Dynamics of intraparticle desorption and chemical reaction in fixed-beds using inert core spherical particles

Chemical Engineering Journal

Volumn 172, Issue 1, 2011, Pages 500-506

  Shams, K ^a   Najari, S ^a  

^a ISFAHAN UNIVERSITY OF TECHNOLOGY   (Iran)

Author keywords

Breakthrough curve; Desorption; Finite difference; Fixed bed; Inert core spheres; Reaction

Indexed keywords

BREAK THROUGH CURVE; FINITE DIFFERENCE; FIXED-BED; INERT CORE SPHERES; REACTION; DESORPTION DYNAMICS; EFFECT OF CHEMICALS; MASS TRANSFER RESISTANCES; NONLINEAR ISOTHERMS; NONLINEARITY EFFECT;

CHEMICAL REACTIONS; CONTROL NONLINEARITIES; FINITE DIFFERENCE METHOD; ISOTHERMS; NONLINEAR EQUATIONS; PACKED BEDS; SPHERES;

DESORPTION;

EID: 79960981529     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2011.06.045     Document Type: Article

References (82)

1. Rosen J.B. General numerical solution for solid diffusion in fixed-beds. Ind. Eng. Chem. 1954, 46:1590-1594.
2. Babcock R.E., Green D.W., Perry R.H. Longitudinal dispersion mechanisms in packed beds. AIChE J. 1966, 12:922-926.
3. Rasmuson A., Neretnieks I. Exact solution of a model for diffusion in particles and longitudinal dispersion in packed beds. AIChE J. 1980, 26:686-690.
4. Raghavan N.S., Ruthven D.M. Numerical simulation of a fixed-bed adsorption column by the method of orthogonal collocation. AIChE J. 1983, 29:922-925.
5. Rasmuson A. Exact solution of a model for diffusion in particles and longitudinal dispersion in packed beds: numerical evaluation. AIChE J. 1985, 31:518-519.
6. Costa C., Rodrigues A. Design of cyclic fixed-bed adsorption processes. AIChE J. 1985, 31:1645-1654.
7. Cen P.L., Yang R.T. Analytic solution for adsorber breakthrough curves with bidisperse sorbents (zeolites). AIChE J. 1986, 32:1635-1641.
8. Brian B.F., Zwiebel I. Numerical simulation of fixed-bed adsorption dynamics by the method of lines. ACS Symp. Ser. 1987, 83:80-86.
9. Sun L.M., Quere P., Levan M.D. Numerical simulation of diffusion limited PSA process models by finite difference methods. Chem. Eng. Sci. 1996, 51:5341-5352.
10. Xiu G.H. Modeling breakthrough curves in a fixed-bed of activated carbon fiber-exact solution and parabolic approximation. Chem. Eng. Sci. 1996, 51:4039-4041.
11. Xiu G.H., Nitta T., Li P., Jin G. Breakthrough curves for fixed-bed adsorbers: quasi lognormal distribution approximation. AIChE J. 1997, 43:979-985.
12. Shams K. Exact solution of a model for in situ volatilization to remediate vadose zone soils. Iranian J. Sci. Technol. Trans. B 1999, 23:229-238.
13. Xiu G.H., Li P. Prediction of breakthrough curves for adsorption of lead (II) on activated carbon fibers in a fixed bed. Carbon 2000, 38:975-981.
14. Susu A.A. Mathematical modelling of fixed bed adsorption of aromatics and sulphur compounds in kerosene deodorization. Chem. Eng. Process. 2000, 39:485-497.
15. Rivero M.J., Ibanez R., Ortiz M.I. Mathematical modelling of styrene drying by adsorption onto activated alumina. Chem. Eng. Sci. 2002, 57:2589-2592.
16. Tsysin G.I., Kovalev I.A., Nesterenko P.N., Penner N.A., Filippov O.A. Application of linear model of sorption dynamics to the comparison of solid phase extraction systems of phenol. Sep. Purif. Technol. 2003, 33:11-24.
17. Claudino A., Soares J.L., Moreira R.F.P.M., Jose H.J. Adsorption equilibrium and breakthrough analysis for NO adsorption on activated carbons at low temperatures. Carbon 2004, 42:1483-1490.
18. Das D., Gaur V., Verma N. Removal of volatile organic compound by activated carbon fiber. Carbon 2004, 42:2949-2962.
19. Ruthven D.M. Sorption kinetics for diffusion-controlled systems with a strongly concentration-dependent diffusivity. Chem. Eng. Sci. 2004, 59:4531-4545.
20. Cheng T., Jiang Y., Zhang Y., Liu S.H. Prediction of breakthrough curves for adsorption on activated carbon fibers in a fixed bed. Carbon 2004, 42:3081-3085.
21. Chang D., Min J., Moon K., Park Y.K., Jeon J.K., Ihm S.K. Robust numerical simulation of pressure swing adsorption process with strong adsorbate CO2. Chem. Eng. Sci. 2004, 59:2715-2725.
22. Scheer A.P., Toledo E.C.V., Filho R.M., Wolf-Maciel M.R. Towards an efficient mathematical procedure for calculating dynamic adsorption process. European Symposium on Computer Aided Process Engineering-15 2005.
23. Ko D.C.K., Porter J.F., McKay G. Application of the concentration dependent surface diffusion model on the multicomponent fixed-bed adsorption systems. Chem. Eng. Sci. 2005, 60:5472-5479.
24. Couenne F., Jallut C., Tayakout-Fayolle M. On minimal representation of heterogeneous mass transfer for simulation and parameter estimation: application to breakthrough curves exploitation. Comput. Chem. Eng. 2005, 30:42-53.
25. Warchoł J., Petrus R. Modeling of heavy metal removal dynamics in clinoptilolite packed beds. Micropor. Mesopor. Mater. 2006, 93:29-39.
26. Shim W.G., Lee J.W., Moon H. Adsorption equilibrium and column dynamics of VOCs on MCM-48 depending on pelletizing pressure. Micropor. Mesopor. Mater. 2006, 88:112-125.
27. Fiol N., Escudero C., Poch J., Villaescusa I. Preliminary studies on Cr(VI) removal from aqueous solution using grape stalk wastes encapsulated in calcium alginate beads in a packed bed up-flow column. React. Funct. Polym. 2006, 66:795-807.
28. Chang H., Yuan X.G., Tian H., Zeng A.W. Experiment and prediction of breakthrough curves for packed bed adsorption of water vapor on cornmeal. Chem. Eng. Process. 2006, 45:747-754.
29. Persson P., Gustavsson P.E., Zacchi G., Nilsson B. Aspects of estimating parameter dependencies in a detailed chromatography model based on frontal experiments. Process Biochem. 2006, 41:1812-1821.
30. Marban G., Valdés-Solis T., Fuertes A.B. Modeling the breakthrough behavior of an activated carbon fiber monolith in n-butane adsorption from diluted streams. Chem. Eng. Sci. 2006, 61:4762-4772.
31. Sankararao B., Gupta S.K. Modeling and simulation of fixed bed adsorbers (FBAs) for multi-component gaseous separations. Comput. Chem. Eng. 2007, 31:1282-1295.
32. Guelli S.M.A., de Souza U., Peruzzo L.C., Ulson de Souza A.A. Numerical study of the adsorption of dyes from textile effluents. Appl. Math. Modell. 2008, 32:1711-1718.
33. Xiao Y., Wang S., Wu D., Yuan Q. Experimental and simulation study of hydrogen sulfide adsorption on impregnated activated carbon under anaerobic conditions. J. Hazard. Mater. 2008, 153:1193-1200.
34. Diban N., Ruiz G., Urtiaga A. I Ortiz, Granular activated carbon for the recovery of the main pear aroma compound: viability and kinetic modelling of ethyl-2,4-decadienoate adsorption. J. Food Eng. 2007, 78:1259-1266.
35. Lee J.W., Yang T.H., Shim W.G., Kwon T.O., Moon I.S. Equilibria and dynamics of liquid-phase trinitrotoluene adsorption on granular activated carbon: effect of temperature and pH. J. Hazard. Mater. 2007, 141:185-192.
36. Gutsche R., Bunke G. Modelling the liquid-phase adsorption in packed beds at low Reynolds numbers: an improved hydrodynamic model. Chem. Eng. Sci. 2008, 63:4203-4217.
37. Vilar V.J.P., Botelho C.M.S., Boaventura R.A.R. Lead uptake by algae gelidium and composite material particles in a packed bed column. Chem. Eng. J. 2008, 144:420-430.
38. Bertrand O., Cochet S., Cartron J.P. Expanded bed chromatography for one step purification of mannose binding lectin from tulip bulbs using mannose immobilized on DEAE streamline. J. Chromatogr. A 1998, 822:19-28.
39. Owen R.O., Chase H.A. Modeling of the continuous counter-current expanded bed adsorber for the purification of proteins. Chem. Eng. Sci. 1999, 54:3765-3781.
40. Ozyurt S., Kirdar B., Ulgen K.O. Recovery of antithrombin III from milk by expanded bed chromatography. J. Chromatogr. A 2002, 944:203-210.
41. Hunter A.K., Carta G. Protein adsorption on novel acrylamido-based polymeric ion exchangers II. Adsorption rates and column behavior. J. Chromatogr. A 2000, 897:81-97.
42. Agilent poroshell 300SB-C18 datasheet, Agilent Technologies Inc., 2003, http://www.agilent.com/
43. Kirkland J.J., Truszkowski F.A., Dilks C.H., Engel G.S. Superficially porous silica microspheres for fast high-performance liquid chromatography of macromolecules. J. Chromatogr. A 2000, 890:3-13.
44. Chen J.F., Ding H.M., Wang J.X., Shao L. Preparation and characterization of porous hollow silica nanoparticles for drug delivery application. Biomaterials 2004, 25:723-727.
45. Xiong C., Coutinho D., Balkus K.J. Fabrication of hollow spheres composed of nanosized ZSM-5 crystals via laser ablation. Micropor. Mesopor. Mater. 2005, 86:14-22.
46. Gong X.C., Luo G.S., Yang W.W., Wu F.Y. Separation of organic acids by newly developed polysulfone microcapsules containing triotylamine. Sep. Purif. Technol. 2006, 48:235-243.
47. Koo I.G., Lee M.S., Lee W.M. Low temperature plasma-chemical treatment of PdCl2 film by atmospheric pressure hydrogen plasma. Thin Solid Films 2006, 506/507:350-354.
48. Zhou Z., Yang J., Zhang Y., Chang L., Sun W., Wang J. NaA zeolite/carbon nanocomposite thin films with high permeance for CO2/N2 separation. Sep. Purif. Technol. 2007, 55:392-395.
49. Shams K. Sorption dynamics of a fixed-bed system of thin-film-coated monodisperse spherical particles/hollow spheres. Chem. Eng. Sci. 2001, 56:5383-5390.
50. Li P., Xiu G., Rodrigues A.E. Analytical breakthrough curves for inert core adsorbent with sorption kinetics. AIChE J. 2003, 49:2974-2979.
51. Li P., Xiu G., Rodrigues A.E. Modeling separation of proteins by inert core adsorbent in a batch adsorber. Chem. Eng. Sci. 2003, 58:3361-3371.
52. Li P., Xiu G., Rodrigues A.E. Modeling breakthrough and elution curves in fixed bed of inert core adsorbents: analytical and approximate solutions. Chem. Eng. Sci. 2004, 59:3091-3103.
53. Khosravi Koocheksarayi M., Shams K., Liu Y.Z. Sorption dynamics of inert core spherical adsorbents including axial dispersion and Langmuir isotherm. AIChE J. 2009, 55:1784-1792.
54. Agar D.W. Multifunctional reactors: old preconceptions and new dimensions. Chem. Eng. Sci. 1999, 54:1299-1305.
55. Dautzenberg F.M., Mukherjee M. Process intensification using multifunctional reactors. Chem. Eng. Sci. 2001, 56:251-267.
56. Gomes V.G., Fuller M. Periodic and nonperiodic dynamic responses for sorption diffusion and reaction in a berty reactor. Ind. Eng. Chem. Res. 1994, 33:102-108.
57. Szukiewicz M., Kaszmarski K., Petrus R. Modelling of fixed-bed reactors: two models of industrial reactor for selective hydrogenation of acetylene. Chem. Eng. Sci. 1998, 53:149-155.
58. Sutikno T. Analytical model for chemisorption of cyanogens chloride on impregnated carbon. Chem. Eng. J. 1999, 75:207-212.
59. Zhang H., Cheng D. Mathematical model for a fixed bed adsorptive reactor. Carbon 2000, 38:877-880.
60. Lode F., Houmard M., Migliorini C., Mazzotti M., Morbidelli M. Continuous reactive chromatography. Chem. Eng. Sci. 2001, 56:269-291.
61. Szukiewicz M.K. New approximate model for diffusion and reaction in a porous catalyst. AIChE J. 2000, 46:661-665.
62. Szukiewicz M.K. Approximate model for diffusion and reaction in a porous catalyst with mass transfer resistances. AIChE J. 2001, 47:2131-2135.
63. Silva V.M.T.M., Rodrigues A.E. Dynamics of a fixed bed adsorptive reactor for synthesis of diethylacetal. AIChE J. 2002, 48:625-634.
64. Szukiewicz M.K. An approximate model for diffiusion and reaction in a porous pellet. Chem. Eng. Sci. 2002, 57:1451-1457.
65. Basagaoglu H., McCoy B.J., Ginn T.R., Loge F.J., Dietrich J.P. A diffusion limited sorption kinetics model with polydispersed particles of distinct sizes and shapes. Adv. Water Resour. 2002, 25:755-772.
66. Xiu G.H., Li P., Rodrigues A.E. Sorption enhanced reaction process with reactive regeneration. Chem. Eng. Sci. 2002, 57:3893-3908.
67. Alhumaizi K., Henda R., Soliman M. Numerical analysis of a reaction diffusion/convection system. Comput. Chem. Eng. 2003, 27:579-594.
68. Coutelieris F.A., Burganos V.N., Payatakes A.C. Model of adsorption reaction desorption in a swarm of spheroidal particles. AIChE J. 2004, 50:779-785.
69. Strohlein G., Mazzotti M., Morbidelli M. Optimal operation of simulated moving bed reactors for nonlinear adsorption isotherms and equilibrium reactions. Chem. Eng. Sci. 2005, 60:1525-1533.
70. Coutelieris F.A., Kainourgiakis M.E., Stubos A.K. Low to moderate Peclet mass transport in assemblages of spherical particles for a realistic adsorption reaction desorption mechanism. Powder Technol. 2005, 159:173-179.
71. Alhumaizi K. A moving collocation method for the solution of the transient convection diffusion reaction problems. J. Comput. Appl. Math. 2006, 193:484-496.
72. Hashim M.A., Chu K.H. Prediction of protein breakthrough behavior using simplified analytical solutions. Sep. Purif. Technol. 2007, 53:189-197.
73. Gomes P.S., Leao C.P., Rodrigues A.E. Simulation of true moving bed adsorptive reactor: detailed particle model and linear driving force approximations. Chem. Eng. Sci. 2007, 62:1026-1041.
74. Wang L., Wang S., Yuan Q. Removal of carbon disulfide via coupled reactions on a bi-functional catalyst: experimental and modeling results. Chemosphere 2007, 69:1689-1694.
75. Basagaoglu H., McCoy B.J. Linear driving force model for diffusion and reaction with interphase partitioning. AIChE J. 2001, 47:754-757.
76. Ma L., Ning P., Zhang Y., Wang X.Q. Experimental and modeling of fixed-bed reactor for yellow phosphorous tail gas purification over impregnated activated carbon. Chem. Eng. J. 2008, 137:471-479.
77. Kim D.H. Approximations for unsteady state diffusion and reaction in porous catalyst and their application to packed bed reactor. AIChE J. 2008, 54:2423-2431.
78. Kim D.H. Linear driving force formulas for unsteady state diffusion and reaction in slab, cylinder and sphere catalyst. AIChE J. 2009, 55:834-839.
79. Kolade M.A., Kogelbauer A., Alpay E. Adsorptive reactor technology for VOC abatement. Chem. Eng. Sci. 2009, 64:1167-1177.
80. Xia S., Hodge N.Y., Wiesner T.F. Closed-form solution to the problem of reaction with fixed bed adsorption using delay-differential equations. Chem. Eng. Sci. 2009, 64:2057-2066.
81. Leonard B.P. A stable and accurate convective modeling procedure based on quadratic upstream interpolation. Comput. Methods Appl. Mech. Eng. 1979, 19:59-98.
82. Lapidus L., Pinder G.F. Numerical Solution of Partial Differential Equations 1981, vol. 1. Prentice Hall, Englwood Cliffs, NJ.