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Alkenylmetalations of functionalized alkynes have been reported. For intramolecular alkenyllithiation of silylalkynes, see
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3 as a catalyst is effective for the addition of PhLi to PhCCMe. However, the Fe/Cu system is not applicable to dialkylacetylenes (cf. entry 4 of Table 1).
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33947589022
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See also ref. 2a Synthesis of benzosiloles through an addition-cyclization sequence is accomplished by rhodium-catalyzed reaction of o-(trimethylsilyl)phenylboronic acids with alkynes.
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2)-Li with Me as a leaving group, where pentaorganosilicates are considered to be intermediates, see
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