Master curves for mass transfer in bidisperse adsorbents for pressure-swing and volume-swing frequency response methods

AIChE Journal

Volumn 57, Issue 8, 2011, Pages 2054-2069

  Wang, Yu ^a   Levan, M Douglas ^a  

^a VANDERBILT UNIVERSITY   (United States)

Author keywords

Adsorption gas; Biporous material; Diffusion (microporous); Frequency response; Mass transfer

Indexed keywords

ANALYTICAL SOLUTIONS; BIDISPERSE; BIPOROUS MATERIALS; EXPERIMENTAL DATA; FLOWTHROUGH; FREQUENCY RESPONSE METHODS; GENERAL MODEL; ISOTHERMAL MODELS; MACRO PORES; MASS TRANSFER MECHANISM; MASS TRANSFER RESISTANCES; MASTER CURVE; MICROPORE DIFFUSION; MICROPORES; NON-ISOTHERMAL SYSTEM; NONISOTHERMAL; PRESSURE SWING; SIMULATION RESULT; SURFACE BARRIER; TEMPERATURE VARIATION;

ADSORPTION; DIFFUSION; MICROPOROSITY;

FREQUENCY RESPONSE;

EID: 79960295420     PISSN: 00011541     EISSN: 15475905     Source Type: Journal    
DOI: 10.1002/aic.12420     Document Type: Article

References (54)

1. Sun LM, Meunier F. On the heat effect in measurements of sorption kinetics by the frequency response method. Chem Eng Sci. 1993; 48: 715-722.
2. Yasuda Y. Frequency response method for study of the kinetic behavior of a gas-surface system. 1. Theoretical treatment. J Phys Chem. 1976; 80: 1867-1869.
3. Yasuda Y. Frequency response method for investigation of gas/surface dynamic phenomena. Heterogen Chem Rev. 1994; 1: 103-124.
4. Reyes SC, Iglesia E. Frequency response techniques for the characterization of porous catalytic solids. Catalysis. 1994; 11: 51-92.
5. Reyes SC, Sinfelt JH, DeMartin GJ, Ernst RH. Frequency modulation methods for diffusion and adsorption measurements in porous solids. J Phys Chem B. 1997; 101: 614-622.
6. Jordi RG, Do DD. Analysis of the frequency response method for sorption kinetics in bidispersed structured sorbents. Chem Eng Sci. 1993; 48: 1103-1130.
7. Jordi RG, Do DD. Analysis of the frequency response method applied to non-isothermal sorption studies. Chem Eng Sci. 1994; 49: 957-979.
8. Song LJ, Rees LVC. Adsorption and diffusion of cyclic hydrocarbon in MFI-type zeolites studied by gravimetric and frequency-response techniques. Micro Meso Mater. 2000; 35-36: 301-314.
9. Vlyon J, Onyestyák G, Rees LVC. A frequency-response study of the diffusion and sorption dynamics of ammonia in zeolites. Langmuir. 2000; 16: 1331-1336.
10. Yasuda Y. Frequency response method for study of the kinetic behavior of a gas-surface system. 2. An ethylene-on-zinc oxide system. J Phys Chem. 1976; 80: 1870-1875.
11. Yasuda Y. Determination of vapor diffusion coefficients in zeolite by the frequency response method. J Phys Chem. 1982; 86: 1913-1917.
12. Yasuda Y, Sugasawa G. A frequency response technique to study zeolitic diffusion of gases. J Catal. 1984; 88: 530-534.
13. Yasuda Y, Yamamoto A. Zeolitic diffusivities of hydrocarbons by the frequency response method. J Catal. 1985; 93: 176-181.
14. Yasuda Y. Kinetic details of a gas/porous adsorbent system by the frequency response method. J Phys Chem. 1991; 95: 2486-2492.
15. Yasuda Y. Frequency response method for study of the kinetic details of a heterogeneous catalytic reaction of gases. 1. Theoretical treatment. J Phys Chem. 1993; 97: 3314-3318.
16. Yasuda Y, Nomura K. Frequency response method for study of the kinetic details of a heterogeneous catalytic reaction of gases. 2. A methanol conversion to olefins. J Phys Chem. 1993; 97: 3319-3323.
17. Yasuda Y, Mizusawa H, Kamimura T. Frequency response method for investigation of kinetic details of a heterogeneous catalyzed reaction of gases. J Phys Chem B. 2002; 106: 6706-6712.
18. Yasuda Y, Matsumoto A, Oda R. Reaction rate spectroscopy for a catalyzed reaction of gases. Bull Chem Soc Jpn. 2004; 77: 1973-1986.
19. Van-Den-Begin NG, Rees LVC, Caro J, Bülow M, Hunger M, Kärger J. Diffusion of ethane in silicalite-1 by frequency response, sorption uptake and nuclear magnetic resonance techniques. J Chem Soc Faraday Trans. 1989; 85: 1501-1509.
20. Sun LM, Bourdin V. Measurement of intracrystalline diffusion by the frequency response method: analysis and interpretation of bimodal response curves. Chem Eng Sci. 1993; 48: 3783-3793.
21. Sun LM, Meunier F, Grenier P. Frequency response for nonisothermal adsorption in biporous pellets. Chem Eng Sci. 1994; 49: 373-381.
22. Giermanska KJ, Cartigny J, Lara ECD, Sun LM. Heat effect and intercrystalline diffusion of light n-alkanes in zeolite NaX measured by frequency response method. Zeolites. 1996; 17: 365-372.
23. Bourdin V, Grenier P, Meunier F, Sun LM. Thermal frequency response method for the study of mass-transfer kinetics in adsorbents. AIChE J. 1996; 42: 700-712.
24. Boniface HA, Ruthven DM. Chromatographic adsorption with sinusoidal input. Chem Eng Sci. 1985; 40: 2053-2061.
25. 2. AIChE J. 1989; 35: 423-428.
26. Kramers H, Alberda G. Frequency response analysis of continuous flow systems. Chem Eng Sci. 1953; 2: 173-181.
27. Park IS, Petkovska M, Do DD. Frequency response of an adsorber with modulation of the inlet molar flow-rate-I. a semi-batch adsorber, II. a continuous flow adsorber. Chem Eng Sci. 1998; 53: 819-832.
28. Do DD, Do HD, Prasetyo I. Constant molar flow semi-batch adsorber as a tool to study adsorption kinetics of pure gases and vapors. Chem Eng Sci. 2000; 55: 1717-1727.
29. Sward BK, LeVan MD. Frequency response method for measuring mass transfer rates in adsorbents via pressure perturbation. Adsorption. 2003; 9: 37-54.
30. Glover TG, Wang Y, LeVan MD. Diffusion of condensible vapors in single adsorbent particles measured via concentration-swing frequency response. Langmuir. 2008; 24: 13406-13413.
31. Wang Y, LeVan MD. Nanopore diffusion rates for adsorption determined by pressure-swing and concentration-swing frequency response and comparison with Darken's equation. Ind Eng Chem Res. 2008; 47: 3121-3128.
32. Wang Y, LeVan MD. Mixture diffusion in nanoporous adsorbents: development of Fickian flux relationship and concentration-swing frequency response method. Ind Eng Chem Res. 2007; 46: 2141-2154.
33. Wang Y, LeVan MD. Investigation of mixture diffusion in nanoporous adsorbents via the pressure-swing frequency response method. 1. Theoretical treatment. Ind Eng Chem Res. 2005; 44: 3692-3701.
34. Wang Y, LeVan MD. Investigation of mixture diffusion in nanoporous adsorbents via the pressure-swing frequency response method. 2. Oxygen and nitrogen in a carbon molecular sieve. Ind Eng Chem Res. 2005; 44: 4745-4752.
35. Wang Y, Sward BK, LeVan MD. New frequency response method for measuring adsorption rates via pressure modulation: application to oxygen and nitrogen in a carbon molecular sieve. Ind Eng Chem Res. 2003; 42: 4213-4222.
36. Petkovska M, Markovic A. Fast estimation of quasi-steady states of cyclic nonlinear processes based on higher-order frequency response functions. Case study: cyclic operation of an adsorption column. Ind Eng Chem Res. 2006; 45: 266-291.
37. Petkovska M, Petkovska LT. Use of nonlinear frequency response for discriminating adsorption kinetics mechanisms resulting with bimodal characteristic functions. Adsorption. 2003; 9: 133-142.
38. Petkovska M, Do DD. Use of higher order FRFs for identification of nonlinear adsorption kinetics: single mechanisms under isothermal conditions. Nonlinear Dyn. 2000; 21: 353-376.
39. Petkovska M, Do DD. Nonlinear frequency response of adsorption systems: isothermal batch and continuous flow adsorber. Chem Eng Sci. 1998; 53: 3081-3097.
40. Bülow M, Schlodder H, Rees LVC, Richards RE. Molecular mobility of hydrocarbon ZSM5/silicalite systems studied by sorption uptake and frequency response methods. In: Murakami Y, Lijima A, Ward JW, editors. New Development in Zeolite Science and Technology. New York: Elsevier Science Publishing Company, Inc., 1986: 579-586.
41. Shen DM, Rees LVC. Frequency response technique measurements of p-xylene diffusion in silicalite-1 and -2. J Chem Soc Faraday Trans. 1993; 89: 1063-1065.
42. Shen DM, Rees LVC. Study of fast diffusion in zeolites using a higher harmonic frequency response method. J Chem Soc Faraday Trans. 1994; 90: 3011-3015.
43. Shen DM, Rees LVC. Analysis of bimodal frequency-response behavious of p-xylene diffusion in silicalite-1. J Chem Soc Faraday Trans. 1995; 91: 2027-2033.
44. Song LJ, Rees LVC. Adsorption and transport of n-hexane in silicalite-1 by the frequency response technique. J Chem Soc Faraday Trans. 1997; 93: 649-657.
45. Bülow M, Shen DM. Sorption kinetics of atmospheric gases on Li, RE(rare earth)-LSX zeolite beads as sorbents for oxygen PVSA processes. Micro Meso Mater. 2007; 105: 163-169.
46. LeVan MD, Carta G. Adsorption and ion exchange. In: Green DW, Perry RH, editors. Perry's Chemical Engineers' Handbook, 8th ed. New York: McGraw-Hill, 2008: 16-1-16-69.
47. Farooq S, Hassan MM, Ruthven DM. Heat effects in pressure swing adsorption system. Chem Eng Sci. 1988; 43: 1017-1031.
48. Mahle JJ, Friday DK, LeVan MD. Pressure swing adsorption for air purification. 1. Temperature cycling and role of weakly adsorbed carrier gas. Ind Eng Chem Res. 1996; 35: 2342-2354.
49. Walton KS, LeVan MD. Consistency of energy and material balances for bidisperse particles in fixed-bed adsorption and related applications. Ind Eng Chem Res. 2003; 42: 6938-6948.
50. Bourdin V, Gray PG, Grenier P, Terrier MF. An apparatus for adsorption dynamics studies using infrared measurement of the adsorbent temperature. Rev Sci Instrum. 1998; 69: 2130-2136.
51. Do DD. Adsorption Analysis: Equilibria and Kinetics. London: Imperial College Press, 1998.
52. Karger J, Ruthven DM. Diffusion in Zeolites and Other Microporous Solids. New York: Wiley, 1992.
53. Qinglin H, Sundaram SM, Farooq S. Revisiting transport of gases in the micropores of carbon molecular sieves. Langmuir. 2003; 19: 393-405.
54. 2 diffusion in commercial 5A powders and pellets. Micro Mater. 1996; 5: 279-288.