Chemoenzymatic total synthesis of ent-neopinone and formal total synthesis of ent -codeinone from β-bromoethylbenzene

Canadian Journal of Chemistry

Volumn 89, Issue 6, 2011, Pages 709-728

  Duchek, Jan ^a   Piercy, T Graeme ^a   Gilmet, Jacqueline ^a   Hudlicky, Tomas ^a  

^a BROCK UNIVERSITY   (Canada)

Author keywords

ent codeinone synthesis; ent neopinone synthesis; Enzymatic dihydroxylation of aromatics; Heck reaction; synthesis of morphine alkaloids

Indexed keywords

ALDOL CONDENSATION; DIHYDROXYLATION; E. COLI; ENT -CODEINONE SYNTHESIS; ENT -NEOPINONE SYNTHESIS; HECK REACTIONS; MANNICH CYCLIZATION; SIDE-CHAINS; SPECTRAL DATA; STEREOGENIC CENTERS; TOLUENE DIOXYGENASE; TOTAL SYNTHESIS;

CONDENSATION REACTIONS; ESCHERICHIA COLI; HYDROXYLATION; SYNTHESIS (CHEMICAL); TOLUENE;

CYCLIZATION;

EID: 80051493050     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/v11-071     Document Type: Review

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