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Volumn 50, Issue 32, 2011, Pages 7273-7277

[Sn4Si{Si(SiMe3)3}4{SiMe 3}2]:A model compound for the unexpected first-order transition from a singlet biradicaloid to a classical bonded molecule

Author keywords

cluster compounds; computer chemistry; singlet biradicaloids; subhalides; tin

Indexed keywords

BIRADICALOID SPECIES; BONDED MOLECULE; CLUSTER COMPOUNDS; COMPUTER CHEMISTRY; FIRST ORDER TRANSITIONS; IDEAL MODEL; MODEL COMPOUND; NEW MEMBERS; SINGLET BIRADICALOIDS; SUBHALIDES;

EID: 79960924056     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201102662     Document Type: Article
Times cited : (19)

References (55)
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    • A presentation of the asymmetric unit can be found in the Supporting Information.
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    • -3) are close to the tin atoms with coordination number three. The distance between these residual electron densities is around 260 pm, corresponding to a bonded system in region II. Further investigations applying synchrotron radiation may provide a deeper insight if both isomers, that is, the singlet biradicaloid form and the classically bonded 2c2e case, are both present in the solid state.
    • -3) are close to the tin atoms with coordination number three. The distance between these residual electron densities is around 260 pm, corresponding to a bonded system in region II. Further investigations applying synchrotron radiation may provide a deeper insight if both isomers, that is, the singlet biradicaloid form and the classically bonded 2c2e case, are both present in the solid state.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.