Spin crossover polymeric iron(II) complex based on triazole with branched long alkyl chain

Inorganic Chemistry Communications

Volumn 14, Issue 9, 2011, Pages 1498-1500

  Lee, Young Hoon ^a   Komatsu, Yasuka ^a   Yamamoto, Yuuki ^a   Kato, Kazuya ^a   Shimizu, Tetsuya ^a   Ohta, Asuka ^a   Matsui, Takeshi ^a   Hayami, Shinya ^a  

^a KUMAMOTO UNIVERSITY   (Japan)

Author keywords

Branched long alkyl chain; Phase transition; Polymeric iron(II) complex; Spin crossover

Indexed keywords

EID: 79960834641     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2011.05.055     Document Type: Article

References (23)

1. H.A. Goodwin Spin transitions in six-coordinate iron(II) complexes Coord. Chem. Rev. 18 1976 293 325
2. P. Gütlich, and A. Hauser Thermal and light-induced spin crossover in iron(II) complexes Coord. Chem. Rev. 97 1990 1 22
3. P. Gütlich, Y. Garcia, and H.A. Goodwin Spin crossover phenomena in Fe(II) complexes Chem. Soc. Rev. 29 2000 419 427
4. V. Niel, A.L. Thompson, M.C. Muñoz, A. Galet, A.E. Goeta, and J.A. Real Crystalline-state reaction with allosteric effect in spin-crossover, interpenetrated networks with magnetic and optical bistability Angew. Chem. Int. Ed. 42 2003 3760 3763 (Pubitemid 37047711)
5. J.-F. Létard, P. Guionneau, L. Rabardel, J.A.K. Howard, A.E. Goeta, D. Chasseau, and O. Kahn Structural, magnetic, and photomagnetic studies of a mononuclear iron(II) derivative exhibiting an exceptionally abrupt spin transition. Light-induced thermal hysteresis phenomenon Inorg. Chem. 37 1998 4432
6. S. Hayami, Z. Gu, M. Shiro, Y. Einaga, A. Fujishima, and O. Sato First observation of light-induced excited spin state trapping for an iron(III) complex J. Am. Chem. Soc. 122 2000 7126 7127 (Pubitemid 30639893)
7. S. Hayami, Z. Gu, Y. Einaga, Y. Kobayashi, Y. Ishikawa, Y. Yamada, A. Fujishima, and O. Sato A novel LIESST iron(II) complex exhibiting a high relaxation temperature Inorg. Chem. 40 2001 3240 3242 (Pubitemid 32878832)
8. K. Nakao, S. Hayami, M. Akita, and K. Inoue LIESST effect and cooperativity of a 2-D Hofmann-type compound Chem. Lett. 37 2008 292 293
9. n Eur. Polym. J. 45 2009 3339 3346
10. O. Roubeau, A. Colin, V. Schmitt, and R. Clérac Thermoreversible gels as magneto-optical switches Angew. Chem. Int. Ed. 43 2004 3283 3286 (Pubitemid 39257583)
11. K. Kuroiwa, T. Shibata, A. Takada, N. Nemoto, and N. Kimizuka Heat-set gel-like networks of lipophilic Co(II) triazole complexes in organic media and their thermochromic structural transitions J. Am. Chem. Soc. 126 2004 2016 2021 (Pubitemid 38228881)
12. F. Armand, C. Badoux, P. Bonville, A. Ruaudel-Teixier, and O. Kahn Langmuir-Bodgett films of spin transition iron(II) metalloorganic polymers. 1. Iron(II) complexes of octadecyl-1,2,4-triazole Langmuir 11 1995 3467 3472
13. O. Roubeau, B. Agricole, R. Clérac, and S. Ravaine Triazole-based magnetic Langmuir-Blodgett films: paramagnetic to spin-crossover behavior J. Phys. Chem. B 108 2004 15110 15116
14. O. Roubeau, E. Natividad, B. Agricole, and S. Ravaine Formation, structure, and morphology of triazole-based Langmuir-Blodgett films Langmuir 23 2007 3110 3117 (Pubitemid 46450141)
15. T. Fujigaya, D.-L. Jiang, and T. Aida Switching of spin states triggered by a phase transition: spin-crossover properties of self-assembled iron(II) complexes with alkyl-tethered triazole ligands J. Am. Chem. Soc. 125 2003 14690 14691 (Pubitemid 37475545)
16. T. Fujigaya, D.-L. Jiang, and T. Aida Spin-crossover dendrimers: generation number-dependent cooperativity for thermal spin transition J. Am. Chem. Soc. 127 2005 5484 5489 (Pubitemid 40569859)
17. M. Seredyuk, A.B. Gaspar, V. Ksenofontov, S. Reiman, Y. Galyametdinov, W. Haase, E. Rentschler, and P. Gütlich Room temperature operational thermochromic liquid crystals Chem. Mater. 18 2006 2513 2519 (Pubitemid 43987341)
18. S. Hayami, S. Miyazaki, J. Kawamata, and K. Inoue Second-order non-linear optical response in LB films for the metal complexes Polyhedron 28 2009 1722 1727
19. S. Hayami, R. Moriyama, A. Shuto, Y. Maeda, K. Ohta, and K. Inoue Spin transition at the mesophase transition temperature in a cobalt(II) compound with branched alkyl chains Inorg. Chem. 46 2007 7692 7694
20. 8: C, 65.39; H, 10.79; N, 7.89. Found: C, 65.42; H, 10.75; N, 7.81.
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