The photolysis of flash-frozen dilute hydrogen peroxide solutions

Journal of Geophysical Research Atmospheres

Volumn 116, Issue 14, 2011, Pages

  Beine, Harry ^a   Anastasio, Cort ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EXPERIMENTS; HYDROGEN; HYDROGEN PEROXIDE; ICE; LIQUIDS; OXIDATION; QUANTUM YIELD; RATE CONSTANTS;

BIPHASIC; CHEMICAL TRACERS; DILUTE AQUEOUS SOLUTION; ICE SAMPLES; INITIAL RATE; LOWER BOUNDS; MATRIX; OH FORMATION; OXIDATIVE CAPACITY; PHOTIC ZONE; PHOTOLYSIS RATES; POLAR ENVIRONMENTS; QUASILIQUID LAYERS; SUMMER SOLSTICE;

PHOTOLYSIS;

AQUEOUS SOLUTION; ATMOSPHERIC CHEMISTRY; DILUTION; FREEZING; HYDROGEN PEROXIDE; OXIDATION; PHOTOCHEMISTRY; PHOTOLYSIS; POLAR REGION; PROBE; REACTION RATE; SCAVENGING (CHEMISTRY); SNOWPACK; TRACER;

EID: 79960549523     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/2010JD015531     Document Type: Article

References (41)

1. Anastasio, C, and A. L. Jordan (2004), Photoformation of hydroxyl radical and hydrogen peroxide in aerosol particles from Alert, Nunavut: Implications for aerosol and snowpack chemistry in the Arctic, Atmos. Environ., 38(8), 1153-1166, doi:10.1016/j.atmosenv.2003.11.016. (Pubitemid 38169440)
2. Anastasio, C, and K. G. McGregor (2001), Chemistry of fog waters in California's Central Valley: 1. In situ photoformation of hydroxyl radical and singlet molecular oxygen, Atmos. Environ., 35, 1079-1089, doi:10.1016/S1352- 2310(00)00281-8. (Pubitemid 32180786)
3. Anastasio, C, B. Faust, and J. Allen (1994), Aqueous phase photochemical formation of hydrogen peroxide in authentic cloud waters, J. Geophys. Res., 99(D4), 8231, doi:10.1029/94JD00085.
4. Anastasio, C, E. S. Galbavy, M. A. Hutterli, J. F. Burkhart, and D. Friel (2007), Photoformation of hydroxyl radical on snow grains at Summit, Greenland, Atmos. Environ., 41, 5110-5121, doi:10.1016/j.atmosenv. 2006.12.011. (Pubitemid 47042535)
5. Chu, L., and C. Anastasio (2005), Formation of hydroxyl radical from the photolysis of frozen hydrogen peroxide, J. Phys. Chem. A, 109, 6264-6271, doi:10.1021/jp051415f. (Pubitemid 41083909)
6. [Addition and correction, J. Phys. Chem. A, 112, 2747-2748, doi:10.1021/jp800491n, 2008.]
7. Chu, L., and C. Anastasio (2007), Temperature and wavelength dependence of nitrite photolysis in frozen and aqueous solutions, Environ. Sci. Technol, 41, 3626-3632, doi:10.1021/es062731q.
8. Dominé, F., and P. B. Shepson (2002), Air-snow interactions and atmospheric chemistry, Science, 297, 1506-1510, doi:10.1126/science. 1074610. (Pubitemid 34970989)
9. Dominé, F., and I. Xueref (2001), Evaluation of depth profiling using laser resonant desorption as a method to measure diffusion coefficients in ice, Anal. Chem., 73(17), 4348-4353, doi:10.1021/ac010255a. (Pubitemid 32830878)
10. Domine, F., et al. (2008), Snow physics as relevant to snow photochemistry, Atmos. Chem. Phys., 8, 171-208, doi:10.5194/acp-8-171-2008.
11. Finlayson-Pitts, B. J., and J. N. Pitts (2000), Chemistry of the Upper and Lower Atmosphere: Theory, Experiments, and Applications, 969 pp., Academic, San Diego, Calif.
12. Fischer, M., and P. Warneck (1996), Photodecomposition of nitrite and undissociated nitrous acid in aqueous solution, J. Phys. Chem., 100, 18,749-18,756, doi:10.1021/jp961692+. (Pubitemid 126834483)
13. Galbavy, E. S., C. Anastasio, B. L. Lefer, and S. R. Hall (2007), Light penetration in the snowpack at Summit, Greenland: Part 1: Nitrite and hydrogen peroxide photolysis, Atmos. Environ., 41, 5077-5090, doi:10.1016/j. atmosenv.2006.04.072. (Pubitemid 47042536)
14. Galbavy, E. S., K. Ram, and C. Anastasio (2010), 2-nitrobenzaldehyde as a chemical actinometer for solution and ice photochemistry, J. Photochem. Photobiol. Chem., 209, 186-192, doi:10.1016/j.jphotochem.2009.11.013.
15. Goldstein, S., D. Aschengrau, Y. Diamant, and J. Rabani (2007), Photolysis of aqueous H2O2: Quantum yield and applications for polychromatic UV actinometry in photoreactors, Environ. Sci. Technol, 41, 7486-7490, doi:10.1021/es071379t. (Pubitemid 350080350)
16. Graedel, T. E., and C. J. Weschler (1981), Chemistry within aqueous atmospheric aerosols and raindrops, Rev. Geophys. Space Phys., 19(4), 505-539, doi:10.1029/RG019i004p00505. (Pubitemid 12504493)
17. Grannas, A. M., et al. (2007), An overview of snow photochemistry: Evidence, mechanisms and impacts, Atmos. Chem. Phys., 7, 4329-4373, doi:10.5194/acp-7-4329-2007. (Pubitemid 47325999)
18. Hagen, W., A. Tielens, and J. M. Greenberg (1981), The infrared-spectra of amorphous solid water and ice Ic between 10 K and 140 K, Chem. Phys., 56(3), 367-379, doi:10.1016/0301-0104(81)80158-9.
19. Hawley, R. L., E. M. Morris, and J. R. McConnell (2008), Rapid techniques for determining annual accumulation applied at Summit, Greenland, J. Glaciol, 54, 839-845, doi:10.3189/002214308787779951.
20. Hullar, T., and C. Anastasio (2011), Yields of hydrogen peroxide from the reaction of hydroxyl radical with organic compounds in solution and ice, Atmos. Chem. Phys. Discuss., 11, 6457-6492, doi:10.5194/acpd-11-6457-2011.
21. Hutterli, M. A., R. Rothlisberger, and R. C. Bales (1999), Atmosphere-to-snow-to-firn transfer studies of HCHO at Summit, Greenland, Geophys. Res. Lett, 26(12), 1691-1694, doi:10.1029/1999GL900327. (Pubitemid 29511423)
22. Hutterli, M. A., J. R. McConnell, R. W. Stewart, H.-W. Jacobi, and R. C. Bales (2001), Impact of temperature-driven cycling of hydrogen peroxide (H2O2) between air and snow on the planetary boundary layer, J. Geophys. Res., 106(D14), 15,395-15,404, doi:10.1029/2001JD900102.
23. Hutterli, M. A., J. R. McConnell, R. W. Stewart, and R. C. Bales (2003), Sensitivity of hydrogen peroxide (H2O2) and formaldehyde (HCHO) preservation in snow to changing environmental conditions: Implications for the interpretation of ice core records, J. Geophys. Res., 108(D1), 4023, doi:10.1029/2002JD002528.
24. Jacobi, H.-W., et al. (2002), Measurements of hydrogen peroxide and formaldehyde exchange between the atmosphere and surface snow at Summit, Greenland, Atmos. Environ., 36, 2619-2628, doi:10.1016/S1352-2310 (02)00106-1. (Pubitemid 34628355)
25. Jacobi, H.-W., B. Kwakye-Awuah, and O. Schrems (2004), Photochemical decomposition of hydrogen peroxide (H2O2) and formaldehyde (HCHO) in artificial snow, Ann. Glaciol., 39, 29-33, doi:10.3189/172756404781814357.
26. Jacobi, H.-W., T. Annor, and E. Quansah (2006), Investigation of the photochemical decomposition of nitrate, hydrogen peroxide, and formaldehyde in artificial snow, J. Photochem. Photobiol. Chem., 179, 330-338, doi:10.1016/j.jphotochem.2005.09.001.
27. Kok, G. L., S.E. McLaren, and T. A. Staffelbach (1995), HPLC determination of atmospheric organic hydroperoxides, J. Atmos. Oceanic Technol., 12(2), 282-289, doi:10.1175/1520-0426(1995)012<0282:HDOAOH>2.0.CO;2.
28. Legrand, M., and P. Mayewski (1997), Glaciochemistry of polar ice cores: A review, Rev. Geophys., 35(3), 219-243, doi:10.1029/96RG03527. (Pubitemid 127667418)
29. Lide, D. R. (Ed.) (2004), CRC Handbook of Chemistry and Physics, CRC Press, Boca Raton, Fla.
30. Luák, S., and P. Sedlák (1992), Photoinitiated reactions of hydrogen peroxide in the liquid phase, J. Photochem. Photobiol. Chem., 68(1), 1-33, doi:10.1016/1010-6030(92)85014-L.
31. Malenkov, G. (2009), Liquid water and ices: Understanding the structure and physical properties. J. Phys. Condens. Matter, 21, 283101, doi:10.1088/0953-8984/21/28/283101.
32. Möller, D. (2009), Atmospheric hydrogen peroxide: Evidence for aqueous-phase formation from a historic perspective and a one-year measurement campaign, Atmos. Environ., 43, 5923-5936, doi:10.1016/j.atmosenv. 2009.08.013.
33. Neftel, A., P. Jacob, and D. Klockow (1984), Measurement of hydrogen peroxide in polar ice samples, Nature, 311, 43-45, doi:10.1038/311043a0. (Pubitemid 16263699)
34. Nissenson, P., D. Dabdub, R. Das, V. Maurino, C. Minero, and D. Vione (2010), Evidence of the water-cage effect on the photolysis of NO3-and FeOH2+. Implications of this effect and of H2O2 surface accumulation on photochemistry at the air-water interface of atmospheric droplets, Atmos. Environ., 44, 4859-4866, doi:10.1016/j.atmosenv.2010.08.035.
35. Ruzicka, R., L. Baráková, and P. Klán (2005), Photodecarbonylation of dibenzyl ketones and trapping of radical intermediates by copper(II) chloride in frozen aqueous solutions, J. Phys. Chem. B, 109(19), 9346-9353, doi:10.1021/jp044661k. (Pubitemid 40751027)
36. Stemmler, K., and U. von Gunten (2000), OH radical-initiated oxidation of organic compounds in atmospheric water phases: Part 1. Reactions of peroxyl radicals derived from 2-butoxyethanol in water, Atmos. Environ., 34, 4241-4252, doi:10.1016/S1352-2310(00)00218-1. (Pubitemid 30628391)
37. Sun, L., and J. R. Bolton (1996), Determination of the quantum yield for the photochemical generation of hydroxyl radicals in TiO2 suspensions, J. Phys. Chem., 100, 4127-4134, doi:10.1021/jp9505800. (Pubitemid 126793347)
38. Thibert, E., and F. Dominé (1997), Thermodynamics and kinetics of the solid solution of HCl in ice, J. Phys. Chem. B, 101(18), 3554-3565, doi:10.1021/jp962115o. (Pubitemid 127611910)
39. Yang, J., et al. (2002), Impacts of snowpack emissions on deduced levels of OH and peroxy radicals at Summit, Greenland, Atmos. Environ., 36, 2523-2534, doi:10.1016/S1352-2310(02)00128-0. (Pubitemid 34628347)
40. Zellner, R., M. Exner, and H. Herrmann (1990), Absolute OH quantum yields in the laser photolysis of nitrate, nitrite and dissolved H2O2 at 308 and 351 nm in the temperature range 278-353 K, J. Atmos. Chem., 10, 411-425, doi:10.1007/BF00115783. (Pubitemid 20355865)
41. Zhou, X., and K. Mopper (1990), Determination of photochemically produced hydroxyl radicals in seawater and freshwater, Mar. Chem., 30, 71-88, doi:10.1016/0304-4203(90)90062-H.