Kinetics of CO2 hydrate formation in a continuous flow reactor

Chemical Engineering Journal

Volumn 172, Issue 1, 2011, Pages 144-157

  Yang, Dali ^a   Le, Loan A ^b   Martinez, Ronald J ^b   Currier, Robert P ^b   Spencer, Dwain F ^c  

^a LOS ALAMOS NATIONAL LABORATORY   (United States)

^b LOS ALAMOS NATIONAL LABORATORY   (United States)

^c SIMTECHE   (United States)

Author keywords

CO2hydrate; Hydrate formation; IGCC; Kinetics; Mass transfer

Indexed keywords

APPARENT KINETICS; CONTINUOUS FLOW REACTORS; FIRST ORDER REACTIONS; FIRST-ORDER MODELS; FLOW CONDITION; FLUID VELOCITIES; GAS CARRIERS; GAS PHASIS; GAS VOLUME FRACTION; GLOBAL REACTION RATE; HEAT AND MASS TRANSFER; HEAT TRANSFER RATE; HYDRATE FORMATION; HYDRATE PHASE; IGCC; IN-PROCESS; PROCESSING CONDITION; RATE LAWS; SLURRY CONCENTRATION; THERMAL TRANSPORT;

ARGON; CARBON MONOXIDE; CARRIER CONCENTRATION; COMPUTER SIMULATION; GAS HYDRATES; HEAT TRANSFER; HELIUM; HYDRATION; KINETICS; MASS TRANSFER; MIXTURES; PHASE INTERFACES; RATE CONSTANTS; SYNTHESIS (CHEMICAL); SYNTHESIS GAS; TITRATION; ENZYME KINETICS; VOLUME FRACTION;

CARBON DIOXIDE;

EID: 79961009880     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2011.05.082     Document Type: Article

References (54)

1. W. Barbour, C. Carner, M. Johnson, R. Morgan, R. Sacquety, B. Williams, S. Sitzer, et al., Carbon Dioxide Emissions from the Generation of Electric Power in the United State, A DOE and EPA Joint Staff Report, Washington DC, July, 2000.
2. Klara S.M., Srivastava R.D. US DOE integrated collaborative technology development program for CO2 separation and capture. Environmental Progress 2002, 21:247-253.
3. Booras G.S., Smelser S.C. An engineering and economic evaluation of CO2 removal from fossil-fuel-fired power plants. Energy 1991, 16:1295-1305.
4. Hess G. Incentives boost coal gasification. Chemical and Engineering News 2006, 84:22-24.
5. Joshi M.M., Lee S.G. Integrated gasification combined cycle. A review of IGCC technology. Energy Sources 1996, 18:537-568.
6. Smith D.J. IGCC: the 21st century's answer for the clean burning of coal. Power Engineering 2000, 104:53-58.
7. Yang H., Xu Z., Fan M., Gupta R., Slimane R.B., Bland A.E., Wright I. Progress in carbon dioxide separation and capture: a review. Journal of Environmental Science 2008, 20:14.
8. D. Spencer, Methods and Systems for Selectively Separating CO2 from a Multi-component Gaseous Stream - New Process and Specific Component Claims, US Patent, No. 6,797,039B2, November 28, 2004.
9. D. Spencer, Improved Methods of Selectively Separating CO2 from a Multi-component Gaseous Stream - New Process and Reactor Design, US Patent, No. 7,128,777, October 31, 2006.
10. Sloan E.D. Clathrate Hydrates of Natural Gases 1998, Marcel Dekker, Inc., New York. 2nd edition.
11. Brewer P., Friederich G., Peltzer E.T., Orr F.M.J. Direct experiments on the ocean disposal of fossil fuel CO2. Science 1999, 284.
12. Robinson D.B., Mehta B.R. Journal of Canadian Petroleum Technology 1971, 10:33-35.
13. Zhang S.-X., Chen G.-J., Ma C.-F., Yang L.-Y., Guo T.-M. Hydrate formation of hydrogen+hydrocarbon gas mixtures. Journal of Chemical and Engineering Data 2000, 45:908-911.
14. Sugahara T., Murayama S., Hashimoto S., Ohgaki K. Phase equilibria for H2+CO2+H2O system containing gas hydrates. Fluid Phase Equilibria 2005, 233:190-193.
15. Morgan J.J., Blackwell V.R., Johnson D.E., Spencer D.F., North W.J. Hydrate formation from gaseous CO2 and water. Environmental Science and Technology 1999, 33:1448-1452.
16. North W.J., Blackwell V.R., Morgan J.J. Studies of CO2 hydrate formation and dissolution. Environmental Science and Technology 1998, 32:676-681.
17. Saji A., Noda H., Tanii T., Kawata H., Takata T., Shoji K., Kitamura H., Kamata T. Simulation on sedimentation of CO2 in deep sea. Kagaku Kogaku Ronbunshu 1996, 22:1273-1280.
18. Koide H., Takahashi M., Shindo Y., Tazaki Y., Iijima M., Ito K., Kimura N., Omata K. Hydrate formation in sediments in the sub-seabed disposal of CO2. Energy 1997, 22:279-283.
19. Mori Y.H. Comments on simulation on sedimentation of CO2 in deep sea. Kagaku Kogaku Ronbunshu 1997, 23:738-739.
20. Brewer P.G., Peltzer E.T., Walz P., Aya I., Yamane K., Kojima R., Nakajima Y., Nakayama N., Haugan P., Johannessen T. Deep ocean experiments with fossil fuel carbon dioxide: creation and sensing of a controlled plume at 4km depth. Journal of Marine Research 2005, 63:9-33.
21. Park Y., Kim D.-Y., Lee J.-W., Huh D.G., Park K.-P., Lee J.Y., Lee H. Sequestering carbon dioxide into complex structures of naturally occurring hydrates. PNAS 2006, 103:12690-12694.
22. Lee S., Liang L.Y., Riestenberg D., West O.R., Tsouris C., Adams E. CO2 hydrate composite for ocean carbon sequestration. Environmental Science and Technology 2003, 37:3701-3708.
23. Uchida T., Ebinuma T., Kawabata J., Narita H. Microscopic observations of formation processes of clathrate-hydrate films at an interface between water and carbon dioxide. Journal of Crystal Growth 1999, 204:348-356.
24. Uchida T., Takagi A., Mae S., Kawabata J. Dissolution mechanisms of CO2 molecules in water containing CO2 hydrates. Energy Conversion and Management 1997, 38:S307-S312.
25. Uchida T., Ikeda I.Y., Takeya S., Ebinuma T., Nagao J., Narita H. CO2 hydrate film formation at the boundary between CO2 and water: effects of temperature, pressure and additives on the formation rate. J. Crystal Growth 2002, 237:383-387.
26. Uchida T., Kawabata J. Measurements of mechanical properties of the liquid CO2-water-CO2-hydrate system. Energy 1997, 22:357-361.
27. Ohgaki K., Hamanaka T. Phase-behaviro of CO2 hydrate-liquid CO2-H2O system at high-pressure. Kagaku Kogaku Ronbunshu 1995, 21:800-803.
28. Zatsepina O.Y., Buffett B.A. Experimental study of the stability of CO2-hydrate in a porous medium. Fluid Phase Equilibria 2001, 192:85-102.
29. Kato M., Iida T., Mori Y.H. Drop formation behaviour of a hydrate-forming liquid in a water stream. Journal of Fluid Mechanics 2000, 414:367-378.
30. Henning R., Schultz A., Thieu V., Halpern Y. Neutron diffraction studies of CO2 clathrate hydrate: formation from deuterated ice. Journal of Physical Chemistry A 2000, 104:5066-5071.
31. Spencer D.F., North W.J. Ocean systems for managing the global carbon cycle. Energy Conversion and Management 1997, 38:S265-S271.
32. G.K. Anderson, G.T. Baca, R.S. Barbero, R.P. Currier, L.A. Le, R.J. Martinez, S.J. Obery, M.A. Sedillo, D. Yang, G.R. Deppe, D.F. Spencer, S.S. Tam, Continuous Hydrate Production Using Bench-Scale Flow Reactors, Los Alamos National Laboratory Report LA-UR-04-6957, Progress Report Submitted to DOE/NETL, Los Alamos, 2005.
33. G.K. Anderson, G.T. Baca, R.S. Barbero, R.P. Currier, L.A. Le, R.J. Martinez, S.J. Obery, M.A. Sedillo, D. Yang, G.R. Deppe, D.F. Spencer, S.S. Tam, The Engineering Test Module (ETM): Construction, Commissioning, and Initial Hydrate Production Experiments, Los Alamos National Laboratory Report LA-UR-05-7377, Progress Report Submitted to DOE/NETL, Los Alamos, 2006.
34. R.P. Currier, L.A. Le, R.J. Martinez, S.J. Obrey, D. Yang, D.F. Spencer, Syngas Upgrading - A Low Temperature Approach (Final Report), Los Alamos National Laboratory Report LA-UR-09-02729, Progress Report Submitted to DOE/NETL, Los Alamos, 2009.
35. Yang D., Le L.A., Martinez R.J., Currier R.P., Spencer D.F., Deppe G. Heat transfter during CO2 hydrate formation in a continuous flow reactor. Energy & Fuels 2008, 22:10.
36. Currier R.P., Yang D., Le L.A., Martinez R.J., Sedillo M.A., Obery S.J., Tam S.S., Lee T., Spencer D.F. CO2 hydrate formation in a continuous flow reactor. Fifth Annual Conference on Carbon Capture & Sequestration 2005.
37. Wender I., Sayari A. Chemistry and Uses of Carbon Dioxide. Final Report 1986, Department of Chemical and Petroleum Engineering, Pittsburgh University, Pittsburgh, USA, p. 119.
38. Anderson G.K. Solubility of carbon dioxide in water under incipient clathrate formation conditions. Journal of Chemical and Engineering Data 2002, 47:219-222.
39. Wilson E.E. A basis for rational design of heat transfer apparatus. Transactions on ASME 1915, 37:47-82.
40. Anderson G.K. Enthalpy of dissociation and hydration number of carbon dioxide hydrate from the clapeyron equation. Journal of Chemical Thermodynamics 2003, 35:1171-1183.
41. Circone S., Stern L.A., Kirby S.H., Durham W.B., Chakoumakos B.C., Rawn C.J., Rondinone A.J., Ishii Y. CO2 hydrate: synthesis, composition, structure, dissociation behavior, and a comparison to structure I CH4 hydrate. Journal of Physical Chemistry B 2003, 107:5529-5539.
42. Kawamura T., Komai T., Yamamoto Y., Nagashima K., Ohga K., Higuchi K. Growth kinetics of CO2 hydrate just below melting point of ice. Journal of Crystal Growth 2002, 234:220-226.
43. Pilling M.J., Seakins P.W. Reaction Kinetices 1995, Oxford Sceience Publications, New York.
44. Froment G.F., Bischoff K.B. Chemical Reactor Design 1979, Wiely, New York. 2nd edition.
45. Tajima H., Yamasaki A., Kiyono F. Continuous formation of CO2 hydrate via a Kenics-type static mixer. Energy & Fuels 2004, 18:1451-1456.
46. Tajima H., Yamasaki A., Kiyono F. Effects of mixing functions of static mixers on the formation of CO2 hydrate from the two-phase flow of liquid CO2 and water. Energy & Fuels 2005, 19:2364-2370.
47. Yamasaki A., Teng H., Wakatsuki M., Yanagisawa Y., Yamada K. CO2 hydrate formation in various hydrodynamic conditions. Annals of The New York Academy of Sciences 2000, 912:235-245.
48. Uchida T., Ikeda I.Y., Takeya S., Kamata Y., Ohmura R., Nagao J., Zatsepina O.Y., Buffett B.A. Kinetics and stability of CH4-CO2 mixed gas hydrates during formation and long-term storage. Chemphyschem 2005, 6:646-654.
49. He Y., Rudolph E.S.J., Zitha P.L.J., Golombok M. Kinetics of CO2 and methane hydrate formation: an experimental analysis in the bulk phase. Fuel 2011, 90:272-279.
50. Lehmkuhler F., Paulus M., Sternemann C., Lietz D., Venturini F., Gutt C., Tolan M. The carbon dioxide-water interface at conditions of gas hydrate formation. JACS 2009, 131:5.
51. Englezos P., Kalogerakis N., Dholabhai P.D., Bishnoi P.R. Kinetics of formation of methane and ethane gas hydrates. Chemical Engineering Science 1987, 42:2647-2658.
52. Moon C., Hawtin R.W., Rodger P.M. Nucleation and control of clathrate hydrates: insights from simulation. Faraday Discussions 2007, 136:367-382.
53. Mori Y.H. Clathrate hydrate formation at the interface between liquid CO2 and water phases - a review of rival models characterizing " hydrate films" Energy Conversion and Management 1998, 39:1537-1557.
54. Clarke M.A., Bishnoi P.R. Determination of the intrinsic rate constant and activation energy of CO2 gas hydrate decomposition using in-situ particle size analysis. Chemical Engineering Science 2004, 59:2983-2993.