Analysis of semibatch emulsion polymerization: Role of ultrasound and initiator

Ultrasonics Sonochemistry

Volumn 19, Issue 1, 2012, Pages 97-103

  Bhanvase, B A ^a   Pinjari, D V ^b   Sonawane, S H ^a   Gogate, P R ^b   Pandit, A B ^b  

^a VISHWAKARMA INSTITUTE OF TECHNOLOGY   (India)

^b INSTITUTE OF CHEMICAL TECHNOLOGY   (India)

Author keywords

Emulsion polymerization; Initiator; PMMA nanoparticles; Semi batch; Ultrasound

Indexed keywords

EMULSIFICATION; FREE RADICALS; INITIATORS (EXPLOSIVES); PARTICLE SIZE; ULTRASONICS;

BATCH EMULSION POLYMERIZATION; MONOMER CONCENTRATION; NARROW SIZE DISTRIBUTIONS; PARAMETRIC CONDITIONS; PMMA NANOPARTICLES; POLYMER PARTICLE SIZE; SEMI-BATCH; SEMI-BATCH EMULSION POLYMERIZATION;

EMULSION POLYMERIZATION;

FREE RADICAL; NANOPARTICLE; POLY(METHYL METHACRYLATE); SURFACTANT;

ARTICLE; BATCH REACTOR; EMULSION; PARTICLE SIZE; POLYMERIZATION; PRIORITY JOURNAL; THERMAL ANALYSIS; ULTRASOUND;

EID: 80051471031     PISSN: 13504177     EISSN: 18732828     Source Type: Journal    
DOI: 10.1016/j.ultsonch.2011.05.016     Document Type: Article

References (35)

1. K. Ohsawa, M. Neo, H. Matsuoka, H. Ito, and T. Nakamura Tissue responses around polymethylmethacrylate particles implanted into bone: analysis of expression of bone matrix protein mRNAs by in situ hybridization J. Biomed. Mater. Res. 54 2001 501
2. R.P. Kusy Characterization of self-curing acrylic bone cements J. Biomed. Mater. Res. 12 1978 271
3. J. Charnley Acrylic Cement in Orthopaedic Surgery 1972 Churchill, Livingstone London
4. B. Sires, and P. Benda Osteogenesis in a human hydroxyapatite orbital implant 5.5 years after implantation Am. J. Ophthalmol. 130 2000 369
5. C. Parra, G. González, and C. Albano Synthesis and characterization of poly(methyl methacrylate) obtained by ultrasonic irradiation E-Polymers 25 2005 ISSN 1618-7229
6. A. Klein, and E.S. Daniels P.A. Lovell, EI-Asserm Emulsion Polymerization and Emulsion Polymers 1997 Wiley New York 207
7. X.L. Xu, Z.C. Zhang, and X.W. Ge Effect of dose rate on emulsion and microemulsion polymerization of styrene J. Polym. Sci., A: Polym. Chem. 36 1998 257
8. G.J. Price Recent developments in sonochemical polymerization Ultrason. Sonochem. 10 2003 277
9. B.M. Teo, S.W. Prescott, M. Ashokkumar, and F. Grieser Ultrasound initiated miniemulsion polymerization of methacrylate monomers Ultrason. Sonochem. 15 2008 89
10. T.J. Mason, and P.J. Lorimer Sonochemistry: Theory, Applications and Uses of Ultrasound in Chemistry 1988 Ellis Horwood Chichester
11. S.H. Sonawane, B. Neppolian, B. Teo, F. Grieser, and M. Ashokkumar Ultrasound-assisted preparation of semiconductor/polymer photoanodes and their photoelectrochemical properties J. Phys. Chem. C. 114 2010 5148
12. Y. Cao, Y. Zheng, and G. Pan Radical generation process studies of the cationic surfactants in ultrasonically irradiated emulsion polymerization Ultrason. Sonochem. 15 2008 320
13. G.J. Price Ultrasonically enhanced polymer synthesis Ultrason. Sonochem. 3 1996 229
14. P. Kruss, and T.J. Patraboy Initiation of polymerization with ultrasound in methyl methacrylate J. Phys. Chem. 89 1985 3379
15. S.K. Ooi, and S. Biggs Ultrasonic initiation of polystyrene latex synthesis Ultrason. Sonochem. 7 2000 125
16. H.M. Cheung, and K. Gaddam Ultrasound-assisted emulsion polymerization of methyl methacrylate and styrene J. Appl. Polym. Sci. 76 2000 101
17. 2 J. Supercrit. Fluids 33 2005 269
18. H. Xia, Q. Wang, Y. Liao, X. Xu, S.M. Baxter, R.V. Slone, S. Wu, G. Swift, and D.G. Westmoreland Polymerization rate and mechanism of ultrasonically initiated emulsion polymerization of n-butyl acrylate Ultrason. Sonochem. 9 2002 151
19. M.A. Bradley, and F. Grieser Emulsion polymerization synthesis of cationic polymer latex in an ultrasonic field J. Colloid Interface Sci. 251 2002 78
20. N. Yin, K. Chen, and W. Kang Preparation of BA/ST/AM nano particles by ultrasonic emulsifier-free emulsion polymerization Ultrason. Sonochem. 13 2006 345
21. Y. Kojima, S. Koda, and H. Nomura Effect of ultrasonic frequency on polymerization of styrene under sonication Ultrason. Sonochem. 8 2001 75
22. N. Yin, and K. Chen Ultrasonically initiated emulsifier-free emulsion copolymerization of n-butyl acrylate and acrylamide. Part I: polymerization mechanism Polym. 45 2004 3587
23. B.M. Teo, M. Ashokkumar, and F. Grieser Sonochemical polymerisation of miniemulsions in organic liquids/water mixtures Phys. Chem. Chem. Phys. 13 2011 4095
24. B.M. Teo, F. Grieser, and M. Ashokkumar High intensity ultrasound initiated polymerisation of butyl methacrylate in mini- and microemulsions Macromol. 42 2009 4479
25. S. Sajjadi, and M. Yianneskis Semibatch emulsion polymerization of methyl methacrylate with a neat monomer feed Polym. React. Eng. 11 2003 715
26. H. Monnier, A.M. Wilhelm, and H. Delmas Effects of ultrasound on micromixing in flow cell Chem. Eng. Sci. 55 2000 4009
27. W.V. Smith, and R.H. Ewart Kinetics of emulsion polymerization J. Chem. Phys. 16 1948 592
28. B.M. Teo, M. Ashokkumar, and F. Grieser Microemulsion polymerizations via high-frequency ultrasound irradiation J. Phys. Chem. B 112 2008 5265
29. H.C.J. Chou, and J.O. Stoffer Ultrasonically initiated free radical-catalyzed emulsion polymerization of methyl methacrylate (I) J. Appl. Polym. Sci. 72 1999 797
30. G. Odian Principles of Polymerization 2004 John Wiley & Sons New Jersey, Inc.
31. K. Landfester, F.J. Schork, and V.A. Kusuma Particle size distribution in mini-emulsion polymerization C. R. Chimie 6 2003 1337
32. B.D. Flockhart The critical micelle concentration of sodium dodecyl sulfate in ethanol-water mixtures J. Colloid Sci. 12 1957 557
33. T.Y. Cao, Q.P. Liu, and J.S. Hu Polymer Emulsion Synthesis Principle, Performance and Appliance 1997 Chemical Industry Press Beijing
34. C. Albano, G. Gonzalez, and C. Parra Sonochemical synthesis of polymethylmethacrylate to be used as biomaterial Polym. Bull. 65 2010 893
35. J. Straka, P. Schmidt, J. Dybal, B. Schneider, and J. Spevacek Blends of poly (ethylene oxide) poly (methyl methacrylate), An i.r. and n.m.r. study Polymer 36 1995 1147