Phototransformation of ibuprofen and ketoprofen in aqueous solutions

Chemosphere

Volumn 84, Issue 11, 2011, Pages 1658-1663

  Szabo R K ^a,b   Megyeri, C S ^a   Illes E ^a   Gajda Schrantz, K ^a   Mazellier, P ^b,c   Dombi, A ^a  

^a UNIVERSITY OF SZEGED   (Hungary)

^b UNIVERSITÉ DE POITIERS   (France)

^c UNIVERSITÉ DE BORDEAUX   (France)

Author keywords

Degradation products; Ibuprofen; Ketoprofen; UV photolysis; UV VUV photolysis

Indexed keywords

DEGRADATION; DISSOLVED OXYGEN; IRRADIATION; PHOTOLYSIS;

ANTI-INFLAMMATORY DRUGS; DECOMPOSITION RATE; DEGRADATION PRODUCTS; IBUPROFEN; KETOPROFEN; PHOTOTRANSFORMATIONS; TARGET CONCENTRATIONS; UV PHOTOLYSIS;

PHOTODEGRADATION;

DISSOLVED OXYGEN; IBUPROFEN; KETOPROFEN;

AQUEOUS SOLUTION; CONCENTRATION (COMPOSITION); DECOMPOSITION; DISSOLVED OXYGEN; DRUG; GAS CHROMATOGRAPHY; IRRADIATION; MASS SPECTROMETRY; MINERALIZATION; PHOTOCHEMISTRY; PHOTODEGRADATION; PHOTOLYSIS; POLLUTANT REMOVAL; REACTION RATE; TRANSFORMATION; ULTRAVIOLET RADIATION;

AQUEOUS SOLUTION; ARTICLE; CONTROLLED STUDY; DRUG DECOMPOSITION; EXAMINATION; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; IRRADIATION; MASS FRAGMENTOGRAPHY; PHOTODEGRADATION; PHOTOLYSIS; QUANTUM YIELD; ULTRAVIOLET RADIATION;

EID: 80051670051     PISSN: 00456535     EISSN: 18791298     Source Type: Journal    
DOI: 10.1016/j.chemosphere.2011.05.012     Document Type: Article

References (27)

1. Alapi T., Dombi A. Comparative study of the UV and UV/VUV photolysis of phenol in aqueous solution. J. Photochem. Photobiol. A. 2007, 188:409-418.
2. Borsarelli C.D., Braslavsky S.E., Sortinao S., Marconi G., Monti S. Photodecarboxylation of ketoprofen in aqueous solution. Photochem. Photobiol. 2000, 72:163-171.
3. Boscá F., Miranda M.A. Photosensitizing drugs containing the benzophenone chromophore. J. Photochem. Photobiol. B. 1998, 43:1-26.
4. Buxton G.V., Greenstock C.L., Helman W.P., Ross A.B. Critical review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals, (OH, O-2) in aqueous solution. J. Phys. Chem. Ref. Data 1988, 17:513-886.
5. Dantas R.F., Rossiterb O., Teixeira A.K.R., Simõesc A.S.M., da Silva V.L. Direct UV photolysis of propranolol and metronidazole in aqueous solution. Chem. Eng. J. 2010, 158:143-147.
6. Douki T., Cadet J. Far-UV photochemistry and photosensitization of 2'-deoxycytidylyl-(3'-5')-thymidine: isolation and characterization of the main photoproducts. J. Photochem. Photobiol. B. 1992, 15:199-213.
7. Felis E., Miksch K. Removal of analgesic drugs from the aquatic environment using photochemical methods. Water Sci. Technol. 2009, 60:2253-2259.
8. Gonzalez M.G., Oliveros E., Wörner M., Braun A.M. Vacuum-ultraviolet photolysis of aqueous reaction systems. J. Photochem. Photobiol., A. 2004, 5:225-246.
9. Halling-Sörensen B., Nors Nielsen S., Lankzky P.F., Ingerslev F., Holten Lützhøft H.C., Jörgensen S.E. Occurrence, fate and effects of pharmaceutical substances in the environment - a review. Chemosphere 1998, 36:357-393.
10. Hatchard C.G., Parker C.A. A new sensitive chemical actinometer. II. Potassium ferrioxalate as a standard chemical actinometer. Proc. R. Soc. A. 1956, 235:518-536.
11. Kim I., Tanaka H. Photodegradation characteristics of PPCPs in water with UV treatment. Environ. Int. 2009, 35:793-802.
12. 2 treatments. Chemosphere 2009, 77:518-525.
13. Klavarioti M., Mantzarinos D., Kassinoss D. Removal of residual pharmaceuticals from aqueous systems by advanced oxidation processes. Environ. Int. 2009, 35:402-417.
14. Kosjek T., Heath E., Kompare B. Removal of pharmaceutical residues in a pilot wastewater treatment plant. Anal. Bioanal. Chem. 2007, 387:1379-1387.
15. Kümmerer K., Al-Ahmad A. Biodegradability of some antibiotics, elimination of the genotoxicity and affection of wastewater bacteria in a simple test. Chemosphere 2001, 40:701-710.
16. Legrini O., Oliveros E., Braun A.M. Photochemical processes for water treatment. Chem. Rev. 1993, 93:671-698.
17. Masschelein, W.J., 2002. Ultraviolet Light in Water and Wastewater Sanitation. Lewis Publishers, pp. 13-22.
18. Matamoros V., Duhec A., Albaiges J., Bayona J.M. Photodegradation of carbamazepine, ibuprofen, ketoprofen and 17α-ethinylestradiol in fresh and seawater. Water Air Soil Pollut. 2009, 196:161-168.
19. Monti S., Sortino S., De Guidi G., Marconi G. Supramolecular photochemistry of 2-(3-benzoylphenyl) propionic acid (Ketoprofen). A study in the b-cyclodextrin cavity. New J. Chem. 1998, 22:599-604.
20. Musa K.A., Matxain J.M., Eriksson L.A. Mechanism of photoinduced decomposition of ketoprofen. J. Med. Chem. 2007, 50:1735-1743.
21. Oppenländer T. Photochemical Purification of Water and Air-Advanced Oxidation Processes (AOPs): Principles, Reaction Mechanisms, Reactor Concepts 2003, Wiley-VCH, New York, p. 396.
22. Pereira V.J., Linden K.G., Weinberg H.S. Evaluation of UV irradiation for photolytic and oxidative degradation of pharmaceutical compounds in water. Water Res. 2007, 41:4413-4423.
23. Radjenović J., Petrović M., Barceló D. Fate and distribution of pharmaceuticals in wastewater and sewage sludge of the conventional activated sludge (CAS) and advanced membrane bioreactor (MBR) treatment. Water Res. 2009, 43:831-841.
24. Real F.J., Benitez F.J., Acero J.L., Sagasti J.J.P., Casas F. Kinetics of the chemical oxidation of the pharmaceutical primidone, ketoprofen and diatrizoate in ultrapure and natural waters. Ind. Eng. Chem. Res. 2009, 48:3380-3388.
25. Rosal R., Rodríguez A., Perdigón-Melón J.A., Petre A., García-Calvo E., Gómez M.J., Agüera A., Fernández-Alba A.R. Occurrence of emerging pollutants in urban wastewater and their removal through biological treatment followed by ozonation. Water Res. 2010, 44:578-588.
26. Ternes T., Meisenheimer M., McDowell D., Sacher F., Brauch H.-J., Haist-Gulde B., Preuss G., Wilme U., Zulei-Seibert N. Removal of pharmaceuticals during drinking water treatment. Environ. Sci. Technol. 2002, 36:3855-3863.
27. 2. Water Res. 2009, 43:1766-1774.