Epoxidation of wild safflower (Carthamus oxyacantha) oil with peroxy acid in presence of strongly acidic cation exchange resin IR-122 as catalyst

International Journal of ChemTech Research

Volumn 3, Issue 3, 2011, Pages 1152-1163

  Meshram, Pawan D ^a   Puri, Ravindra G ^a   Patil, Harshal V ^a  

^a NORTH MAHARASHTRA UNIVERSITY   (India)

Author keywords

Acidic cation exchange resin; Epoxidation; Reaction parameters; Wild safflower oil

Indexed keywords

ACETIC ACID; CARBOXYLIC ACID; EPOXIDE; ETHYLENE OXIDE; FORMIC ACID; HYDROGEN PEROXIDE; IODINE; LINOLEIC ACID; OLEIC ACID; PERACETIC ACID; POLACRILIN; SAFFLOWER OIL;

AQUEOUS SOLUTION; ARTICLE; CATALYST; CHEMICAL REACTION; EPOXIDATION; INFRARED SPECTROSCOPY; OXYGEN TRANSPORT; TEMPERATURE;

EID: 79961130230     PISSN: None     EISSN: 09744290     Source Type: Journal    
DOI: None     Document Type: Article

References (30)

1. Le P. L., Wan Yunus W.M.Z., Yeong S. K., Dezulkelfly K. A., Lim W. H., Optimization of the epoxidation of methyl ester of palm fatty acid distillate J. Oil Palm Res., 2009, 21, 675-682.
2. Holser R. A., Transesterification of epoxidized soybean oil to prepare epoxy methyl esters, Ind. Crops and Products, 2008, 27, 130-132.
3. Goud V.V., Mungroo R., Pradhan N.C., and Dalai A.K., Modification of epoxidised canola oil, Asia-Pacific J. Chem. Eng., 2011, 6, 14-22.
4. Dahlke B., Hellbardt S., Paetow M., Zech W.H., Polyhydroxy fatty acids and their derivatives from plant oils, J. Am. Oil Chem. Soc., 1995, 72, 349-353.
5. Okieimen F.E, Pavithran C., Bakare I.O., Epoxidation and hydroxylation of rubber seed oil: one-pot multi step reactions, Euro. J. Lipid Sci. & Tech., 2005, 107, 864-870.
6. Patwardhan A.V., Goud V.V., Pradhan N.C., Epoxidation of Karanja (Pongamia glabra) Oil by H2O2, J. Am. Oil Chem. Soc., 2006, 83, 247-252.
7. Carlson K.D., Kleiman R., Bagby M.O, Epoxidation of lesquerella and limmanthes (meadowfoam) oil, J. Am. Oil Chem. Soc., 1994, 71, 175-182.
8. Marcel S.F., Lei K. J. and Mohammad K.P., Epoxidation reactions of unsaturated fatty esters with peroxomonosulphate, Lipids, 1998, 33, 633-637.
9. Sonnet P. E. and Foglia T., Epoxidation of natural triglycerides with ethyl methydioxyrane, J. Am. Oil Chem. Soc., 83, 835-840.
10. Aerts A. J., Jacob P.A., Epoxide yield determination of oils and fatty acid methyl esters using 1H NMR, J. Am. Oil Chem. Soc., 2004, 81, 841-846
11. Gurbanov M. S., and Mamedov B. A., Epoxidation of Flax Oil with Hydrogen Peroxide in a Conjugate System in the presence of Acetic Acid and Chlorinated Cation Exchanger KU-2×8 as Catalyst, Russian J. App. Chem., 2009, 82, 1483-1487.
12. Khot S. N., Lascala J. J., Can E., Moyre S. S., Williams, G. I., Palmese, G.R., Kusefoglu, S. H. and Wool, R.P., Development and Application of Triglyceride-Based Polymers and Composites, J. Appl. Polym. Sci., 2001, 82, 703-723.
13. Biermann U., Friedt W., Lang S., Luhs W., Machmuller G., Metzger J. O., Klaas M. R., Schafer H.J. and Schneider M.P., New Synthesis with Oils and Fats as Renewable Materials for the Chemical Industry, Agew. Chem. Int. Ed., 2000, 39, 2206-2224.
14. Muturi P., Wang D., and Dirlikov S., Epoxidized vegetable oils as reactive diluents. I. Comparison of vernonia, epoxidized soybean and epoxidized linseed oil, Progress in Organic Coatings, 1994, 25, 85-94.
15. Adhvaryu A., Erhan S.Z., Epoxidized soybean oil as a potential source of high-temperature lubricants, Industrial Crops and Products, 2002, 15, 247-254.
16. Soucek M. D., Johnson A. H., Wegner J. M., Ternary evaluation of UV-curable seed oil inorganic/organic hybrid coatings using experimental design Progress in Organic Coatings, 2004, 51, 300-311.
17. Zhang L.P., Safflower: a versatile plant, IV International Safflower Conf., Bari, 2-7 June, 1997, 311-329.
18. Hilker D., Bothe J. P. and Warnecke H.J., Chemo-Enzymatic Epoxidation of Unsaturated Plants Oils, Chemical Engineering Science, 2001, 56, 427-432
19. Anjani K., Mukta N. and Lakshmamma P., Crop improvement: In Research Achievements in Safflower, Directorate of Oilseeds Research, Hyderabad, India, 11.
20. Ravikumar R.L., Soregaon C.D. and Satish D., Molecular diversity analysis of five different species of genus Carthamus, National Seminar on Changing Global Vegetable Oils Scenario: Issues and Challenges before India, Directorate of Oilseeds Research, Hyderabad, India, 29-31 January, 2007, 2-4.
21. Ashri A., Zimmer D.E., Urie A.L., Cahaner A. and Marani A., Evaluation of world collection of safflower Carthamus tinctorius L. yield and yield components and their relationships, Crop Sci., 1974, 14, 799-802.
22. Banergy R., Pandey V. and Dixit B. S., Wild Safflower: An alternative source of safflower oil, J. Oil Tech. Assoc. Ind., 1999, 31, 59-60.
23. Dalai A.K., Mungroo R., Pradhan N.C., Goud V.V., Epoxidation of canola oil with hydrogen peroxide catalyzed by acidic ion exchange resin, J. Am. Oil Chem. Soc.,2008, 85, 887-896.
24. Petrovic Z. S., Zlatanic A., Lava C.C., Sinadinovic-Fiser S., Epoxidation of soybean oil in toluene with peroxoacetic and peroxoformic acids. Kinetics and side reactions, Eur. J. Lipid Sci. & Tech., 2002, 104, 293-299.
25. Gan L.H., Goh S.H., and Ooi K.S., Kinetics studies of epoxidation and oxirane cleavage of palmolein methyl esters, J. Am. Oil Chem. Soc., 1992, 69, 347-351.
26. S. Hernandez-Lopez, E. Martin del Campo-Lopez, V. Sanchez-Mendieta, F. Urena-Nunez and E. Vigueras- Santiago, Gamma Irradiation on Acrylated-Expoxidized Soybean Oil: Polymerization and Characterization, Adv. in Tech. of Mat. and Mat. Proc. J., 2006, 8, 220-225.
27. Vlcek T., Petrovic Z.S., Optimization of the chemoenzymatic epoxidation of soybean oil, J. Am. Oil Chem. Soc., 2006, 83,247-252
28. Pares X.P.X., Bonnet C., and Morin O., Synthesis of New Derivatives from Vegetable Oil Methyl Esters via Epoxidation and Oxirane Opening, in Recent Developments in the Synthesis of Fatty Acid Derivative (Knothe, G. and Derksen, J.T.P., Eds.) AOCS Press, 1999, Champaign, IL, 141-156.
29. G. Lopez Tellez, E. Vigueras-Santiago, S. Hernandez-Lopez, Characterization of epoxidized linseed oil at different percentage, Surface and Emptiness, 2009, 22, 5-10.
30. G. Lopez-Tellez, E. Vigueras-Santiago, S. Hernandez-Lopez, B. Bilyeu, Synthesis and thermal cross linking study of partially aminated epoxidized linseed oil, Designed Monomers and Polymers, 2008, 11, 435-445.