Highly efficient separation of actinides from lanthanides by a phenanthroline-derived bis-triazine ligand

Journal of the American Chemical Society

Volumn 133, Issue 33, 2011, Pages 13093-13102

  Lewis, Frank W ^a   Harwood, Laurence M ^a   Hudson, Michael J ^a   Drew, Michael G B ^a   Desreux, Jean F ^b   Vidick, Geoffrey ^b   Bouslimani, Nouri ^b   Modolo, Giuseppe ^c   Wilden, Andreas ^c   Sypula, Michal ^c   Vu, Trong Hung ^d   Simonin, Jean Pierre ^d  

^a UNIVERSITY OF READING   (United Kingdom)

^b UNIVERSITY OF LIÈGE   (Belgium)

^c FORSCHUNGSZENTRUM JÜLICH   (Germany)

^d CNRS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

BIPYRIDINE UNITS; BIPYRIDINES; FAST EXTRACTION; FASTER RATES; FORCE FIELD CALCULATIONS; HIGH EFFICIENCY; HIGH SELECTIVITY; KINETICS MEASUREMENTS; LIGAND DESIGN; METAL ION EXTRACTION; NITRIC ACID SOLUTIONS; PHENANTHROLINES; ROTATING MEMBRANE; SURFACE ACTIVITIES;

ACTINIDES; AMERICIUM; CURIUM; EUROPIUM; KINETICS; LIGANDS; METAL IONS; MINERALOGY; NITRIC ACID; PHASE INTERFACES; SOLVENT EXTRACTION; SOLVENTS; X RAY CRYSTALLOGRAPHY; YTTERBIUM;

CHELATION;

ACTINIDE; EUROPIUM; LANTHANIDE; LIGAND; NITRIC ACID; PHENANTHROLINE; TRACER; TRIAZINE DERIVATIVE; YTTERBIUM;

ARTICLE; CELL MEMBRANE; CHEMICAL ANALYSIS; CHEMICAL MODIFICATION; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; MOLECULAR MODEL; NUCLEAR OVERHAUSER EFFECT; PHASE SEPARATION; SEPARATION TECHNIQUE; SOLVENT EXTRACTION; STRUCTURE ANALYSIS; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 80051766076     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja203378m     Document Type: Article

References (88)

1. OECD/NEA. Nuclear Fuel Cycle Transition Scenario Studies-Status Report, NEA No. 6194; OECD Publications: Paris, 2009.
2. Baumgärtner, F. Kerntechnik 1978, 20, 74
3. Baumgärtner, F.; Ertel, D. J. Radiat. Chem. 1980, 58, 11
4. McKibben, J. M. Radiochim. Acta 1984, 36, 3
5. Sood, D. D.; Patil, S. K. J. Radioanal. Nucl. Chem. 1996, 203, 547
6. Madic, C. Actual. Chim. 1999, 16
7. Musikas, C.; Schultz, W.; Liljenzin, J.-O. Solvent Extraction Principles and Practice, 2 nd ed.; Rydberg, J.; Cox, M.; Musikas, C.; Choppin, G., Eds.; Marcel Dekker, Inc.: New York, 2004; pp 507-557.
8. Magill, J.; Berthou, V.; Haas, D.; Galy, J.; Schenkel, R.; Wiese, H.-W.; Heusener, G.; Tommasi, J.; Youinou, G. Nucl. Energy 2003, 42, 263
9. Mathur, J. N.; Murali, M. S.; Nash, K. L. Solvent Extr. Ion Exch. 2001, 19, 357
10. Cotton, S. Comprehensive Coordination Chemistry II, Vol. 3; McCleverty, J. A.; Meyer, T. J., Eds.; Elsevier: Oxford, 2004; pp 93-188.
11. Burns, C. J.; Neu, M. P.; Boukhalfa, H.; Gutowski, K. E.; Bridges, N. J.; Rogers, R. D. Comprehensive Coordination Chemistry II, Vol. 3; McCleverty, J. A.; Meyer, T. J., Eds.; Elsevier: Oxford, 2004; pp 189-332.
12. Katz, J. J.; Morss, L. R.; Edelstein, N. M.; Fuger, J. The Chemistry of the Actinide and Transactinide Elements, Vol. 1; Katz, J. J.; Morss, L. R.; Edelstein, N. M.; Fuger, J., Eds.; Springer: Dordrecht, 2006; pp 1-17.
13. Choppin, G. R. J. Alloys Compd. 1995, 223, 174
14. Alexander, V. Chem. Rev. 1995, 95, 273
15. Choppin, G. R. J. Alloys Compd. 2002, 344, 55
16. Gaunt, A. J.; Neu, M. P. C. R. Chim. 2010, 13, 821
17. Dam, H. H.; Reinhoudt, D. N.; Verboom, W. Chem. Soc. Rev. 2007, 36, 367
18. Ekberg, C.; Fermvik, A.; Retegan, T.; Skarnemark, G.; Foreman, M. R. S.; Hudson, M. J.; Englund, S.; Nilsson, M. Radiochim. Acta 2008, 96, 225
19. Kolarik, Z. Chem. Rev. 2008, 108, 4208
20. Drew, M. G. B.; Guillaneux, D.; Hudson, M. J.; Iveson, P. B.; Russell, M. L.; Madic, C. Inorg. Chem. Commun. 2001, 4, 12
21. Iveson, P. B.; Riviére, C.; Guillaneux, D.; Nierlich, M.; Thuéry, P.; Ephritikhine, M.; Madic, C. Chem. Commun. 2001, 1512
22. Boucher, C.; Drew, M. G. B.; Giddings, P.; Harwood, L. M.; Hudson, M. J.; Iveson, P. B.; Madic, C. Inorg. Chem. Commun. 2002, 5, 596
23. Ionova, G.; Rabbe, C.; Guillaumont, R.; Ionov, S.; Madic, C.; Krupa, J.-C.; Guillaneux, D. New J. Chem. 2002, 26, 234
24. Berthet, J.- C.; Miquel, Y.; Iveson, P. B.; Nierlich, M.; Thuéry, P.; Madic, C.; Ephritikhine, M. J. Chem. Soc., Dalton Trans. 2002, 3265
25. Colette, S.; Amekraz, B.; Madic, C.; Berthon, L.; Cote, G.; Moulin, C. Inorg. Chem. 2002, 41, 7031
26. Colette, S.; Amekraz, B.; Madic, C.; Berthon, L.; Cote, G.; Moulin, C. Inorg. Chem. 2003, 42, 2215
27. Colette, S.; Amekraz, B.; Madic, C.; Berthon, L.; Cote, G.; Moulin, C. Inorg. Chem. 2004, 43, 6745
28. Denecke, M. A.; Rossberg, A.; Panak, P. J.; Weigl, M.; Schimmelpfennig, B.; Geist, A. Inorg. Chem. 2005, 44, 8418
29. Drew, M. G. B.; Foreman, M. R. J., St.; Geist, A.; Hudson, M. J.; Marken, F.; Norman, V.; Weigl, M. Polyhedron 2006, 25, 888
30. Steppert, M.; Walther, C.; Geist, A.; Fanghänel, T. New J. Chem. 2009, 33, 2437
31. Banik, N. L.; Schimmelpfennig, B.; Marquardt, C. M.; Brendebach, B.; Geist, A.; Denecke, M. A. Dalton Trans. 2010, 39, 5117
32. Benay, G.; Schurhammer, R.; Wipff, G. Phys. Chem. Chem. Phys. 2010, 12, 11089
33. Drew, M. G. B.; Foreman, M. R. S. J.; Hill, C.; Hudson, M. J.; Madic, C. Inorg. Chem. Commun. 2005, 8, 239
34. Nilsson, M.; Ekberg, C.; Foreman, M.; Hudson, M.; Liljenzin, J.-O.; Modolo, G.; Skarnemark, G. Solvent Extr. Ion Exch. 2006, 24, 823
35. Trumm, S.; Lieser, G.; Foreman, M. R. S. J.; Panak, P. J.; Geist, A.; Fanghänel, T. Dalton Trans. 2010, 39, 923
36. Hubscher-Bruder, V.; Haddaoui, J.; Bouhroum, S.; Arnaud-Neu, F. Inorg. Chem. 2010, 49, 1363
37. Ekberg, C.; Aneheim, E.; Fermvik, A.; Foreman, M.; Löfström- Engdahl, E.; Retegan, T.; Spendlikova, I. J. Chem. Eng. Data 2010, 55, 5133
38. Berthet, J.-C.; Maynadié, J.; Thuéry, P.; Ephritikhine, M. Dalton Trans. 2010, 39, 6801
39. Benay, G.; Schurhammer, R.; Wipff, G. Phys. Chem. Chem. Phys. 2011, 13, 2922
40. Geist, A.; Hill, C.; Modolo, G.; Foreman, M. R. St., J.; Weigl, M.; Gompper, K.; Hudson, M. J. Solvent Extr. Ion Exch. 2006, 24, 463
41. Magnusson, D.; Christiansen, B.; Foreman, M. R. S.; Geist, A.; Glatz, J.-P.; Malmbeck, R.; Modolo, G.; Serrano-Purroy, D.; Sorel, C. Solvent Extr. Ion Exch. 2009, 27, 97
42. For a related ligand derived from pyridine, see: Hudson, M. J.; Boucher, C. E.; Braekers, D.; Desreux, J. F.; Drew, M. G. B.; Foreman, M. R. St., J.; Harwood, L. M.; Hill, C.; Madic, C.; Marken, F.; Youngs, T. G. A. New J. Chem. 2006, 30, 1171
43. For a related ligand derived from 2,2′:6′,2″- terpyridine, see: Lewis, F. W.; Harwood, L. M.; Hudson, M. J.; Drew, M. G. B.; Modolo, G.; Sypula, M.; Desreux, J. F.; Bouslimani, N.; Vidick, G. Dalton Trans. 2010, 39, 5172
44. For an example of a radiolytically unstable BTBP, see: Fermvik, A.; Berthon, L.; Ekberg, C.; Englund, S.; Retegan, T.; Zorz, N. Dalton Trans. 2009, 6421
45. Berthet, J.-C.; Thuéry, P.; Foreman, M. R. S.; Ephritikhine, M. Radiochim. Acta 2008, 96, 189
46. Berthet, J.-C.; Thuéry, P.; Dognon, J.-P.; Guillaneux, D.; Ephritikhine, M. Inorg. Chem. 2008, 47, 6850
47. Berthet, J.-C.; Siffredi, G.; Thuéry, P.; Ephritikhine, M. Dalton Trans. 2009, 3478
48. Sammes, P. G.; Yahioglu, G. Chem. Soc. Rev. 1994, 23, 327
49. Luman, C. R.; Castellano, F. N. Comprehensive Coordination Chemistry II, Vol. 1; McCleverty, J. A.; Meyer, T. J., Eds.; Elsevier: Oxford, 2004; pp 25-39.
50. Accorsi, G.; Listorti, A.; Yoosaf, K.; Armaroli, N. Chem. Soc. Rev. 2009, 38, 1690
51. Bencini, A.; Lippolis, V. Coord. Chem. Rev. 2010, 254, 2096
52. Zong, R.; Thummel, R. P. J. Am. Chem. Soc. 2004, 126, 10800
53. Cockrell, G. M.; Zhang, G.; VanDerveer, D. G.; Thummel, R. P.; Hancock, R. D. J. Am. Chem. Soc. 2008, 130, 1420
54. See for example: Cumper, C. W. N.; Ginman, R. F. A.; Vogel, A. I. J. Chem. Soc. 1962, 1188
55. See for example: Donnay, G.; Donnay, J. D. H.; Harding, M. J. C. Acta Crystallogr. 1965, 19, 688
56. Chandler, C. J.; Deady, L. W.; Reiss, J. A. J. Heterocycl. Chem. 1981, 18, 599
57. Jones, P.; Villeneuve, G. B.; Fei, C.; DeMarte, J.; Haggarty, A. J.; Nwe, K. T.; Martin, D. A.; Lebuis, A.-M.; Finkelstein, J. M.; Gour-Salin, B. J.; Chan, T. H.; Leyland-Jones, B. R. J. Med. Chem. 1998, 41, 3062
58. Kikuchi, K.; Hibi, S.; Yoshimura, H.; Tokuhara, N.; Tai, K.; Hida, T.; Yamauchi, T.; Nagai, M. J. Med. Chem. 2000, 43, 409
59. Coffman, D. D.; Jenner, E. L.; Lipscomb, R. D. J. Am. Chem. Soc. 1958, 80, 2864
60. Bremner, D. H.; Mitchell, S. R.; Staines, H. Ultrason. Sonochem. 1996, 3, 47
61. Bremner, D. H.; Burgess, A. E.; Li, F.-B. Green Chem. 2001, 3, 126
62. Lewis, F. W; Harwood, L. M.; Hudson, M. J. WO2011077081 A1, 2011.
63. This type of reactivity has been reported with 1,2-dibromoethane; see: Ibarzo, J.; Ortuña, R. M. Tetrahedron 1994, 50, 9825
64. Foreman, M. R. S.; Hudson, M. J.; Drew, M. G. B.; Hill, C.; Madic, C. Dalton Trans. 2006, 1645
65. Ackerman, J. J. H.; Soto, G. E.; Spees, W. M.; Zhu, Z.; Evelhoch, J. L. Magn. Reson. Med. 1996, 36, 674
66. Grycova, L.; Dommisse, R.; Pieters, L.; Marek, R. Magn. Reson. Chem. 2009, 47, 977
67. Anet, F. A. L.; Haq, M. Z. J. Am. Chem. Soc. 1965, 87, 3147
68. Desreux, J. F. Inorg. Chem. 1980, 19, 1319
69. Spirlet, M. R.; Rebizant, J.; Desreux, J. F.; Loncin, M. F. Inorg. Chem. 1984, 23, 359
70. Desreux, J. F.; Loncin, M. F. Inorg. Chem. 1986, 25, 69
71. Bertini, I.; Luchinat, C.; Parigi, G. Solution NMR of Paramagnetic Molecules; Elsevier: Amsterdam, 2001; pp 62-67.
72. Ranganathan, R. S.; Raju, N.; Fan, H.; Zhang, X.; Tweedle, M. F.; Desreux, J. F.; Jacques, V. Inorg. Chem. 2002, 41, 6856
73. Keizers, P. H. J.; Desreux, J. F.; Overhand, M.; Ubbink, M. J. Am. Chem. Soc. 2007, 129, 9292
74. Clore, G. M.; Iwahara, J. Chem. Rev. 2009, 109, 4108
75. Inagaki, F.; Miyazawa, T. Prog. Nucl. Magn. Reson. Spectrosc. 1981, 14, 7
76. Cordier, P. Y.; Hill, C.; Baron, P.; Madic, C.; Hudson, M. J.; Liljenzin, J.-O. J. Alloys Compd. 1998, 271-273, 738
77. Hagström, I.; Spjuth, L.; Enarsson, Å.; Liljenzin, J.-O.; Skålberg, M.; Hudson, M. J.; Iveson, P. B.; Madic, C.; Cordier, P. Y.; Hill, C.; Francois, N. Solvent Extr. Ion Exch. 1999, 17, 221
78. Drew, M. G. B.; Iveson, P. B.; Hudson, M. J.; Liljenzin, J.-O.; Spjuth, L.; Cordier, P. Y.; Enarsson, Å.; Hill, C.; Madic, C. J. Chem. Soc., Dalton Trans. 2000, 821
79. Brinck, T.; Murray, J. S.; Politzer, P. J. Org. Chem. 1991, 56, 2934
80. Serrano-Purroy, D.; Baron, P.; Christiansen, B.; Malmbeck, R.; Sorel, C.; Glatz, J.-P. Radiochim. Acta 2005, 93, 351
81. Simonin, J.-P.; Weill, J. Solvent Extr. Ion Exch. 1998, 16, 1493
82. Simonin, J.-P.; Hendrawan, H. J. Phys. Chem. B 2000, 104, 7163
83. Simonin, J.-P.; Hendrawan, H.; Dardoize, F.; Clodic, G. Hydrometallurgy 2003, 69, 23
84. Nilsson, M.; Andersson, S.; Drouet, F.; Ekberg, C.; Foreman, M.; Hudson, M.; Liljenzin, J.- O.; Magnusson, D.; Skarnemark, G. Solvent Extr. Ion Exch. 2006, 24, 299
85. Nilsson, M.; Ekberg, C.; Foreman, M.; Hudson, M.; Liljenzin, J.-O.; Modolo, G.; Skarnemark, G. Solvent Extr. Ion Exch. 2006, 24, 823
86. Magnusson, D.; Christiansen, B.; Glatz, J.-P.; Malmbeck, R.; Modolo, G.; Serrano-Purroy, D.; Sorel, C. Solvent Extr. Ion Exch. 2009, 27, 26
87. Lecomte du Noüy, P. J. Gen. Physiol. 1925, 7, 625
88. Yildirim Erbil, H. Surface Chemistry of Solid and Liquid Interfaces; Blackwell Publishing Ltd: Oxford, 2006.