Anderson R.F., LeHuray A.P., Fleischer M.Q., Murray J.W. Uranium deposition in Saanich Inlet sediments, Vancouver Island. Geochimica et Cosmochimica Acta 1989, 53:2205-2213.
2. Anderson R.F., Fleischer M.Q., Lyons T., Cowie G. Sedimentary record of a shoaling of the oxic/anoxic interface in the Black Sea. EOS, Transactions, American Geophysical Union 1991, 72(51):36-37.
3. Bacon M.P., Edmond J.M. Barium at GEOSEC III in the Southwest Pacific. Earth and Planetery Science Letters 1972, 16:66-74.
4. Balistrieri L.S., Murray J.W. The surface chemistry of goethite (alpha-FeOOH) in major ion sea water. American Journal of Science 1981, 281:788-806.
5. 2 in major ion sea water. Geochimica et Cosmochimica Acta 1982, 46(6):1041-1052.
6. Balistrieri L.S., Murray J.W. The adsorption of Cu, Pb, Zn, and Cd on goethite from major ion seawater. Geochimica et Cosmochimica Acta 1982, 46(7):1253-1265.
7. Bargar J.R., Tebo B.M., Bergmann U., Webb S.M., Glatzel P., Chiu V.Q., Villalobos M. Biotic and abiotic products of Mn(II) oxidation by spores of the marine Bacillus sp. strain SG-1. American Mineralogist 2005, 90:143-154.
8. Bertine K.K. The deposition of molybdenum in anoxic water. Marine Chemistry 1972, 1:43-53.
9. Bevington P.R., Robinson D.K. Data Reduction and Error Analysis for the Physical Sciences 1992, McGraw Hill, 328 pp. 2nd edition.
10. Bishop J. The barite-opal-organic carbon association in oceanic particulate matter. Nature 1988, 332:341-343.
11. Boyle E.A. Cadmium: chemical tracer of deep-water paleoceanography. Paleoceanography 1988, 3:471-490.
12. Boyle E.A., Sclater F., Edmond J.M. The distribution of dissolved copper in the Pacific. Earth and Planetery Science Letters 1977, 37:38-54.
13. Brewer P.G., Spencer D.W. Distribution of some trace elements in Black Sea and their flux between dissolved and particulate phases. Memoirs of the American Association of Petroleum Geologists 1974, vol. 20:137-143. American Association of Petroleum Geologists, Tulsa, Oklahoma, USA. E.T. Degens, D.A. Ross (Eds.).
14. Bruland K.W. Oceanographic distributions of cadmium, zinc, nickel, and copper in the North Pacific. Earth and Planetery Science Letters 1980, 47:176-198.
15. Bruland K.W. Trace elements in seawater. Chemical Oceanography 1983, 8:157-221. Academic Press, New York. J.P. Riley, R. Chester (Eds.).
16. Bruland K.W., Donat J.R., Hutchins D.A. Interactive influences of bioactive trace-metals on biological production in oceanic waters. Limnology and Oceanography 1991, 36:1555-1577.
17. Burton J.D., Stratham P.J. Trace metals as tracers in the ocean. Philosophical Transactions of the Royal Society of London 1988, 325:127-145.
18. Calvert S.E., Pedersen T.F. Geochemistry of recent oxic and anoxic marine sediments: Implications for the geological record. Marine Geology 1993, 113:67-88.
19. Calvert S.E., Pederson T.F. Elemental proxies for paleoclimatic and paleoceanographic variability in marine sediments: interpretations and application. Paleoceanography of the Late Cenozoic. Part 1. Methods of Late Cenozoic Paleoceanography 2007, 567-644. Elsevier, New York. C. Hillaire-Marcel, A. de Vernal (Eds.).
20. Caspers H. Black Sea and Sea of Azov. J.W. Hedgpeth. Geological Society of America Memoirs 1957, 801-921.
21. Chan L., Drummond D., Edmond J., Grant B. On the barium data from the Atlantic GEOSEC Expedition. Deep-Sea Research 1977, 24:613-649.
22. Codispoti L.A., Friederich G.E., Murray J.W., Sakamoto C.M. Chemical variability in the Black Sea: implications of continuous vertical profiles that penetrated the oxic/anoxic interface. Deep-Sea Research 1991, 38(2a):691-710.
23. Collier R.W. Particulate and dissolved vanadium in the North Pacific Ocean. Nature (London) 1984, 309:441-444.
24. Collier R.W. Molybdenum in the Northeast Pacific Ocean. Limnology and Oceanography 1985, 30(6):1351-1354.
25. Collier R., Edmond J. Trace element geochemistry of marine biogenic particulate matter. Progress in Oceanography 1984, 13:113-199.
26. Crusius J., Calvert S., Pedersen T., Sage D. Rhenium and molybdenum enrichments in sediments as indicators of oxic, suboxic and sulfidic conditions of deposition. Earth and Planetery Science Letters 1996, 145:65-78.
27. 2 concentration. Nature 1999, 402(6758):165-167.
28. Cullen J.T., Field M.P., Sherrell R.M. The determination of trace elements in filtered suspended marine particulate material by sector field HR-ICP-MS. Journal of Analytical Atomic Spectrometry 2001, 16:1307-1312.
29. The Black Sea-Geology, chemistry, and biology. Memoirs of the American Association of Petroleum Geologists 1974, vol. 20:633. American Association of Petroleum Geologists, Tulsa, Oklahoma, USA. E.T. Degens, D.A. Ross (Eds.).
30. Donat J.R., Bruland K.W. Chapter 11: trace elements in the oceans. Trace Elements in Natural Waters 1994, 247-280. CRC press, INC. S.A. Salbu (Ed.).
31. Dymond J., Suess E., Lyle M. Barium in deep-sea sediment: a geochemical proxy for paleoproductivity. Paleoceanography 1992, 7(2):163-181.
32. Emerson S., Huested S. Ocean anoxia and the concentrations of molybdenum and vanadium in seawater. Marine Chemistry 1991, 34:177-196.
33. Emerson S., Jacobs L., Tebo B. The behavior of trace metals in marine anoxic waters: solubilities at the oxygen-hydrogen sulfide interface. Trace Metals in Sea Water 1983, 579-608. Plenum Press, New York. C.S. Wong, E. Boyle, K.W. Bruland, J.D. Burton, E.D. Goldberg (Eds.).
34. Falkner K.K., Klinkhammer G.P., Bowers T.S., Todd J.F., Lewis B.L., Landing W.M., Edmond J.M. The behavior of barium in anoxic marine waters. Geochimica et Cosmochimica Acta 1993, 57:537-554.
35. Falkner K.K., Klinkhammer G.P., Ungerer A., Christie D. Inductively coupled plasma mass spectrometry in geochemistry. Annual Review of Earth and Planetary Sciences 1995, 23:409-449.
36. Fraustu da Silva J.J.R., Williams R.J.P. The Biological Chemistry of the Elements 1991, Clarendon Press, Oxford.
37. Fuchsman C.A., Murray J.W., Konovalov S.K. Concentration and natural stable isotope profiles of nitrogen species in the Black Sea. Marine Chemistry 2008, 111:90-105.
38. Gobeil C., Macdonald R.W., Sundby B. Diagenetic separation of cadmium and manganese in suboxic continental margin sediments. Geochimica et Cosmochimica Acta 1997, 61:4647-4654.
39. Guieu C., Martin J.M. Level and fate of metals in the Danube delta plume. Estuarine, Coastal and Shelf Science 2002, 54(3):501-512.
40. Haraldsson C., Westerlund S. Trace metals in the water columns of the Black Sea and Framvaren Fjord. Marine Chemistry 1988, 23:417-424.
41. Haraldsson C., Westerlund S. Total and suspended cadmium, cobalt, copper, iron, lead, manganese, nickel and zinc in the water column of the Black Sea. NATO ASI Series 1991, vol. 351:161-172. E. Izdar, J.W. Murray (Eds.).
42. Helz G.R., Miller C.V., Charnock J.M., Mosselmans J.F.W., Pattrick R.A.D., Garner C.G., Vaughan D.J. Mechanism of molybdenum removal from the sea and its concentration in black shales: EXFAS evidence. Geochimica et Cosmochimica Acta 1996, 60:3631-3642.
43. Ho T.-Y., Quigg A., Finkel Z.V., Milligan A.J., Wyman K., Falkowski P.G., Morel F.M.M. The elemental composition of some marine phytoplankton. Journal of Phycology 2003, 39:1145-1159.
44. Ho T.Y., Wen L.S., You C.F., Lee D.C. The trace-metal composition of size-fractionated plankton in the South China Sea: biotic versus abiotic sources. Limnology and Oceanography 2007, 52(5):1776-1788.
45. Jacobs L., Emerson S. Trace metal solubility in an anoxic fjord. Earth and Planetary Sciences 1982, 60:237-252.
46. 2S interface in a permanently anoxic basin: Framvaren Fjord, Norway. Geochimica et Cosmochimica Acta 1985, 49:1433-1444.
47. Jacobs L., Emerson S., Huested S.S. Trace metal geochemistry in the Cariaco Trench. Deep-Sea Research 1987, 34:965-981.
48. Klinkhammer G., Bender M. The distribution of manganese in the Pacific Ocean. Earth and Planetary Science Letters 1980, 46:361-384.
49. Konovalov S.K., Murray J.W. Variations in the chemistry of the Black Sea on a time scale of decades (1960-1995). Journal of Marine Systems 2001, 31:217-243.
50. Konovalov S., Luther G.W., Friederich G.E., Nuzzio D.B., Tebo B.M., Murray J.W., Oguz T., Glazer B., Trouwborst R.E., Clement R.E., Murray K.J., Romanov A.S. Lateral injection of oxygen with the Bosporus plume-fingers of oxidizing potential in the Black Sea. Limnology and Oceanography 2003, 48(6):2369-2376.
51. Konovalov S., Luther G.W., Yucel M. Porewater redox species and processes in the Black Sea sediments. Chemical Geology 2007, 245:254-274.
52. Kramer D., Cullen J.T., Christian J.R., Johnson W.K., Pedersen T.F. Silver in the subarctic northeast Pacific Ocean: explaining the basin scale distribution of silver. Marine Chemistry 2011, 123(1-4):133-142.
53. Kryc K.A., Murray R.W., Murray D.W. Al-to-oxide and Ti-to-organic linkages in biogenic sediment: relationships to paleoexport production and bulk Al/Ti. Earth and Planetary Research Letters 2003, 211:125-141.
54. Kuss J., Kremling K. Particulate trace element fluxes in the deep northeast Atlantic Ocean. Deep-Sea Research Part I 1999, 46(1):149-169.
55. Langmuir D. Uranium solution-mineral equilibria at low temperatures with applications to sedimentary ore deposits. Geochimica et Cosmochimica Acta 1978, 42:547-569.
56. Lewis B.L., Landing W.M. The biogeochemistry of manganese and iron in the Black Sea. Deep-Sea Research 1991, 38(1-2):773-804.
57. Lewis B.L., Landing W.M. The investigation of dissolved and suspended particulate trace metal fractionation in the Black Sea. Marine Chemistry 1992, 40(1-2):105-141.
58. Literathy P., Laszlo F. Micropollutants in the Danube River basin. Water Science and Technology 1999, 40(10):17-26.
59. Mandernack K.W., Post J., Tebo B.M. Manganese mineral formation by bacterial spores of a marine Bacillus, strain SG-1: evidence for the direct oxidation of Mn(II) to Mn(IV). Geochimica et Cosmochimica Acta 1995, 59:4393-4408.
60. Martin J., Knauer G. The elemental composition of plankton. Geochimica et Cosmochimica Acta 1973, 37:1639-1653.
61. Martin J.H., Bruland K.W., Broenkow W.W. Cadmium transport in the California current. Marine Pollutant Transfer 1976, 159-184. Lexington Books, Heath, Boston. H.L. Windom, R.A. Duce (Eds.).
62. Martin J.H., Knauer G.A., Gordon R.M. Silver distributions and fluxes in north-east Pacific waters. Nature 1983, 305:306-309.
63. McKay J.L., Pedersen T.F. The accumulation of silver in marine sediments: a link to biogenic Ba and marine productivity. Global Biogeochemical Cycles 2008, 22:GB4010. 17 PP.
64. 2S in the Chesapeake Bay. Estuarine Coastal and Shelf Science 1991, 33:521-527.
65. Morford J., Emerson S. The geochemistry of redox sensitive trace metals in sediments. Geochimica et Cosmochimica Acta 1999, 63:1735-1750.
66. Muller F.L.L., Gulin S.B., Kalvøy A. Chemical speciation of copper and zinc in surface waters of the western Black Sea. Marine Chemistry 2001, 76(4):233-251.
67. Muramoto J., Honjo S., Fry B., Hay B., Howarth R. Sulfur, iron and organic carbon fluxes in the Black Sea: sulfur isotopic evidence for origin of sulfur fluxes. Deep-Sea Research 1991, 38(2A):1151-1187.
68. Murphy J., Riley J.P. A modified single solution method for the determination of phosphate in natural waters. Analytical Chimica Acta. 1962, 27:31-36.
69. Murray J. The surface chemistry of hydrous manganese dioxide. Journal of Colloidal Interface Science 1974, 46:357-371.
70. Murray J.W. The interaction of metal ions at the manganese dioxide-solution interface. Geochimica et Cosmochimica Acta 1975, 39(4):505-519.
71. Murray J.W. The interaction of cobalt with hydrous manganese dioxide. Geochimica et Cosmochimica Acta 1975, 39(5):635-647.
72. Murray J.W. Iron oxides. Mineralogical Society of America 1979, vol. 6:47-98. R.G. Burns (Ed.).
73. Murray J.W., Brewer P.G. The mechanisms of removal of iron, manganese and other trace metals from seawater. Marine Manganese Deposits 1977, 291-325. Elsevier, Holland. G.P. Glasby (Ed.).
74. Murray J.W., Dillard J.G. The oxidation of cobalt(II) adsorbed on manganese dioxide. Geochimica et Cosmochimica Acta 1979, 43:781-787.
75. Murray R.W., Leinen M. Chemical transport to the seafloor of the equatorial Pacific Ocean across a latitudinal transect at 135°W: tracking sedimentary major, minor, trace, and rare earth element fluxes at the Equator and the Intertropical Convergence Zone. Geochimica et Cosmochimica Acta 1993, 57:4141-4163.
76. Murray J.W., Yakushev E. The suboxic zone in the Black Sea. Past and Present Water Column Anoxia 2006, NATO ARW. L. Neretin (Ed.).
77. Murray J.W., Spell B., Paul B. The contrasting geochemistry of manganese and chromium in the eastern tropical Pacific Ocean. Trace Metals in Seawater 1983, 643-669. Plenum Press. C.S. Wong (Ed.).
78. Murray J.W., Dillard J.G., Giovanoli R., Moers H., Stumm W. Oxidation of Mn(II): initial mineralogy, oxidation state and ageing. Geochimica et Cosmochimica Acta 1985, 49:463-470.
79. Murray J.W., Jannasch H.W., Hojo S., Anderson R.F., Reeburgh W.S., Top Z., Friederich G.E., Codispoti L.A., Izdar E. Unexpected changes in the oxic/anoxic interface in the Black Sea. Nature 1989, 338(6214):411-413.
80. Murray J.W., Codispoti L.A., Friederich G.E. Oxidation-reduction environments: the suboxic zone in the Black Sea. Aquatic Chemistry 1995, 157-176. American Chemical Society. C.P. Huang, C.O. Melia, J.J. Morgan (Eds.).
81. Nameroff, T.J., 1996. The geochemistry of redox-sensitive metals in sediments of the oxygen minimum off Mexico. Ph.D. Thesis, University of Washington, Seattle, WA.
82. Nameroff T.J., Balistrieri L.S., Murray J.W. Suboxic trace metal geochemistry in the eastern tropical north Pacific. Geochimica et Cosmochimica Acta 2002, 66:1139-1158.
83. Nameroff T.J., Calvert S.E., Murray J.W. Glacial-interglacial variability in the eastern tropical North Pacific oxygen minimum zone recorded by redox-sensitive trace metals. Paleoceanography 2004, 19:A1010.
84. Oǧuz T. Role of physical processes controlling oxycline and suboxic layer structures in the Black Sea. Ambio 2002, vol. 21 (2).
85. Oǧuz T., Murray J.W., Callahan A. Modeling redox cycling across the suboxic-anoxic interface zone in the Black Sea. Deep-Sea Research, Part I 2001, 48:761-787.
86. Oǧuz T., Ducklow H.W., Purcell J.E., Malanotte-Rizzoli P. Modeling the response of top-down control exerted by gelatinous carnivores on the Black Sea pelagic food web. Journal of Geophysical Research 2001, 106:4543-4564.
87. Okus E., Asian-Yilma A., Yuksek A., Tas S., Tufekci V. Nutrient distribution in the Bosphorus and surrounding areas. Water Science and Technology 2002, 46:59-66.
88. Orians K.J., Boyle E.A., Bruland K.W. Dissolved titanium in the open ocean. Nature 1990, 348:322-325.
89. Paytan A., Kastner M. Benthic Ba fluxes in the central equatorial Pacific, implications for the oceanic Ba cycle. Earth and Planetary Science Letters 1996, 142:439-450.
90. Paytan A., Kastner M., Chavez F. Glacial to interglacial fluctuations in productivity in the equatorial Pacific as indicated by marine barite. Science 1996, 274:1355-1357.
91. Piper D.Z., Calvert S.E. A marine biogeochemical perspective on black shale deposition. Earth-Science Reviews 2009, 95(1-2):63-96.
92. Piper, D.Z., Calvert, S.E., in press, Holocene and late glacial Paleoceanography and Paleolimnology of the Black Sea: Changing sediment provenance and basin hydrography over the past 20,000 years. Geochimica et Cosmochimica Acta.
93. Raven J.A. The iron and molybdenum use efficiencies of plant growth with different energy, carbon and nitrogen sources. New Phytologis 1988, 109:279-287.
94. Ricking M., Tertyze K. Trace metals and organic compounds in sediment samples from the River Danube in Russe and Lake Srebarna (Bulgaria). Environmental Geology 1999, 37(1-2):40-46.
95. Rue E.L., Smith G.J., Cutter G.A., Bruland K.W. The response of trace element redox couples to suboxic conditions in the water column. Deep-Sea Research 1997, 44:113-134.
96. Saager P.M., De Baar H.J.W., Howland R.J. Cd, Zn, Ni, and Cu in the Indian Ocean. Deep-Sea Research 1992, 39:9-35.
97. Sañudo-Wilhelmy S.A., Flegal A.R. Anthropogenic silver in the Southern California Bight: a new tracer of sewage in coastal waters. Environmental Science and Technology 1992, 26:2147-2151.
98. Saydam C., Tugrul S., Basturk O., Oguz T. Identification of the oxic/anoxic interface surfaces in the Black Sea. Deep-Sea Research I 1993, 40(7):1405-1412.
99. Shaffer G. Phosphate pumps and shuttles in the Black Sea. Nature 1986, 321:515-517.
100. Skrabal S.A. Dissolved titanium distributions in the Mid-Atlantic Bight. Marine Chemistry 2006, 102:218-229.
101. Skrabal S.A., Terry C.M. Distributions of dissolved titanium in porewaters of estuarine and coastal marine sediments. Marine Chemistry 2002, 77:109-122.
102. Sorokin Y.I. The Black Sea. Ecosystems of the World 26: Estuaries and Enclosed Seas 1983, 253-292. Elsevier, Amsterdam. B.H. Ketchum (Ed.).
103. Spencer D.W., Brewer P.G. Vertical advection, diffusion and redox potentials as controls on the distribution of manganese and other trace metals dissolved in waters of the Black Sea. Journal of Geophysical Research 1971, 76:5877-5892.
104. Spencer D.W., Brewer P.G., Sachs P.L., Smith C.L. The distribution of some chemical elements between dissolved and particulate phases in the ocean. AEC Rep. NYO-4150-2 1971, 41 pp.
105. Spencer D.W., Brewer P.G., Sachs P.L. Aspects of the distribution and trace element composition of suspended matter in the Black Sea. Geochimica et Cosmochimica Acta 1972, 36(1):71-86.
106. Stiefel E.I. Molybdenum bolsters the bioinorganic brigade. Science 1996, 272(5268):1599-1600.
107. Stumm W., Morgan J.J. Aquatic Chemistry: An Introduction Emphasizing Chemical Equilibria in Natural Waters 1981, 780. John Wiley and Sons, New York, NY.
108. Stumm W., Morgan J.J. Aquatic Chemistry 1996, JohnWilley and Sons, New York. 3rd edition.
109. Suess E. Mineral phases formed in anoxic sediments by microbial decomposition of organic matter. Geochimica et Cosmochimica Acta 1979, 43:339-352.
110. Tankere S.P.C., Muller F.L.L., Burton J.D., Statham P.J., Guieu C., Martin J.M. Trace metal distributions in shelf waters of the northwestern Black Sea. Continental Shelf Research 2001, 21:1501-1532.
111. Taylor S.R. Abundance of chemical elements in the continental crust: a new table. Geochimica et Cosmochimica Acta 1964, 28:1273-1285.
112. Taylor S.R., McLennan S.M. The Continental Crust: It's Composition and Evolution 1985, 312. Blackwell, Oxford.
113. Taylor S.R., McLennan S.M. The geochemical evolution of the continental crust. Reviews in Geophysics 1995, 33:241-265.
114. Tebo B.M. Manganese (II) oxidation in the suboxic zone of the Black Sea. Deep-Sea Research 1991, 38(2):883-905.
115. Tebo B.M., Bargar J.R., Clement B.G., Dick G.J., Murray K.J., Parker D., Verity R., Webb S.M. Biogenic manganese oxides: properties and mechanisms of formation. Annual Reviews of Earth and Planetary Science 2004, 32:287-328.
116. Trouwborst R.E., Clement B.G., Tebo B.M., Glazer B.T., Luther G.W. Soluble (Mn(III) in suboxic zones. Science 2006, 313:1955-1957.
117. Tuǧrul S., Bastürk O., Saydam C., Yilmaz A. Changes in the hydrochemistry of the Black Sea inferred from density profiles. Nature 1992, 359:137-139.
118. Twining B.S., Baines S.B., Fisher N.S. Element stoichiometries of individual plankton cells collected during the Southern Ocean Iron Experiment (SOFeX). Limnology and Oceanography 2004, 49:2115-2128.
119. Twining B.S., Nuňez-Milland D., Vogt S., Johnson R.S., Sedwickd P.N. Variations in Synechococcus cell quotas of phosphorus, sulfur, manganese, iron, nickel, and zinc within mesoscale eddies in the Sargasso Sea. Limnology and Oceanography 2010, 55(2):492-506.
120. Twining B.S., Baines S.B., Bozard J.B., Vogt S., Walker E.A., Nelson D.M. Metal quotas of plankton in the equatorial Pacific Ocean. Deep-Sea Research II 2011, 58:325-341.
121. Vinogradov M.Y., Nalbandov Y.R. Effect of changes in water density on the profiles of physicochemical and biological characteristics in the pelagic ecosystem of the Black Sea. Oceanology 1990, 30:567-573.
122. Wanty R.B., Goldhaber M.B. Thermodynamics and kinetics of reactions involving vanadium in natural systems: accumulation of vanadium in sedimentary rocks. Geochimica et Cosmochimica Acta 1992, 56:1471-1484.
123. Wanty R.B., Goldhaber M.B., Northrop H.R. Geochemistry of vanadium in an epigenetic sandstone-hosted vanadium-uranium deposit, Henry basin, Utah. Economic Geology 1990, 85:270-284.
124. Wedepohl K.H. Origin and Distribution of the Elements 1968, Pergamon Press, London.
125. Wedepohl K.H. The composition of the continental crust. Geochimica et Cosmochimica Acta 1995, 59(7):1217-1232.
126. Wehrli B., Stumm W. Vanadyl in natural waters: adsorption and hydrolysis promote oxygenation. Geochimica et Cosmochimica Acta 1989, 53:69-77.
127. Wei C.L., Murray J.W. The behavior of scavenging isotopes in marine anoxic environments: lead -210 and polonium -210 in the water column of the Black Sea. Geochemica et Cosmochimica Acta 1994, 58:1795-1812.
128. Yarincik K., Murray R., Peterson L. Climatically sensitive eolian and hemipelagic deposition in the Cariaco Basin, Venezuela, over the past 580,000years: results from Al/Ti and K/Al. Paleoceanography 2000, 15:210-228.
129. Yemenicioǧlu S., Erdogan S., Tugrul S. Distribution of dissolved forms of iron and manganese in the Black Sea. Deep-Sea Research Part II: Topical Studies in Oceanography 2006, 53(17-19):1842-1855.
130. Yiǧiterhan, O., 2005. Trace metal composition of particulate matter in the water column and sediments of the Black Sea and regional rivers. PhD Thesis, Middle East Technical University, pp. 324.
131. Yiǧiterhan O., Murray J.W. Trace metal composition of particulate matter of the Danube River and Turkish rivers draining into the Black Sea. Marine Chemistry 2008, 111:63-76.
132. Yiǧiterhan, O., Murray, J.W., Tuǧrul, S., Yemenicioǧlu, S., (in preparation). Change of particles composition in the Black Sea from river input to ultimate burial. (In: Marine Chemistry (format)).
133. Zheng Y., Anderson R.F., van Geen A., Kuwabara J. Authigenic molybdenum formation in marine sediments: a link to porewater sulfide in the Santa Barbara Basin. Geochimica et Cosmochimica Acta. 2000, 64:4165-4178.