Synthesis and characterization of manganese oxide and investigation of its catalytic activities for oxidation of benzyl alcohol in liquid phase

International Journal of Chemical Reactor Engineering

Volumn 9, Issue , 2011, Pages

  Ilyas, Mohammad ^a   Saeed, Muhammad ^a  

^a UNIVERSITY OF PESHAWAR   (Pakistan)

Author keywords

benzaldehyde; benzoic acid; benzyl alcohol; FTIR; manganese oxide; SEM; XRD

Indexed keywords

BENZOIC ACID; CATALYTIC OXIDATION; CHEMICAL ANALYSIS; MANGANESE OXIDE; MIXTURES; OXIDES; OXYGEN; PARTICLE SIZE; PARTICLE SIZE ANALYSIS; PORE SIZE; SCANNING ELECTRON MICROSCOPY; WATER FILTRATION; X RAY DIFFRACTION;

BENZALDEHYDE; BENZYL ALCOHOL; EFFECT OF CATALYST LOADINGS; FTIR; MECHANOCHEMICAL PROCESS; OXYGEN AND NITROGENS; PARTIAL PRESSURE OF OXYGEN; SYNTHESIS AND CHARACTERIZATIONS;

CATALYST ACTIVITY;

EID: 79961244075     PISSN: None     EISSN: 15426580     Source Type: Journal    
DOI: 10.2202/1542-6580.2646     Document Type: Article

References (50)

1. Brock, S. L., Sanabria, M., Nair, J., Suib, S. L., Ressler, T., "Tetraalkylammonium Manganese Oxide Gels: Preparation, Structure, and Ion-Exchange Properties", Journal of Physical Chemistry B, (2001) Vol.105, No. 23, 5404-5410. (Pubitemid 35372587)
2. Brunauer, S., Emmett, P.; Teller, E.; "Adsorption of gases in multimolecular layers" Journal of American Chemical Society, (1938) Vol. 60, No. 2, 309-319.
3. Brunauer, S., Deming, L. S., Deming, W. E., Teller, E., "On a Theory of the vander Waals Adsorption of Gase" Journal of American Chemical Society, (1940) Vol. 62, No. 7, 1723-1732.
4. Chen, J., Lin, J. C., Purohit, V., Cutlip, M. B., Suib, S. L., "Photoassisted Catalytic Oxidation of Alcohols and Halogenated Hydrocarbons with Amorphous Manganese Oxides", Catalysis Today, (1997) Vol. 33, No. 1- 3, 205-214. (Pubitemid 127378874)
5. Chen, X., Shen, Y. F., Suib, S. L., O'Young, C. L., "Catalytic Decomposition of 2-Propanol over Different Metal-Cation-Doped OMS-2 Materials", Journal of Catalysis, (2001) Vol. 197, 292-302. (Pubitemid 32376684)
6. Caot, H., Suib, S. L., "Highly Efficient Heterogeneous Photooxidation of 2- Propanol to Acetone with Amorphous Manganese Oxide Catalysts", Journal of American Chemical Society, (1994) Vol. 116, No. 12, 5334-5342. (Pubitemid 24981116)
7. Doheim, M. M., Hanafy, S. A., El-Shobaky, G. A., "Catalytic Conversion of Ethanol and Isopropanol over the Mn2O3/Al2O3 System Doped with Na2O", Materials Letters, (2002) Vol. 55, 304-311.
8. Espinal, L., Suib, S. L., Rusling, J. F., "Electrochemical Catalysis of Styrene Epoxidation with Films of MnO2 Nanoparticles and H2O2", Journal of American Chemical Society, (2004) Vol.126, 7676-7682. (Pubitemid 38781501)
9. Gandhe, A. R., Rebello, J. S., Figueiredo, J. L., Frenandes, J. B., "Manganese Oxide OMS-2 as an Effective Catalyst for Total Oxidation of Ethyl Acetate", Applied Catalysis B: Environmental, (2007) Vol. 72, 129-135. (Pubitemid 46227950)
10. Ghosh, M., Biswas, K., Sundaresan, A., Rao, C. N. R., "MnO and NiO Nanoparticles: Synthesis and Magnetic Properties", Journal of Material Chemistry, (2006) Vol. 16, No.1, 106-111. (Pubitemid 43324491)
11. Hu, C., Xing, S., Qu, J., He, H., "Catalytic Ozonation of Herbicide 2, 4-D over Cobalt Oxide Supported on Mesoporous Zirconia", Journal of Physical Chemistry C, (2008) Vol. 112, No. 15, 5978-5983.
12. Hu, J., Sun, K., He, D., Xu, B., "Amorphous Manganese Oxide for Catalytic Aerobic Oxidation of Benzyl Alcohol", Chinese Journal of Catalysis,(2007), Vol. 28, No. 12, 1025-1027.
13. Ilyas, M.; Ikramullah.; "Dehydrogenation of Cyclohexanol to Cyclohexanone Catalyzed by Y2O3/ZrO2: Activation Energy" Catalysis Communications, (2004) Vol. 5, No. 1, 1-4.
14. Ilyas, M., Sadiq, M., "Liquid Phase Aerobic Oxidation of Benzyl Alcohol Catalyzed by Pt/ZrO2", Chemical Engineering and Technology, (2007) Vol. 30, No.10, 1391-1397. (Pubitemid 47611239)
15. Ilyas, M., Sadiq, M., "Kinetics of Heterogeneous Solvent-free Liquid Phase Oxidation of Alcohol Using ZrO2 Catalyst with Molecular Oxygen", Chinese Journal of Chemistry, (2008) Vol. 26, No. 5, 941-946.
16. Ilyas, M., Saeed, M., "Oxidation of Benzyl Alcohol in Liquid Phase Catalyzed by Oxides of Nickel", Journal of The Chemical Society of Pakistan, (2009) Vol 31, No. 4, 526-533.
17. Ilyas, M., Saeed, M., "Oxidation of Benzyl Alcohol in Liquid Phase Catalyzed by Cobalt Oxide" International Journal of Chemical Reactor Engineering (2010) Vol. 8, A77.
18. Ji, H., Wang, T., Zhang, M., She, Y., Wang, L., "Simple Fabrication of Nanosized NiO2 Powder and its Application to Oxidation Reactions", Journal of Applied Catalysis A: General, (2005) Vol. 282, 25-30. (Pubitemid 40329000)
19. Jing, H., Keqiang1, S., Daiping, H., Boqing, X., "Amorphous Manganese Oxide for Catalytic Aerobic Oxidation of Benzyl Alcohol", Chinese Journal of Catalysis, (2007) Vol. 28, No. 12, 1025-1027.
20. Kannan, R., Jegan, A., Ramasubbu, A., Karunakaran, K., Vasanthkumar, S., "Synthesis and Catalytic Studies of Layered and OMS Type Nano Manganese Oxide Material", Digest Journal of Nanomaterial Biostructres, (2011) Vol. 6, 755-760
21. Kijlstra, W. S., Brands, D. S., Smit, H. I., Poels, E. K., Bliek, A., "Mechanism of the Selective Catalytic Reduction of NO with NH3 over MnOx/Al2O3", Journal of Catalysis, (1997) 171, 219-230.
22. Li, Q., Luo, G., Li, J., Xia, X., "Preparation of Ultrfine MnO2 Powders by the Solid state Method Reaction of KMnO4 with Mn (II) salts at Room Temperature", Journal of Materials Processing Technology, (2003) Vol. 137, 25-29.
23. Lia, J., Shafi, K., Ulman, A., Loos, K., Yang, N. L., Cui, M. H., Vogt, T., Estournes, C., Locke, D. C., "Mixed Iron-Manganese Oxide Nanoparticles", Journal of Physical Chemistry: B, (2004) Vol.108, No. 39, 14876-14883.
24. Li, X., Xu, J., Wang, F., Gao, J., Zhou, L., Yang, G., "Direct Oxidation of Toluene to Benzoic Acid with Molecular Oxygen over Manganese Oxides", Catalysis Letters, (2006) Vol.108, No.3-4, 137-140.
25. Liang, S., Teng, F., Bulgan, G., Zong, R., Zhu, Y., "Effect of Phase Structure of MnO2 Nanorod Catalyst on the Activity for CO Oxidation", Journal of Physical Chemistry C, (2008) Vol. 112, No. 14, 5307-5315.
26. Lou, J., Zhang, Q., Garcia-Martnez, J., Suib, S. L., "Adsorption and acidic Properties, Reversible Lattice Oxygen Evolution, and Catalytic Mechanism of Cryptomelane -Type Manganese Oxides as Oxidation Catalysts" Journal of The American Chemical Society, (2008) Vol. 130, 3198-3207. (Pubitemid 351455989)
27. Lou, J., Zhang, Q., Garcia-Martnez, J., Suib, S. L., "Adsorption and acidic Properties, Reversible Lattice Oxygen Evolution, and Catalytic Mechanism of Cryptomelane -Type Manganese Oxides as Oxidation Catalysts" Journal of The American Chemical Society, (2008) Vol. 130, 3198-3207.
28. Mirzaei, A. A., Shaterian, H. R., Habibi, M., Hutchings, G. J., Taylor, S. H., "Characterization of Copper-Manganese Oxide Catalysts: Effect of Precipitate ageing Upon the Structure and Morphology of Precursors and Catalysts", Applied Catalysis A: Genral, (2003) Vol. 253, 499-508.
29. Mori, K., Hara, T., Mizugaki, T., Ebitani, K., Kaneda, K., "Hydroxyapatite- Supported Palladium Nanoclusters: A Highly Active Heterogeneous Catalyst for Selective Oxidation of Alcohols by Use of Molecular Oxygen" Journal of the American Chemical Society, (2004) Volume 126, No. 24, 10657-10666. (Pubitemid 39129166)
30. Malinger, K. A., Ding, Y. S., Sithambaram, S., Espinal, L., Gomez, S., Suib, S. L., "Microwave frequency effects on synthesis of cryptomelane-type manganese oxide and catalytic activity of cryptomelane precursor", Journal of Catalysis, (2006) Vol. 239, No. 2, 290-298.
31. Qi, G., Yang, R. T., "Low-Temperature Selective Catalytic Reduction of NO with NH3 over Iron and Manganese Oxides Supported on Titania", Applied Catalysis B: Environmental, (2003) Vol. 44, 217-225. (Pubitemid 37007956)
32. Radhakrishnan, R., Oyama, S. T., "Ozone Decomposition over Manganese Oxide Supported on ZrO2 and TiO2: A Kinetic Study Using in Situ Laser Raman Spectroscopy", Journal of Catalysis, (2001) Vol. 199, No. 2, 282-290. (Pubitemid 32450042)
33. Sing, K.; Everett, D.; Haul, R.; Moscou, L.; Pierotte, R.; Rouquerol, J.; Siemieniewska, T.; "Reporting Physisorption data for Gas/solid Systems with Special Reference to the Determination of Surface Area and Porosity" Pure and Applied Chemistry, (1985) Vol. 57, No. 4, 603-619.
34. Su, Y., Wang, L. C., Liu, Y., Cao, Y. M., He, H. Y., Fan, K. N., "Micreowave- Accelarated Solvent Free Aerobic Oxidation of Benzyl Alcohol over Efficient and Reusable Manganese Oxides", Catalysis Communications, (2007) Vol. 8, No. 12, 2181-2185. (Pubitemid 47633363)
35. Tang, Q., Liu, T., Yang, Y., "Role of Potassium in the Aerobic Oxidation of Aromatic Alcohols Over K+-promoted Mn/C catalysts" Catalysis Communications, (2008), Vol. 9, 2570-2573.
36. Tang, Q., Huang, X., Wu, C., Zhao P., Chen, Y., Yang, Y., "Structure and Catalytic Properties of K-doped Manganese Oxide Supported on Alumiona", Journal of Molecular Catalysis A: Chemical, (2009), Vol. 306, 48-53
37. Tian, Z. R., Tong, W., Wang, J. Y., Duan, N. G., Krishnan, V. V., Suib, S. L., "Manganese Oxide Mesoporous Structures: Mixed-Valent Semiconducting Catalysts", Science, (1997) Vol. 276, No. 5314, 926-930. (Pubitemid 27209085)
38. Trawczynski, J., Bielak, B., Mista, W., "Oxidation of Ethanol over Supported Manganese Catalysts - Effect of the Carrier", Journal of Applied Catalysis B: Environmental, (2005) Vol. 55, No. 4, 277-285.
39. Vileno, E., Zhou, H., Zhang, Q., Suib, S. L., Corbin, D. R., Koch, T. A., "Synthetic Todorokite Produced by Microwave Heating: An Active Oxidation Catalyst", Journal of Catalysis, (1999) Vol. 187, No. 2, 285-297. (Pubitemid 129717374)
40. Wang, X., Andrews, L., "Infrared Spectra of M (OH)1,2,3 (M = Mn, Fe, Co, Ni) Molecules in Solid Argon and the Character of First Row Transition Metal Hydroxide Bonding", Journal of Physical Chemistry A, (2006) Vol.110, No. 33, 10035-10045. (Pubitemid 44373317)
41. Wang, L.; Ebina, Y.; Takada, K.; Kurashima, K.; Sasaki, T.; "A New Mesoporous Manganese Oxide Pillared with Double Layers of Alumina", Advanced Materials, 2004, Vol. 16, No. 16, 1412-1416.
42. Wang, L. C, He, L., Liu, Y. M., Cao, Y., He, H. Y., Fan, K. N., Zhuang, J. H., "Effect of Pretreatment Atmosphere on CO Oxidation over α-Mn2O3 Supported Gold Catalysts", Journal of Catalysis, 2009, Vol. 264, 145-153.
43. Xia, G. G., Yin, Y. G., Willis, W. S., Wang, J. Y., Suib, S. L., "Efficient Stable Catalysts for Low Temperature Carbon Monoxide Oxidation", Journal Catalysis, 1999, Vol. 185, No. 1, 91-105. (Pubitemid 129717251)
44. Yang, H., Hu, Y., Zhang, X., Qiu, G., "Mechanochemical Synthesis of Cobalt Oxide Nanoparticles", Materials Letters, 2004, Vol. 58, 387-389.
45. Ye, C., Lin, Z. M., Yan, J. X., "Preparation and Characterization of Rod-shaped MnO2 Crystal", Solid State Communications, 2005, Vol. 133, 121-123.
46. Yuan, A. B., Zhou, M., Wang, X. L., Sun, Z. H., Wang, Y. Q., "Synthesis and Characterization of Nanostructured Manganese Dioxide Used as Positive Electrode Material for Electrochemical Capacitor with Lithium Hydroxide Electrolyte", Chinese Journal of Chemistry, 2008, Vol. 26, No. 1, 65-69.
47. Yuan, C., Gao, B., Su, L., Zhang, X., "Interface Synthesis of Mesoporous MnO2 and its Electrochemical Capacitive Behaviors", Journal of Colloid And Interface Science, 2008, Vol. 322, 545-550.
48. Zhou, H., Shen, Y. F., Wang, J. Y., Chen, X.; O'Young, C. L., Suib, S. L., "Studies of Decomposition of H2O2 over Manganese Oxide Octahedral Molecular Sieve Materials", Journal of Catalysis, 1998, Vol. 176, No. 2, 321-328.
49. Zaki, M. I., Hassan, M. A., Pasupulety, L., Fouad, N. E., knozinger, H., "CO and CH4 Total Oxidation Over Manganese Oxide Supported on ZrO2, TiO2, TiO2-Al2O3 and SiO2-Al2O3 Catalysts", New Journal of Chemistry, 1999, Vol. 23, 1197-1202.
50. Zhu, S., Zhang, D., Li, Z., Furukawa, H., Chen, Z., "Precision Replication of Hierarchical Biological Structures by Metal Oxides Using a Sonochemical Method", Langmuir, 2008, Vol. 24, No. 12, 6292-6299.