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Volumn 50, Issue 32, 2011, Pages 7278-7282

A process for the synthesis of formic acid by CO2 hydrogenation: Thermodynamic aspects and the role of CO

Author keywords

carbon dioxide; formic acid; reaction mechanisms; ruthenium; thermodynamics

Indexed keywords

ALCOHOL SOLVENT; CATALYTIC CYCLES; HYDROGEN BONDINGS; PHOSPHINE COMPLEX; REACTION MECHANISM; THERMODYNAMIC ASPECTS;

EID: 79960913537     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201101292     Document Type: Review
Times cited : (269)

References (49)
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    • Selected reviews on this topic
    • Selected reviews on this topic
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    • 3 as base or tailor-made expensive ionic liquids, from which either the formic acid cannot be isolated or where the catalyst activity and achieved product concentration are not in the range required for an economic process
    • 3 as base or tailor-made expensive ionic liquids, from which either the formic acid cannot be isolated or where the catalyst activity and achieved product concentration are not in the range required for an economic process
  • 20
    • 67649774239 scopus 로고    scopus 로고
    • 2) Use of multiphase liquid-liquid systems for catalyst separation, but where the catalyst recycling is either very inefficient, a base exchange for the separation of the formic acid is necessary (mainly imidazoles), or an extracting agent is required prior to distillation, resulting in an expensive and complex process
    • Z. Zhang, S. Hu, J. Song, W. Li, G. Yang, B. Han, ChemSusChem 2009, 2, 234-238; 2) Use of multiphase liquid-liquid systems for catalyst separation, but where the catalyst recycling is either very inefficient, a base exchange for the separation of the formic acid is necessary (mainly imidazoles), or an extracting agent is required prior to distillation, resulting in an expensive and complex process
    • (2009) ChemSusChem , vol.2 , pp. 234-238
    • Zhang, Z.1    Hu, S.2    Song, J.3    Li, W.4    Yang, G.5    Han, B.6
  • 25
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    • 2; Addition of deactivating reagents and separation of the ruthenium species is reported, but the ruthenium must then be regenerated to the active catalyst in a separate wet-chemical step
    • 2; Addition of deactivating reagents and separation of the ruthenium species is reported, but the ruthenium must then be regenerated to the active catalyst in a separate wet-chemical step
    • (1989)
    • Beevor, R.G.1    Gulliver, D.J.2    Kitson, M.3    Sorrell, R.M.4
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    • [3f-i]
    • [3f-i]
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    • The details on the process concept and experimental data are described elsewhere: PCT Application PCT/EP 2010/058208.
    • The details on the process concept and experimental data are described elsewhere: PCT Application PCT/EP 2010/058208.
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    • Experimental details are given in the Supporting information.
    • Experimental details are given in the Supporting information.
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    • 2] as catalyst showed good activity in the work of Jessop, Noyori et al.
    • 2] as catalyst showed good activity in the work of Jessop, Noyori et al.
  • 36
    • 79960907306 scopus 로고    scopus 로고
    • This maximum concentration in the equilibrium could be reached either in the hydrogenation itself or in the backward reaction for 2-methyl-1,3- propanediol when a 10 % mixture of formic acid in the product phase was exposed to the hydrogenation conditions; see the Supporting Information.
    • This maximum concentration in the equilibrium could be reached either in the hydrogenation itself or in the backward reaction for 2-methyl-1,3- propanediol when a 10 % mixture of formic acid in the product phase was exposed to the hydrogenation conditions; see the Supporting Information.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.