Synthesis and characterization of η3-Allyl palladium(II) complexes with tetraalkyldiphosphine disulfides, R2P(S)P(S)R 2 (R=Me, Et, nPr, nBu, Ph)

Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

Volumn 41, Issue 7, 2011, Pages 834-838

  Subasi, Elif ^a   Senturk, Ozan Sanli ^b  

^a DOKUZ EYLUL UNIVERSITY   (Turkey)

^b ISTANBUL TECHNICAL UNIVERSITY   (Turkey)

Author keywords

allyl complexes; diphosphinedisulfide; palladium complexes; synthesis

Indexed keywords

EID: 80051739537     PISSN: 15533174     EISSN: 15533182     Source Type: Journal    
DOI: 10.1080/15533174.2011.591311     Document Type: Article

References (30)

1. Birri, A.; Harvey, B.; Hogarth, G.; Subasi, E.; Ugur, F. Allyl palladium dithiocarbamates and related dithiolate complexes as precursors to palla dium sulfides. J. Organomet. Chem. 2007, 692, 2448-2455. (Pubitemid 46635455)
2. 3-allyl)Pd(S2X)] (X=CNMe2, CNEt2, COEt, PPh2). J. Coord Chem. 2005, 58, 623-628. (Pubitemid 41685803)
3. Churchill, M.R. The molecular structure of acetylacetonato(cyclo-octa-2, 4-dienyl)palladium. Chem. Commun. 1965, 625-630.
4. Musco, A.; Rampone, R.; Ganis, P.; Pedone, C. Molecular asymmetry of r-allylic compounds of transition metals: VI. ï-Ketoamine derivatives of symmetrically and dissymmetrically substituted j-allypalladium com plexes. J. Organomet. Chem. 1972, 34, C48.
5. Benedetti, E.; Maglio, G.; Palumbo, R.; Pedone, C. r-Allylpalladium(II) complexes of amino acids. J. Organomet. Chem. 1973, 60, 189-195.
6. 3-allyl palla-dium(II) complexes with Ph2P(S)CHP(S)Ph2 and OC(CF3)CHCO(C4H3S) co-ligands. Transition Met. Chem. 2005, 30, 372-375. (Pubitemid 41042314)
7. (a) Baker, K.; Fowles, G.W.A. Sulphur complexes of quadrivalent titanium. J. Less Common. Met. 1965, 8, 47.
8. (b) Cowley, A.H. The chemistry of the phosphorus-phosphorus bond. Chem. Rev. 1965, 6, 65, 617-634.
9. Almond, M.J.; Sarikahya, F.; Senturk, O.S. Photochemical synthe sis of metal carbonyl complexes of teraalkyl diphosphine disülfide [M(CO)4(R2P(S)P(S)R2] (M=Mo, W; R=Me, Et, n-Pr, n-Bu). Polyhedron 1997, 16, 1101-1103.
10. Sarikahya, F.; Senturk, O.S.; Topaloglu, I. Preparation of complexes formed in the reaction between dicobaltoctacarbonyl and tetraalkyldiphosphine disulfides. Syn. React. Inorg. Met. 2000, 30, 1697-1702.
11. 10(R2P(S)P(S)R2) (M=Mo, W; R=Me, Et, n-Pr, n-Bu). Syn. React. Inorg. Met. 2001, 31, 1843-1851. (Pubitemid 33588656)
12. Senturk, O.S.; Shekhel, H.A.; Strenberg, B.T.; Udachin, K.A.; Sert, S.; Ozdemir, U.; Sarikahya, F. Photochemical reactions of Re(CO)5Br with tetraalkyldiphosphine disulfides (R=Me, Et, n-Pr, n-Bu, Ph) and the crystal structure of (ReBr(C0)3(Et2P(S)P(S)Et2)). Polyhedron 2003, 22, 1659-1664.
13. 2 P(S)P(S)R2 (R=Et, n-Pr, n-Bu, Ph). J. Coord. Chem. 2008, 61, 776-780.
14. McQuillan, G.P; Oxton, I. A. Diphosphane derivatives. Part 3. The donor characteristics of tetramethyl-1,2-dithioxodi-a; 5-phosphane (tetram-ethyldiphosphine disulphide) and the vibrational spectra and structures of some of its complexes. J. Chem. Soc. Dalton. Trans. 1979, 895-900.
15. Jones, G.C.H.; Jones, P.G.; Maddock, A.G.; Mays, M.J.; Vergano, R.A.; Williams, A. F. Structure and bonding in gold(I) compounds. Part 3. Möss-bauer spectra of three-co-ordinate complexes. J. Chem. Soc. Dalton Trans. 1977, 1443-1440.
16. Wagner, K.P.; Hess, R.W; Treichel, P.M.; Calabrase, J.C. Synthesis and structure of a series of thiophosphinato-bridged platinum complexes. Crys tal and molecular structure of bis-μ-(diethylphosphido sulfide)bis(triphenyl phosphite)diplatinum. Inorg. Chem. 1975,14, 1121-1126.
17. Lobana, T.S.; Sharma, K. Ligating properties of tertiary phosphine arsine sulfides or selenides. 7. Synthesis and characterization of palladium(II) complexes with some monotertiary and ditertiary phosphine sulfides or selenides. Transit. Met. Chem. 1982, 7, 6, 333-335. (Pubitemid 13578028)
18. (a) Maitlis, P.M.; Espinet, P.; Russel, M.J.H.; In Wilkinson, G.; Stone, F.G.A.; Abel, E.W Comprehensive Organometallic Chemistry; Pergamon Press: Oxford, 1982, 6, 385.
19. 3-2-MeC3H4, pm(Me)2S = Pyridine-4,6-dimethyl-2-thionate. J. Organomet. Chem. 1999,579,321-327. (Pubitemid 129612408)
20. (c) Ruiz, J.; Giner, J.; Rodriguez, V.; Lopez, G.; Casabo, J.; Molins, E.; Miravitlles, C. Polyhedron 2000,19, 1627-1631.
21. Perrin, D.D.; Armarego, W.L.F.; Perrin, D.R. Purification of Laboratory Chemicals, 2nd ed.; Pergamon: Oxford, 1980.
22. Zhang, Y.; Yuan, Z.; Puddephatt, J. Allyl (β-diketonato) palladium (II) complexes, including liquid precursors for chemical vapor decomposition of palladium. Chem. Mater. 1998, 10, 2293-2300. (Pubitemid 128473981)
23. Vogel, A.I. Text-book of Practical Organic Chemistry, 3rd ed.; Longman: London, 1977, 139-145, 163-179, 193, 280-288.
24. (a) Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordi nation Compounds, 4th ed.; 1986, 388(a)
25. 3-C3H5)]. Polyhedron 2001, 20, 3119-3125.
26. 3C4. Spectrochim. Acta A 1977, 33, 233-238.
27. (b) Cowley, A.H.; White, W.D. The vibrational spectra and structures of phospho rus compounds-I. Diphosphine disulfides. Spectrochim. Acta 1966, 22, 1431-1440.
28. Claver, C; Ruiz, A.; Masdeu, M.A.; Vinas, J.; Saballs, T; La-hoz, F.J.; Plou, F.J. Diolefin and carbonyl rhodium(I) and irid-ium(I) complexes with phosphine sulphide ligands. Crystal structure of [Rh(COD)(Et2P(S)(S)PEt2)] ClO#INF#4#/INF#. Organomet. Chem. 1989, 373, 269-278.
29. Shobatake, K.; Nakamoto, K. Metal isotope effect on metal-ligand vibra tions. III π-Allyl complexes of palladium(II). J. Am. Chem. Soc. 1970, 92, 3339-3342.
30. Harris, R.K.; Merwin, I.H.; Hagele, G. P-31 nuclear-magnetic-resonance studies of solid diphosphine disulfides-Crystallographic considerations. J. Chem. Soc. Faraday Trans. I 1987, 83, 1055-1062.